Improved performance of a biomaterial-based cation exchanger for the adsorption of uranium(VI) from water and nuclear industry wastewater

The amine-modified polyhydroxyethylmethacrylate (poly(HEMA))-grafted biomaterial (tamarind fruit shell, TFS) carrying carboxyl functional groups at the chain end (PGTFS-COOH) was prepared and used as an adsorbent for the removal of uranium(VI) from water and nuclear industry wastewater. FTIR spectral analysis revealed that U(VI) ions and PGTFS-COOH formed a chelate complex. The adsorption process was relatively fast, requiring only 120 min to attain equilibrium. The adsorption kinetic data were best described by the pseudo-second-order equation. The equilibrium adsorption data were correlated with the Sips isotherm model. The maximum U(VI) ions uptake with PGTFS-COOH was estimated to be 100.79 mg/g. The complete removal of 10 mg/L U(VI) from simulated nuclear industry wastewater was achieved by 3.5 g/L PGTFS-COOH. The reusability of the adsorbent was demonstrated over 4 cycles using NaCl (1.0 M) + HCl (0.5 M) solution mixture to de-extract the U(VI). The results show that the PGTFS-COOH tested is very promising for the recovery of U(VI) from water and wastewater.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

Rain‐washing of foliar deposits of Dimilin®WP‐25 formulated in four different carrier liquids

Abstract

Dimilin^® WP‐25, a wettable powder formulation of diflubenzuron (DFB) [1‐(4‐chlorophenyl)‐3‐(2,6‐difluorobenzoyl) urea], was formulated in four different carrier liquids, viz., water; a light petroleum paraffinic oil, ID 585; a heavy paraffinic oil, Sunspray^® 7N; and a 1:2 mixture of a light petroleum aromatic solvent (Cyclosol^® 63) and canola oil; to provide four end‐use mixtures, Dim‐W, Dim‐585, Dim‐7N and Dim‐Cy‐C respectively, each containing 28 g of DFB per litre. Balsam fir branch tips clipped from greenhouse‐grown seedlings, and sugar maple branch tips clipped from field‐grown young trees, were exposed to uniform‐sized droplets (ranging in diameters from 135 to 190 μm) of the four end‐use mixtures which were atomized using a monodispersed droplet generator. Droplets were collected on the fir and maple branch tips and the initial residue per g fresh weight of foliage was determined by high‐performance liquid chromatography (HPLC). The branch tips were exposed to cumulative rainfall of 3, 6 and 10 mm at an intensity of 5 mm/h and at time intervals of 1, 12, 36 and 72 h after DFB treatment, to test the influence of ‘ageing’ of foliar residues on rainfastness. Foliar samples were collected for residue determination just before the onset of rainfall, and at 0.5 h post‐rain. DFB was quantified by the HPLC method. In the case of fir foliage, the Dim‐W formulation was the most susceptible to rain‐washing and the rainfastness did not increase with the ageing period of foliar deposits. In contrast, the three oil‐based mixtures showed greater rainfastness depending upon the carrier liquid and the ageing period. Rainfastness decreased in the order of Dim‐Cy‐C > Dim‐7N > Dim‐585 > Dim‐W. In contrast, the data on maple foliage indicated that the ageing of deposits increased the rainfastness of all the 4 end‐use mixtures. Dim‐585 was the most susceptible to rain washing, and rainfastness decreased in the order of Dim‐W > Dim‐Cy‐C > Dim‐7N > Dim‐585.     

Modeling the impacts of calcite precipitation on the epilimnion of an ultraoligotrophic, hard-water lake

A mass-balance model of calcite precipitation was developed to investigate the interactions of the varied processes governing the generation and fate of calcite in lakes. The model was used in conjunction with data to assess the evolution and impact of calcite precipitation for calcareous, ultraoligotrophic Torch Lake, Michigan (USA). This lake is an ideal setting for implementation of a baseline modeling study of calcite precipitation where the physical drivers could be evaluated without being dominated, as in many systems, by biological processes. The model provides a representation of calcite precipitation with particulate surface area changing over time, and demonstrates that it is possible for the change in water clarity to be explained by calcite precipitation employing standard optical models. Using the mass balance model to quantify the roles of the various chemical, biological and physical processes interacting in the lake's epilimnion, it was shown that the seasonal temperature rise and air-water CO₂ exchange drive calcite precipitation much more than primary production for this ultraoligotrophic system.     

