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941.
UPLC-线性离子阱串联质谱法测定水中新烟碱类杀虫剂 总被引:1,自引:0,他引:1
水样经离心后,采用直接进样超高效液相色谱线性离子阱串联质谱法快速测定水中9种新烟碱类杀虫剂.试验表明,该方法在20.0 ng/L~200 ng/L范围内线性良好,方法检出限为2.9 ng/L~8.4 ng/L,实际水样的加标回收率为81.2% ~109%,测定6次结果的RSD为4.1% ~13.9%,基质效应不明显.将... 相似文献
942.
为研究节理厚度对爆炸应力波传播影响规律,以工程现场揭露的红黏土为充填介质,制作含节理爆破模型,开展不同厚度节理爆破模型试验,并对现场试验爆破参数进行优化。研究结果表明:节理充填介质延长了爆炸应力波传播时间并吸收了部分应力波,应力波衰减速率为2.225~4.188 MPa/mm,滞后时间0.1~0.15 μs/mm;节理对不同方向的应力波吸收程度不同,横向应力的衰减速率大于纵向应力的衰减速率,二者均随节理厚度的增加呈线性衰减。爆破参数优化应控制炮孔至节理面的距离、减小装药量,周边孔宜采用空气间隔分段装药。 相似文献
943.
为降低深部矿体开采中冒顶事故的发生概率,确保井下安全开采,采用Q系统分级法、RMR岩体分类和BQ分级法对矿区岩体进行质量评价,结合块体理论和三维有限元分析进路开挖后顶板的稳定性。研究表明:部分岩体在进路开挖后顶板处出现较大拉应力集中,抗拉稳定性降低,极有可能出现冒顶事故。针对这类不稳定岩体,提出永久巷道采用锚喷支护,临时巷道采用锚杆穿带支护;并运用悬吊理论、组合梁理论、屈服强度理论和安全系数法分析支护条件下进路顶板的稳定性,优化支护结构参数。通过振弦式锚杆应力计收集现场未支护巷道与支护巷道轴向力,得出该支护设计对开挖后岩体变形起到了明显改善作用。 相似文献
944.
了解瓦斯气体在采掘空间的分布及运移规律,是有效开展煤矿瓦斯治理工作的基础。通过对井下瓦斯浓度监测数据可视化及数理分析,揭示了回采工作面回风流中存在瓦斯气团的可能性,表明了回风巷中瓦斯气体运移具有风流携带气团漂移的特点;回风巷中的同一瓦斯气团先后经过相邻2个传感器时,2个传感器分别观测到的瓦斯浓度变化的曲线形态具有相似性,根据这一特点,给出了回风巷瓦斯气团漂移速度计算公式和应用实例。研究成果有助于优化采煤工作面通风设计,有效监测回风巷中瓦斯气体运移状态,避免高浓度瓦斯气团导致的矿井灾害。 相似文献
945.
Muhammad I. Chughtai Uzma Maqbool Mazhar Iqbal Muhammad S. Shah Terence Fodey 《Journal of environmental science and health. Part. B》2017,52(12):871-879
This study was undertaken to develop and validate direct competitive ELISA for the determination of chloramphenicol residues in bovine milk. Antisera and an enzyme-tracer for chloramphenicol were prepared and used to develop an ELISA with inhibition concentrations, IC20 and IC50, of 0.09 and 0.44 ng mL?1, respectively. Milk samples were spiked with standards equivalent to 0, 0.2, 0.3, 0.5, 1.0 &; 1.5 ng mL?1 and extracted in methanol. The mean recoveries were found to be 73–100% with coefficient of variance 7–11%. The decision limit (CCα) and detection capability (CCβ) were calculated as 0.10 and 0.12 ng mL?1, respectively. The results were found comparable with the commercial ELISA, having recoveries of 87 to 100%, CCα 0.09 ng mL?1 and CCβ 0.12 ng mL?1. As per Commission Decision 2002/657/EC, in-house ELISA was further validated by using LC-MS/MS. Mass spectral acquisition was done by using electrospray ionization in the negative ion mode applying single reaction monitoring of the diagnostic transition reaction for CAP (m/z 152, 194 and 257). The calibration curve showed good linearity in concentrations from 0.025 to 1.6 ng mL?1 with correction coefficient 0.9902. The mean recoveries were found to be 88 to 100%. The CCα was calculated as 0.057 ng mL?1 and CCβ 0.10 ng mL?1. Since CCα and CCβ are less than half of the MRPL (0.15 ng mL?1), the test was found suitable for screening and quantification of CAP residues in bovine milk samples. Results of surveillance studies indicated that out of 31 analyzed milk samples, 12.9% samples were found with CAP residues but only 3.2% samples were declared positive with maximum concentration 0.31 ng mL?1, slightly above the MRPL. 相似文献
946.
