Synthesis and biodegradation of poly(γ-butyrolactone-co-l-lactide)

Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.¹H and¹³C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×10⁴. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT _m andT _g values of the copolymers showed a gradual depression with an increase in BL content. NoT _m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers.     

黄山风景区物质容量研究

系统地分析了旅游区物质容量与其子容量之间的关系,根据黄山区风景区客流空间负荷特点,认为北海游览区是黄山风景区物质容量的“瓶照”最低水桶板原则,合理计算了黄山风景区物质容量;详细探讨了扩大黄山风景区物质容量的若干途径。     

自然降尘与常规气象因子的相关分析

笔者整理统计了１９９２年至１９９４年逐月自然降水和与之相应的常规气象因子监测数据，找到了自然降尘的季节性分布规律。在此基础上，求得了自然降尘分别与月平均气温、月平均气压、月平均风速、月平均温度、月降水量、月蒸发量的相关系数，并进行了检验，为污染预报工作提供了科学依据。     

伊犁地区矿泉水中无机成分分析

通过对伊犁地区部分矿泉水水质分析,展示了该地区矿泉水中微量元素含量及其分布的特点,为今后开发和利用水地区的矿泉资源提供了一定的科学依据.     

Enzymatic degradation of poly([R,S] β-hydroxybutyrate)

The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity.     

乡镇环境保护的“角直模式”

本文分析了江苏省角直镇乡镇经济腾飞与环境保护协调同步的发展过程,总结出了“统一规划、合理布局、集中控制、全面管理、环境保护与经济建设协调发展”的“角直模式”,并就模式的优缺点作了一定程度的探讨.     

磷肥厂烘干磨高压静电除尘技术及应用

本文根据高压静电除尘的原理,磷肥厂烘干磨粉尘的特性分析,以及作者本人的工作实践,探讨了高压静电除尘技术在磷肥厂烘干磨粉尘治理中应用的可行性。     

多目标灰色关联度决策模型分析

本文针对多目标决策的复杂性,运用灰色系统分析方法和物元分析理论,建立了决策方案的评价体系并对评价指标进行规范化处理。以决策方案的灰色关联度作为评判准则,建立了一种目标灰色关联度决策模型。     

西昌地区野生藜蒿资源的开发利用

作者根据对四川省西昌地区野生藜蒿资源的调查研究。论述了野生藜蒿的生物学特征，分布、开发利用价值，繁殖特性和经济效益，并提出了开发利用野生藜蒿资源的建议。     

Climate Convention Implementation: An Opportunity for the Pacific Island Nations to Move Toward Sustainable Energy Systems

This article does not focus on adaptation or mitigation policy directly but on an allied opportunity that exists for the Pacific Islands via the auspices of the Climate Convention, because the existing very costly energy systems used in the Pacific Island region are fossil-fuel dependent. It is argued here that efforts can be made towards the development of energy systems that are ecologically sustainable because Pacific Island nations are eligible to receive assistance to introduce renewable energy technology and pursue energy conservation via implementation mechanisms of the Climate Convention and, in particular, through transfer of technology and via joint implementation. It is contended that assistance in the form of finance, technology, and human resource development from developed countries and international organizations would provide sustainable benefits in improving the local Pacific Island environments. It is also emphasized that mitigation of greenhouse gas emissions is not the responsibility of the Pacific Islands as they contribute very little on a per capita global scale and a tiny proportion of total global greenhouse gas emissions.