祁连山北坡自然恢复杨桦林地植物功能型组成及其影响因素

依据生活型(乔木、藤本、灌木、半灌木、多年生禾草、多年生杂类草和一二年生草本)和水分生态型(旱生、旱中生、中生和湿生)将祁连山北坡次生杨桦林28个调查样地中的81个物种划分为18种植物功能型(Plant functiontypes,PFTs),并通过典范对应分析(CCA)方法研究植物功能型与环境因子间的关系.结果表明:自然恢复杨桦林地植物功能型主要集中在中生多年生杂类草(PFTs16)、湿生多年生杂类草(PFTs23)、旱中生多年生杂类草(PFTs9)和中生灌木(PFTs18)4个植物功能型上;乔、灌、草三层冠层特征和中生植物的大量出现,反映了群落植物生活型趋于复杂化和结构化,生态型逐渐向中生化方向演替的特点;土壤容重、有机碳和全氮含量主要影响植物的生活型分异特征,土壤含水量和林冠郁闭度是植物的水分生态型分异的主要环境因子,而坡位、坡度控制着群落植物总体分布格局的形成.图1表3参31     

Municipal solid waste management: Identification and analysis of engineering indexes representing demand and costs generated in virtuous Italian communities

The definition and utilisation of engineering indexes in the field of Municipal Solid Waste Management (MSWM) is an issue of interest for technicians and scientists, which is widely discussed in literature. Specifically, the availability of consolidated engineering indexes is useful when new waste collection services are designed, along with when their performance is evaluated after a warm-up period. However, most published works in the field of MSWM complete their study with an analysis of isolated case studies. Conversely, decision makers require tools for information collection and exchange in order to trace the trends of these engineering indexes in large experiments. In this paper, common engineering indexes are presented and their values analysed in virtuous Italian communities, with the aim of contributing to the creation of a useful database whose data could be used during experiments, by indicating examples of MSWM demand profiles and the costs required to manage them.     

CHANGING RAINFALL-RUNOFF RELATIONSHIPS IN THE URBANIZING PEACHTREE CREEK WATERSHED,ATLANTA, GEORGIA1

ABSTRACT: Peachtree Creek is a gaged watershed that has experienced a substantial increase in urbanization. The relationships of runoff to rainfall were studied for total annual flows, low flows, and peak flows. For each type of flow the relationship in the later, more urbanized period was compared to that in the earlier, less urbanized period. An increase in total runoff in wet years was observed as urbanization increased, but a decrease occurred during dry years. For low flows a similar decrease of runoff in dry years was found. An increase in peak runoff was observed over most of the range of precipitation. Increasing peak flows and declining low flows can be adequately explained by urban hydrologic theoryshed. which focuses on the effects of urban impervious surfaces upon direct runoff and infiltration. However, a decline of total runoff in dry years can be explained only by taking into account evapotranspiration as well. The concept of advectively assisted urban evapotranspiration, previously discovered by climatologists, is needed to explain such a loss of total runoff. Urban hydrologic theory must take into account vegetation and evapotranspiration, as well as impervious surfaces and their direct runoff, to explain the magnitude of total annual flows and low flows. Urban stormwater management should address the restoration of low flows, as well as the control of floods.     

IS IT REALISTIC TO DEFINE A 100-YEAR DROUGHT FOR WATER MANAGEMENT?1

ABSTRACT: The concept of recurrence interval has been used for years in engineering designs. Can the same concept be applied to the drought analysis? This paper uses the plotting position method to define drought of various recurrence intervals based on stream-flow data. The method of truncation level was applied to the same data to examine the defined drought. Based on the method of truncation level, drought duration and its corresponding flow deficit were investigated. Eighteen flow gage stations from the Scioto River Basin in Ohio were selected for the study. The results show that flows of 100-year droughts using the plotting position method are practically nil. On the other hand, flows of droughts using the truncation method are gradually decreasing with an increase in truncation level, where flows of 95 percent are approximately equal to those of two-year droughts defined by the plotting position. It is also shown that there is a strung correlation between drought duration and deficit.     

Long-term depletion of calcium and other nutrients in eastern US forests

Both harvest removal and leaching losses can deplete nutrient capital in forests, but their combined long-term effects have not been assessed previously. We estimated changes in total soil and biomass N, Ca, K, Mg, and P over 120 years from published data for a spruce-fir site in Maine, two northern hardwood sites in New Hampshire, central hardwood sites in Connecticut and Tennessee, and a loblolly pine site in Tennessee. For N, atmospheric inputs counterbalance the outputs, and there is little long-term change on most sites. For K, Mg, and P, the total pool may decrease by 2%–10% in 120 years depending on site and harvest intensity. For Ca, net leaching loss is 4–16 kg/ha/yr in mature forests, and whole-tree harvest removes 200–1100 kg/ha. Such leaching loss and harvest removal could reduce total soil and biomass Ca by 20%–60% in only 120 years. We estimated unmeasured Ca inputs from rock breakdown, root-zone deepening, and dry deposition; these should not be expected to make up the Ca deficit. Acid precipitation may be the cause of current high leaching of Ca. Although Ca deficiency does not generally occur now in acid forest soils, it seems likely if anthropogenic leaching and intensive harvest removal continue.     

The world agricultural system and ethical considerations relating to the rural environment: Some perspectives on cause and effect in underdeveloped countries

Food is a basic human need and therefore a basic human right. While food output has increased to a level where there is enough food produced to feed the world, still millions starve. Using the concept of capitalist world economy as a framework, this paper provides a structural analysis of the food production and distribution system within monopoly capitalism and its implications for countries of the underdeveloped world. Focusing on the impact of a dominant world food supply system on indigenous systems (particularly through the rise of science, technology, and monopoly capital), considerations relating to environmental use and food production and distribution are raised. Finally a call is made for a new agricultural ethic.