首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5391篇
  免费   397篇
  国内免费   1986篇
安全科学   117篇
废物处理   204篇
环保管理   765篇
综合类   3632篇
基础理论   2074篇
环境理论   3篇
污染及防治   412篇
评价与监测   282篇
社会与环境   175篇
灾害及防治   110篇
  2024年   5篇
  2023年   27篇
  2022年   74篇
  2021年   53篇
  2020年   40篇
  2019年   45篇
  2018年   48篇
  2017年   56篇
  2016年   43篇
  2015年   63篇
  2014年   111篇
  2013年   304篇
  2012年   254篇
  2011年   136篇
  2010年   131篇
  2009年   144篇
  2008年   118篇
  2007年   285篇
  2006年   298篇
  2005年   240篇
  2004年   186篇
  2003年   220篇
  2002年   281篇
  2001年   296篇
  2000年   443篇
  1999年   512篇
  1998年   397篇
  1997年   398篇
  1996年   489篇
  1995年   400篇
  1994年   357篇
  1993年   251篇
  1992年   173篇
  1991年   210篇
  1990年   133篇
  1989年   95篇
  1988年   64篇
  1987年   65篇
  1986年   33篇
  1985年   33篇
  1984年   73篇
  1983年   53篇
  1982年   26篇
  1981年   5篇
  1980年   9篇
  1979年   5篇
  1977年   7篇
  1976年   27篇
  1975年   33篇
  1974年   11篇
排序方式: 共有7774条查询结果,搜索用时 781 毫秒
571.
合成制备了铝铁锡共聚物,测定分析了其水解共聚合和熟化过程中的pH变化,并通过扫描电镜和混凝实验对共聚物的晶形貌像和絮凝作用进行了研究。结果表明:Sn^4 具有比Fe^3 ,Al^3 更强的水解活性,它有使共聚物的分子趋于均一的作用;铝铁锡共聚物的最佳配比为:NAl∶NFe∶NSn=5∶5∶3,最佳水解度B^*=2.0,此共聚物具有比CPAFC更优良的絮凝性能。  相似文献   
572.
二氧化氯对有机染料脱色效果的研究   总被引:9,自引:0,他引:9  
本文对二氧化氯二两种直接染料和两种活性染料脱色效果的影响因素-ClO2的投加量、染料的初始浓度、pH值、温度以及反应时间等进行了研究。结果表明,在适当的条件下,二氧化氯对这几种有机染料均具有很好的脱色效果。  相似文献   
573.
强化混凝去除微污染原水胶体颗粒的研究   总被引:4,自引:0,他引:4  
周勤  肖锦  黄耀熊 《环境化学》2001,20(4):374-377
对珠江水系统进行了强化混凝处理,燕利用准弹性激光散射技术(PCS)对常规混凝和强化混凝前后水中胶体颗粒(小于0.45um)的大小与分布进行了测定,探讨了搅拌条件对混凝效果的影响。  相似文献   
574.
对硝基苯酚在沉积物上的吸附特性1   总被引:3,自引:0,他引:3  
朱利中  杨坤 《环境化学》2001,20(5):449-454
研究了沉积物吸附对硝基苯酚的作用机理及影响因素.结果表明,对硝基苯酚在沉积物上的吸附由其中的有机质含量和结构决定,体系的pH值对对硝基苯酚的吸附有较大的影响,其主要原因是体系的pH值控制着沉积物中有机质的溶出量.在实验浓度范围内,分配作用在沉积物吸附对硝基苯酚中占主导地位.  相似文献   
575.
苯蒸气在有机膨润土上的吸附动力学   总被引:4,自引:0,他引:4  
本文研究了苯蒸气在溴化十六烷基三甲基胺(CTMAB)系列单阳离子有机膨润土上的吸附动力学过程。结果表明,苯蒸气在有机膨润土上的吸附符合一级动力学方程,即:r=KvCo;在12h内,吸附反应均可达到平衡,吸附速率常数(Kv)与温度(T)成正相关,吸附反应的活化能在9.50-17.92kJ.mol^-1之间。  相似文献   
576.
