星用热缩套管力学性能钴源辐照效应研究

目的研究星用热缩套管的力学性能(断裂伸长率和拉伸强度)在空间辐射环境中的退化情况。方法利用钴源放射的γ射线模拟地球轨道粒子辐照环境,通过表面形貌分析、辐解气体分析、X射线光电子能谱分析、红外光谱分析等多种手段分析热缩套管力学性能退化的原因。结果辐照后热缩套管颜色变深,力学参数出现严重退化现象。在最大辐照剂量下,材料断裂伸长率由414.3%下降为0.06%,拉伸强度由17.43 MPa下降为2.15 MPa,热缩套管原有力学性能几乎完全丧失。结论热缩套管主链出现断链现象,生成可挥发的CO2,CH4等气体,从而导致样品力学性能严重退化。     

机械活性物质环境条件对产品的影响及对策

介绍了机械活性物质环境条件中的砂尘环境和影响砂尘环境的因素;分析了砂尘环境对产品的主要影响,如造成产品冲蚀和磨损,降低电子产品的性能等;最后提出了对砂尘防护的几点对策.通过分析研究,旨在为相关企业提供理论依据和技术参考,便于在产品生产过程中,注意增强产品对环境的适应性,从而提高产品的质量.     

三种厌氧促进剂对亚铵废液厌氧发酵的影响

根据亚铵法草浆蒸煮废液的间歇式厌氧发酵试验结果,分析了活性炭、硫酸亚铁和膨润地亚胺废液厌氧发酵的影响。结果表明,当投量为２．５ｇ／Ｌ时,３４种耨氧促进剂都能显著地促进亚铵废液的厌氧发酵;与对照试验相比,可将厌氧系统的３０ｄ累积产气量分别提高１６．１％、１３．９％和２６．１％。本研究还初步探讨了这３种厌氧促进剂的作用机理。     

固体推进剂老化过程影响因素及化学反应机理研究进展

基于固体推进剂的贮存老化,以NEPE推进剂和以HTPB推进剂为代表,综述了近年来固体推进剂老化进程中所受的各种影响因素、作用机制及化学反应机理研究进展。总结了温湿度、应力和环境气氛为代表的外部环境因素,配方性质、组分变化和添加剂等内部影响因素对推进剂老化及贮存失效期限的影响。分别从微观和宏观角度出发,分析了内外部各种影响因素加速或减缓固体推进剂老化进程的作用机制。此外,针对黏合剂、氧化剂、防老剂等化学组分,总结了固体推进剂贮存老化期间发生的氧化交联、分解、降解断链等主要化学反应,并分析了各个反应发生的机理及原因。最后,展望了未来固体推进剂老化影响因素研究的发展趋势,并为今后固体推进剂老化机理及失效模式研究提供了研究思路。     

国家《大气污染防治行动计划》健康效益评估

为了提高空气质量改善进程,2013 年国家发布了《大气污染防治行动计划》。本文基于空气污染与健康效益评估模型(BenMAP),对人口分布资料、大气污染与人体健康影响的暴露反应关系等进行了本土化修正,采用“支付意愿法”与“疾病成本法”相结合的方法,系统评估了《大气污染防治行动计划》实施后,PM_2.5 污染变化引起的环境健康效益。研究结果表明,《大气污染防治行动计划》的实施将在一定程度上降低PM_2.5 环境浓度,改善环境空气质量。如果《大气污染防治行动计划》空气质量目标全面实现,可以避免城镇8.9 万居民的过早死亡,减少12 万人次住院治疗以及941 万人次的门诊和急诊病例,实现的全国健康效益约为867 亿元/ 年,说明了《大气污染防治行动计划》实施的健康有益性。本文对政府部门开展污染损失评估及制定环境健康政策具有重要的参考价值。     

新型防突装置对封隔器胶筒力学性能影响研

为了进一步保证封隔器安全坐封,提高封隔器胶筒的力学性能,基于现有成熟技术,设计了一种新型防突装置,分析了不同防突装置材料和结构参数对封隔器胶筒肩部突出、接触应力、Von Mises应力的影响。结果表明:新型封隔器肩部突出距离相比常规封隔器降低了63.35%,使胶筒不易被破坏,延长了胶筒的寿命;对防突装置材料和结构参数进行优选,选择材料为铝合金,距胶筒端面距离H=2.5mm,厚度B=0.5mm的新型防突装置;新型防突装置的设计与应用为封隔器坐封提供了安全保障。     

巴东文家滑坡岩土体物理力学性质分析评价

依据文家滑坡的地质勘查成果,对其滑体、滑带、滑床等岩土体物理力学性质,特别对C、φ值的取定进行了分析评价,力求为滑坡稳定性分析及后期防治工程设计提供科学合理的依据.     

