邢台市颗粒污染物变化特征和后向轨迹分析

为深入了解邢台市PM_(10)、PM_(2.5)浓度变化情况和气流后向轨迹,对邢台市2013—2016年环境大气颗粒污染物监测数据进行了分析,同时利用HYSPLIT模型计算出逐日72 h后向气流轨迹。结果表明:邢台市的PM_(10)和PM_(2.5)质量浓度在2013—2016年间呈逐年下降趋势,PM_(10)和PM_(2.5)质量浓度高值出现在冬季(296μg/m~3和192μg/m~3),最低值出现在夏季(140μg/m~3和80μg/m~3),PM_(10)和PM_(2.5)质量浓度在日变化上均呈"双峰双谷"型分布;后向轨迹的季节聚类分析表明,春季大气颗粒物污染以粒径2.5～10μm的颗粒污染物为主,夏季、秋季和冬季的大气颗粒物污染以PM_(2.5)为主;逐日聚类分析表明,在路径为西北偏西向的、途经多个沙源地的气流影响下,邢台市的PM_(10)和PM_(2.5)质量浓度处于一个相对高值;来源于偏南向的气流由于化合反应,污染物积聚导致PM_(10)、PM_(2.5)质量浓度也处于相对高值;在来源于西北向和偏北向的、水汽含量相对较低的气流影响下,邢台市的PM_(10)、PM_(2.5)质量浓度出现一个明显的下降。     

节理充填岩体爆炸应力波传播规律模型试验与应用研究

为研究节理厚度对爆炸应力波传播影响规律,以工程现场揭露的红黏土为充填介质,制作含节理爆破模型,开展不同厚度节理爆破模型试验,并对现场试验爆破参数进行优化。研究结果表明:节理充填介质延长了爆炸应力波传播时间并吸收了部分应力波,应力波衰减速率为2.225~4.188 MPa/mm,滞后时间0.1~0.15 μs/mm;节理对不同方向的应力波吸收程度不同,横向应力的衰减速率大于纵向应力的衰减速率,二者均随节理厚度的增加呈线性衰减。爆破参数优化应控制炮孔至节理面的距离、减小装药量,周边孔宜采用空气间隔分段装药。     

深部采场进路开采顶板稳定性分析与支护设计

为降低深部矿体开采中冒顶事故的发生概率,确保井下安全开采,采用Q系统分级法、RMR岩体分类和BQ分级法对矿区岩体进行质量评价,结合块体理论和三维有限元分析进路开挖后顶板的稳定性。研究表明:部分岩体在进路开挖后顶板处出现较大拉应力集中,抗拉稳定性降低,极有可能出现冒顶事故。针对这类不稳定岩体,提出永久巷道采用锚喷支护,临时巷道采用锚杆穿带支护;并运用悬吊理论、组合梁理论、屈服强度理论和安全系数法分析支护条件下进路顶板的稳定性,优化支护结构参数。通过振弦式锚杆应力计收集现场未支护巷道与支护巷道轴向力,得出该支护设计对开挖后岩体变形起到了明显改善作用。     

采煤工作面回风巷瓦斯气团漂移现象初探

了解瓦斯气体在采掘空间的分布及运移规律,是有效开展煤矿瓦斯治理工作的基础。通过对井下瓦斯浓度监测数据可视化及数理分析,揭示了回采工作面回风流中存在瓦斯气团的可能性,表明了回风巷中瓦斯气体运移具有风流携带气团漂移的特点;回风巷中的同一瓦斯气团先后经过相邻2个传感器时,2个传感器分别观测到的瓦斯浓度变化的曲线形态具有相似性,根据这一特点,给出了回风巷瓦斯气团漂移速度计算公式和应用实例。研究成果有助于优化采煤工作面通风设计,有效监测回风巷中瓦斯气体运移状态,避免高浓度瓦斯气团导致的矿井灾害。     

Development of in-house ELISA for detection of chloramphenicol in bovine milk with subsequent confirmatory analysis by LC-MS/MS

This study was undertaken to develop and validate direct competitive ELISA for the determination of chloramphenicol residues in bovine milk. Antisera and an enzyme-tracer for chloramphenicol were prepared and used to develop an ELISA with inhibition concentrations, IC₂₀ and IC₅₀, of 0.09 and 0.44 ng mL^?1, respectively. Milk samples were spiked with standards equivalent to 0, 0.2, 0.3, 0.5, 1.0 &; 1.5 ng mL^?1 and extracted in methanol. The mean recoveries were found to be 73–100% with coefficient of variance 7–11%. The decision limit (CCα) and detection capability (CCβ) were calculated as 0.10 and 0.12 ng mL^?1, respectively. The results were found comparable with the commercial ELISA, having recoveries of 87 to 100%, CCα 0.09 ng mL^?1 and CCβ 0.12 ng mL^?1. As per Commission Decision 2002/657/EC, in-house ELISA was further validated by using LC-MS/MS. Mass spectral acquisition was done by using electrospray ionization in the negative ion mode applying single reaction monitoring of the diagnostic transition reaction for CAP (m/z 152, 194 and 257). The calibration curve showed good linearity in concentrations from 0.025 to 1.6 ng mL^?1 with correction coefficient 0.9902. The mean recoveries were found to be 88 to 100%. The CCα was calculated as 0.057 ng mL^?1 and CCβ 0.10 ng mL^?1. Since CCα and CCβ are less than half of the MRPL (0.15 ng mL^?1), the test was found suitable for screening and quantification of CAP residues in bovine milk samples. Results of surveillance studies indicated that out of 31 analyzed milk samples, 12.9% samples were found with CAP residues but only 3.2% samples were declared positive with maximum concentration 0.31 ng mL^?1, slightly above the MRPL.     