Lignoid chemical defenses in the freshwater macrophyte Saururus cernuus   总被引:3,自引:0,他引:3  
Summary. Chemical defense against herbivores has rarely been investigated for freshwater plants, possibly due to the common misconception that herbivory on aquatic macrophytes is low and would not select for chemical defenses. In previous work, the freshwater angiosperm Saururus cernuus was shown to be a low preference food for omnivorous crayfish despite its high nutrient value and relatively soft texture. We used feeding by the crayfish Procambarus clarkii to guide fractionation of the deterrent lipid-soluble extract of this plant, leading to the identification of seven deterrent lignoid metabolites, (–)-licarin A, (+)-saucernetin, (–)-dihydroguaiaretic acid, (–)-sauriols A and B, (–)-saucerneol, and (–)-saucerneol methyl ether. Lignans have been implicated in terrestrial plant chemical defenses as insect growth inhibitors, insect toxins, nematocides, antibacterial, and antifungal agents. However, these activities have rarely been demonstrated using ecologically relevant methodologies in terrestrial systems, and never before in freshwater systems. The widespread nature of lignans amongst very distantly related plants, along with their rich diversity of molecular structure, suggests that they could play a large role in mediating plant-herbivore interactions. In addition to the lignoid compounds we identified, there were other compounds present in low concentration or unstable compounds that were deterrent, that did not appear to be lignans, but that we were unable to identify. This plant thus appears to be defended by a complex mixture of natural products. Received 6 June 2000; revised 23 August 2000; accepted 2 September 2000  相似文献   
577.
Summary. Metrius contractus, a primitive paussoid bombardier beetle, emits its defensive quinonoid froth with accompanying sound (a faint “hiss”), but the sound is not pulsed, indicating that the secretory emission itself is not pulsed. Pulsed secretory delivery in bombardier beetles appears to occur in Brachinini only. Received 8 July 2001; accepted 23 July 2001.  相似文献   
578.
Summary. Benzoic acid is a known stimulant of olfactory receptor cells in trichoid sensilla on the antennae of adult females of Bombyx mori. Exposure of freshly excised antennae, from B. mori females and males, to vapours of [14C]-benzoic acid revealed that the adsorbed acid is rapidly metabolized (15% conversion in 10 s), suggesting the presence of a highly active enzymatic system. The major product could be identified as N-benzoylserine by use of [2H5]-benzoic acid, and mass spectrometry linked to a gas chromatograph (GC-MS) or a liquid chromatograph (LC-MS), for analysis of the metabolites. The conjugation of benzoic acid with an amino acid apparently represents a novel mode for the rapid deactivation of odorant molecules. Received 26 March 2001.  相似文献   
579.
During the 1990s a consensus emerged within the international humanitarian system that there was a need to enhance the 'coherence' between humanitarian and political responses to complex political emergencies. Closer integration between aid and political responses was seen to be necessary in order to address the root causes of conflict-induced crises, and to ensure that aid did not exacerbate political tensions. This paper explores the theory and practice of coherence over the past decade. It argues that, by sleight of hand, the coherence agenda has been reinterpreted such that humanitarian action has become the primary form of political action, rather than merely a substitute for it. The coherence agenda has been driven by geopolitical events, domestic policy considerations in donor countries and the more parochial concerns of aid policy, and is reflected in a number of substantive changes in the humanitarian architecture. Many of the tenets of this 'new humanitarianism' have been embraced by the majority of relief agencies, and thus legitimised it. The paper concludes that political humanitarianism, as opposed to active engagement by political and military actors, is flawed ethically and technically. It will provide neither an effective palliative for the ill effects of war, nor address its causes.  相似文献   
580.
贵州省煤中挥发性和半挥发性微量元素分布规律的初步研究   总被引:25,自引:0,他引:25  
冯新斌  倪建宇 《环境化学》1998,17(2):148-153
研究了贵州省四大煤田不同层位、不同煤种中Hg,As,Se,Pb,Cd,Tl,Zn,Sb等挥发性和半挥发性微量元素的分布规律。贵州省原煤中Hg,As,Se,Pb,Cd,Sb等元素的含量高于地壳克拉克值;Tl,Zn等的含量低于地壳克拉克值;另外,除了Pb,Zn外,贵州省原煤中Hg,As,Se,Cd的含量远远高于东北和内蒙古东部地区。微量元素聚类分析结果表明,Hg,As,Sb可能主要分布于煤的黄铁矿中;Zn和Se可能主要赋存于闪锌矿中;Cd可能部分存在于硫化物中,部分存在于硅酸盐矿物相中;Pb可能主要存在于硅酸盐矿物相中;而Tl在煤中的赋存形式较复杂。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号