某水电站库首右岸拉裂变形体形成机理研究

某水电站库首右岸存在一个拉裂变形体,低线施工公路从陡峭拉裂变形体山坡下部通过。低线公路开挖完成后路堑边坡发生局部塌滑,于2003年5月在其上部形成浅层滑坡体(1000多方)。结合拉裂变形体的分析和治理工作,在统计分析大量勘探资料的基础上,提出了该拉裂变形体是边坡在自重应力和构造应力的复合应力场下快速却荷引起岩体的浅表生改造,形成如荷松动岩体,后期在低线公路祠室大爆破开挖施工、下部坡体切脚和基雨的影响下形成浅层滑坡体,并逐步向上扩展的形成机理。     

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Mechanical waste-processing methods, which combine crushing and separation processes for the recovery of valuable materials, have been widely applied in waste printed wiring board (PWB) treatment. However, both the high impact toughness and the tensile and flexural strengths of whole PWB with a laminated structure result in great energy consumption and severe abrasion of the cutters during multi-level crushing. In addition, the high temperatures occurring in continual crushing probably cause the decomposition of the polymer matrix. A thermal-crack method using residual steam as the heating medium has been developed to pre-treat waste PWBs. This treatment reduces the mechanical strength in order to improve the recovery rate of valuable materials in subsequent mechanical recycling. The changes of the PWBs’ macro-mechanical properties were studied to evaluate thermal expansion impacts associated with changes in temperature, and the dynamic dislocation micro-structures were observed to identify the fracture mechanism. The results showed that thermal cracking with steam at the temperature of 500 K can effectively attenuate the mechanical properties of waste PWBs, by reducing the impact, tensile and flexural strengths respectively, by 59.2%, 49.3% and 51.4%, compared to untreated PWB. Thermal expansion can also facilitate the separation of copper from glass fiber by reducing peel resistance by 95.4% at 500 K. It was revealed that the flexural fracture was a transverse cracking caused by concentrated stress when the heating temperature was less than 500 K, and shifted to a vertical cracking after exceeding 500 K.     

Determination of types of interactions exhibited by binary mixtures of heavy metals tested against the hermit crab,Clibanarius africanus

Single and joint action toxicity of heavy metal compounds (ZnCO₃, CuSO₄ and CdSO₄) were carried out against the hermit crab, Clibanarius africanus in laboratory bioassays. On the basis of 96?h LC₅₀ values, CuSO₄ (96?h LC₅₀?=?0.03?mM) was found to be the most toxic followed by CdSO₄ and ZnCO₃ (96?h LC₅₀?=?0.24?mM) in decreasing order of toxicity. The evaluation of the metal compounds in mixtures of ZnCO₃–CuSO₄, ZnCO₃–CdSO₄ and CdSO₄–CuSO₄ in pre-defined molar ratios revealed that interactions between Zn–Cu and Zn–Cd test mixtures were in conformity with the models of antagonism (reduction in toxicity of constituent metals). The synergistic ratios (S.R.s) and relationship between observed/predicted 96?h LC₅₀ values (relative toxic unit, RTU) were consistently below 1, indicating antagonistic interactions. Analysis using isobolograms also indicated the interactions between the mixture components to be antagonistic. However, with regards to CdSO₄–CuSO₄ test mixtures, the interactions between these metals were mainly in conformity with the model of synergism. The S.R. and RTU values were largely above 1, indicating synergistic interactions. The importance of the joint action evaluations for the management and protection of aquatic ecosystems, particularly in the setting up of water quality criteria was discussed.