On the Role of Spatial,Temporal, and Climatic Forces on Stream Sediment Loading from Rural and Urban Ecosystems
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Audrey L. Squires Jan Boll Erin S. Brooks 《Journal of the American Water Resources Association》2017,53(5):1195-1211
In this study, we characterize the greatest sediment loading events by their sediment delivery behavior; dominant climate, watershed, and antecedent conditions; and their seasonal distribution for rural and urban land uses. The study area is Paradise Creek Watershed, a mixed land use watershed in northern Idaho dominated by saturation excess processes in the upstream rural area and infiltration excess in the downstream urban area. We analyzed 12 years of continuous streamflow, precipitation, and watershed data at two monitoring stations. We identified 137 sediment loading events in the upstream rural section of the watershed and 191 events in the downstream urban section. During the majority of these events conditions were transport limited and the sediment flush occurred early in the event, generally in the first 20% of elapsed event time. Statistical analysis including two dozen explanatory variables showed peak discharge, event duration, and antecedent baseflow explained most of the variation in event sediment load at both stations and for the watershed as a whole (R2 = 0.73‐0.78). In the rural area, saturated soils combined with spring snowmelt in March led to the greatest loading events. The urban area load contribution peaked in January, which could be a re‐suspension of streambed sediments from the previous water year. Throughout the study period, one event contributed, on average, 33% of the annual sediment load but only accounted for 2% of the time in a year. 相似文献
947.
基于FLUENT软件,对油田高含盐污水的雾化蒸发过程进行了数值模拟,得到了逆流型雾化蒸发塔内的流场分布特性,对比分析了不同操作参数对蒸发效果的影响。结果表明:液滴蒸发速率沿塔体中心轴线自上而下呈加快趋势;进口空气流速与温度是影响液滴蒸发的关键操作参数,提高流速及温度均可加快液滴的蒸发速率;当进口空气流速达到0.4 m/s后,对蒸发速率的影响减弱;当进口空气温度达到313 K后,对蒸发速率的提高作用不大;喷雾锥角的变化对蒸发速率影响不明显;液滴越细化,蒸发速率越快。 相似文献
948.
Climate change is causing severe negative consequences to small low-lying islands. To mitigate and adapt to climate change, it is important to improve public knowledge on its causes and consequences. As a social issue that needs collective action to address, the knowledge gap among different segments of population would be a barrier to people’s behaviors toward mitigation and adaption to climate change. This study aims to investigate public knowledge acquisition of climate change by revisiting the knowledge gap hypothesis. A nationally representative random computer-assisted telephone interview survey (N?=?1093) was conducted in Singapore. Quantitative analyses revealed that both newspaper reading and television viewing could reduce the knowledge gap between high and low socioeconomic status individuals. We recommend that governments and relevant authorities should utilize mass media to disseminate information and cultivate public understanding of climate change. 相似文献
949.
基于GIS的城市特大火灾蔓延模拟 总被引:2,自引:0,他引:2
本文将对城市特大火灾的蔓延机理进行深入剖析,并构建火灾蔓延的半经验半理论模型。该模型包括两个子模型,其一为个体建筑火灾发展的简化模型,其二为建筑物间的火灾蔓延模型。前者简化了个体建筑内部火灾发展与蔓延的复杂过程,仅简单评价了个体建筑火灾发展所处的阶段,即起火、轰燃、充分发展与倒塌,并计算出各阶段相应的物理量。后者则是从建筑物间火灾蔓延的机理入手,借鉴已有模型对两种主要的火灾蔓延方式热辐射与热对流进行模型的简化和修正,并且量化了影响建筑物间火灾蔓延的气象条件。最后,作者提供了基于GIS的城市特大火灾蔓延模拟方案,并将模拟方案用于对日本1995年阪神地震后神户市高桥医院周边一处起火进行火灾蔓延模拟,再将模拟结果与实际火灾蔓延结果进行对比,从对比中充分体现出模型的有效性。 相似文献
950.