基于可疑筛查技术研究有机磷阻燃剂V6转化规律

运用Orbitrap高分辨质谱仪,评估了人体肝微粒体(HLM)代谢V6的转化规律.除5种已被报道过的O-脱烷基、氧化性去磷酸化和氧化脱氯产物外,首次发现了6种新型产物.基于其MS/MS质谱图,该6种代谢产物被鉴定为醛基和羧基产物.其中,5种代谢物生成量随孵育时间呈线性增加趋势,具有累积性.此外,推导的代谢途径表明,脱烷基化和羟基化代谢物进一步转化为次级代谢物,即醛和羧基代谢物.     

多种复合材料固定化反应器的对比研究

选用活性炭、海砺壳2种材料作为固定化载体,对改良型UASB系统去除COD的性能进行研究,结果表明选择既高柱又循环且增加载体填充体积的系统,可有效去除高浓度有机废水的COD,但当填充载体过高时,循环系统难以实现,并存在憋气的可能。     

甲基一六O五降解菌J5的分离及其降解性状研究

从农药厂污水处理系统中分离到 1株降解甲基一六O五 (O ,O-二甲基 -O- 对硝基苯基 -硫代磷酸酯 ,简称MP)的芽胞杆菌 ,初步鉴定为蜡状芽胞杆菌 (Bacilluscereus)J5。J5能够高效降解MP ,但它不能利用MP作为唯一碳源生长 ,其代谢方式可能为共代谢。在有葡萄糖作为碳源的条件下 ,J5可以高效转化MP ,其转化效率可达 95 %以上。用薄层层析、紫外扫描和液相色谱法初步研究了J5对MP的降解性能及相关降解产物     

Metabolic fate of dichloromethyl‐0,0‐diphenyl phosphonate (I) and dichloromethyl‐0,0‐di‐(p‐nitrophenyl) phosphonate (II) in/on rice plants∗

Abstract

Metabolic fate of two dichloromethyl diaryl phosphonates (³²P labelled) in/on rice plants was investigated. The test compounds were found to be less persistent on the surface of rice leaves with half lives 7.4 and 6.7 days respectively. Main degradation product from both the phosphonates were dichloromethyl phosphonic acid with trace of dichloromethyl‐O‐aryl phosphonate as a transitory intermediate product.     

Magnetic resonance spectroscopy of the fetal brain

Fetal magnetic resonance spectroscopy (MRS) is technically feasible in utero and demonstrates similar findings to those observed in neonatal populations. MRS can provide additional information to conventional T1- and T2-weighted imaging of the fetal brain. It is of particular use when subtle changes are present on conventional fetal MRI sequences, and when imaging fetuses at risk of brain injury and metabolic abnormalities. Copyright © 2009 John Wiley & Sons, Ltd.     

Energy metabolism and growth of Monoporeia affinis Lindstr. in the Northern Lake Krivoe (Karelia)

The physiological method for estimating production based on the relationship between growth and energy metabolism has been used for calculating model growth curves for the amphipod Monoporeia affinis and comparing them with the results of field studies. Calculations demonstrated that the physiological growth curves fit the results of field observations best under certain conditions which have zoological sense: the growth curve should reflect the actual maximum body size of an animal in the given population, the duration of the life cycle, and the time required for reaching the reproductive size.     

城市废物的回收处理与利用

当前世界各国均面临着“废弃物”所造成的环境污染问题。本文列举了一些国家“废弃物”的排放以及回收利用情况,并举例说明对变废为宝的技术路线和应该采取的措施。     

上海市经济-环境系统的物质输入分析

对区域或城市经济-环境系统的物质输入分析。可以判断可持续发展所处的状态。进而为区域或城市制定循环经济发展战略提供依据。利用物质流的理论和方法．依据欧盟指导原则，分析了1990—2003年间上海市经济-环境系统的物质总需求和资源生产率等主要指标。研究结果表明：①上海市巨大的物质总需求和直接物质消耗给上海市的生态环境带来了巨大的压力；②1996年上海市的资源生产率是全国的1．22倍．但2000年日本的资源生产率是上海市的36倍；③影响上海市的物质总需求或者环境质量的关键因素是技术和制度能力。在上述的分析基础上。提出在2020年之前上海市发展循环经济要注重于输入端的减物质化和加强循环绍济的技术支撑研究与开发以及制度能力建设。     

Shellac-coated iron oxide nanoparticles for removal of cadmium(II) ions from aqueous solution

This study describes a new effective adsorbent for cadmium removal from aqueous solution synthesized by coating a shellac layer, a natural biodegradable and renewable resin with abundant hydroxyl and carboxylic groups, on the surface of iron oxide magnetic nanoparticles. Transmission Electron Microscopy (TEM) imaging showed shellac-coated magnetic nanoparticle (SCMN) adsorbents had a core-shell structure with a core of 20 nm and shell of 5 nm. Fourier Transform Infrared Spectroscopic analysis suggested the occurrence of reaction between carboxyl groups on the SCMN adsorbent surface and cadmium ions in aqueous solution. Kinetic data were well described by pseudo second-order model and adsorption isotherms were fitted with both Langmuir and Freundlich models with maximum adsorption capacity of 18.80 mg/g. SCMN adsorbents provided a favorable adsorption capacity under high salinity conditions, and cadmium could easily be desorbed using mild organic acid solutions at low concentration.     

粉煤灰基质滤料生物过滤处理生活污水研究

将粉煤灰基质滤料用于曝气生物滤池,该滤料具有较高的比表面积和孔隙率,吸附性能良好,挂膜后生物相丰富。对于中等浓度的生活污水,当水力负荷和COD有机物负荷分别控制在1.53 m3/(m2.h)、3.68 kg/(m3.d)以下时,该曝气生物滤池COD和NH3-N去除率能稳定在85%以上,出水COD和NH3-N达到排放标准要求。该曝气生物滤池对进水水质水量的变动具有较强的抗冲击负荷能力。