油田高含盐污水雾化蒸发的数值模拟

基于FLUENT软件,对油田高含盐污水的雾化蒸发过程进行了数值模拟,得到了逆流型雾化蒸发塔内的流场分布特性,对比分析了不同操作参数对蒸发效果的影响。结果表明:液滴蒸发速率沿塔体中心轴线自上而下呈加快趋势;进口空气流速与温度是影响液滴蒸发的关键操作参数,提高流速及温度均可加快液滴的蒸发速率;当进口空气流速达到0.4 m/s后,对蒸发速率的影响减弱;当进口空气温度达到313 K后,对蒸发速率的提高作用不大;喷雾锥角的变化对蒸发速率影响不明显;液滴越细化,蒸发速率越快。     

Decreasing the knowledge gap among different socioeconomic status groups on the issue of climate change

Climate change is causing severe negative consequences to small low-lying islands. To mitigate and adapt to climate change, it is important to improve public knowledge on its causes and consequences. As a social issue that needs collective action to address, the knowledge gap among different segments of population would be a barrier to people’s behaviors toward mitigation and adaption to climate change. This study aims to investigate public knowledge acquisition of climate change by revisiting the knowledge gap hypothesis. A nationally representative random computer-assisted telephone interview survey (N?=?1093) was conducted in Singapore. Quantitative analyses revealed that both newspaper reading and television viewing could reduce the knowledge gap between high and low socioeconomic status individuals. We recommend that governments and relevant authorities should utilize mass media to disseminate information and cultivate public understanding of climate change.     

象山港经济贝类中有机氯农药和多氯联苯的残留水平及其变化趋势

对分布于象山港海域的经济贝类中有机氯农药和多氯联苯的含量用气相色谱方法进行测定,结果显示:HCHS为(2.26~12.65)×10-9,DDTS为(7.32~27.25)×10-9,PCBs(13.54~22.57)×10-9;经济贝类中的有机氯农药的组分特征为HCHs中-βHCH占优势,DDTs中DDD和DDE占绝对优势;2001年至2003年HCHs、PCBs含量总体呈微弱下降趋势,而DDTs含量在2003年明显上升;各海区缢蛏中HCHs、DDTs、PCBs残留量均呈西店(港底)<西周(港中)<西泽(港口)。     

基于GIS的城市特大火灾蔓延模拟

本文将对城市特大火灾的蔓延机理进行深入剖析,并构建火灾蔓延的半经验半理论模型。该模型包括两个子模型,其一为个体建筑火灾发展的简化模型,其二为建筑物间的火灾蔓延模型。前者简化了个体建筑内部火灾发展与蔓延的复杂过程,仅简单评价了个体建筑火灾发展所处的阶段,即起火、轰燃、充分发展与倒塌,并计算出各阶段相应的物理量。后者则是从建筑物间火灾蔓延的机理入手,借鉴已有模型对两种主要的火灾蔓延方式热辐射与热对流进行模型的简化和修正,并且量化了影响建筑物间火灾蔓延的气象条件。最后,作者提供了基于GIS的城市特大火灾蔓延模拟方案,并将模拟方案用于对日本1995年阪神地震后神户市高桥医院周边一处起火进行火灾蔓延模拟,再将模拟结果与实际火灾蔓延结果进行对比,从对比中充分体现出模型的有效性。     

Effects of leachant temperature and pH on leachability of metals from fly ash. A case study: Can thermal power plant, province of Canakkale, Turkey

Lignite powered electric generation plants result in increasing environmental problems associated with gaseous emissions and the disposal of ash residues. Especially, low quality coals with high ash content cause enormous quantities of both gaseous and solid fly ash emissions. The main problem is related to the disposal of fly ash, which, in many cases, contains heavy metals. It is known that toxic trace metals may leach when fly ash is in contact with water. In this study, fly ash samples obtained from the thermal power plant in the town of Can in Turkey were investigated for leachability of metals under different acidic and temperature conditions. The experimental results show that a decrease in pH of the leachant favors the extraction of metal ions from fly ash. A significant increase in the extraction of arsenic, cadmium, chromium, zinc, lead, mercury, and selenium ions from the ash is attributed to the instability of the mineral phases. These heavy metals concentrations increase with respect to increasing acidic conditions and temperature. Peak concentrations, in general, were found at around 30°C.