印刷线路板厂含铜污泥固化处理工艺研究

研究采用水泥作固化基材固化处理某印刷线路板厂酸性废水用石灰混凝所产生的含铜、锡、金的污泥 ,对固化块在不同 pH的水中重金属Cu2 +的浸出实验结果表明 :水泥固化处理该混凝污泥效果良好 ,控制合适的条件 ,可得到混合性能好、初凝时间适当、抗压强度较好的固化块。Cu2 +的浸出率低于允许浸出浓度。混凝过程中加入硫脲硅酸钠等助剂 ,可提高固化效果。研究还对几种不同配比的固化块抗压强度进行了探讨。     

紫外—双氧水和亚铁离子体系对硝基苯光降解的研究

研究了以５００Ｗ直管高压汞灯为光源，在双氧水和亚铁离子的体系中，对硝基苯进行光降解的可能性。结果表明，在实验条件下，本系统对硝基苯有明显的降解效果。浓度为５０ｍｇ／Ｌ的硝基苯经过６０ｍｉｎ的光照，其降解率可达９１．７％。此外，还探讨 铁离子浓度、双氧水浓度、硝基苯浓度、ｐＨ值等因素对光降解的影响。     

金属板料成形摩擦机理研究

对不锈钢板料和碳钢在金属塑性成形时 (高接触压力 )的摩擦机理进行了实验研究 ,分析了压力对滑动阻力和摩擦系数的影响 ,得出了随压力增大摩擦系数逐渐变小的结论 ,从而为应用有限元法进行板料成形过程中塑性变形的计算机模拟提供真实的边界条件打下了基础。     

废旧锂离子电池回收利用的研究现状

目前废旧锂离子电池的回收利用，重点是电极材料中有价金属的回收，主要是应用酸浸和溶剂萃取相联合的湿法冶金技术，其次将电化学技术用于浸出液中金属的沉积和对失效电极材料的直接修复也有相关的研究报导。根据锂离子电池的发展和未来的环境要求，今后的回收利用将朝综合处理和多元化处理技术的方向发展。     

冶金污泥稳定化/固化处理工艺研究

冶金工业在生产过程中产生大量酸性废水.对这类废水目前通常采用石灰中和沉淀处理.文章中通过研究采用水泥和工业废渣作固化基材固化处理冶金工业酸性废水用石灰混凝所产生的含铜、砷的污泥,分析了影响固化块抗压强度的多种因素,采用固体废物浸出毒性浸出方法对浸出率进行实验探讨.     

Promotional effect of cobalt doping on catalytic performance of cryptomelane-type manganese oxide in toluene oxidation

The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H₂-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T_90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOF_Co) being 245°C, 1.23 × 10⁻³ mol_toluene/(g_cat·sec), and 11.58 × 10⁻³ sec⁻¹ for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO₂, SO₂ or NH₃, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O₂ and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H₂O and CO₂.     

中山市金属回收企业绿色供应链绩效评价研究

废旧金属资源的回收是循环经济的重要组成部分,进一步加强废旧金属回收行业的管理,对于保证资源永续、减少环境污染、节省能源、提高经济效益具有重要的意义。当前的竞争环境使金属回收企业和政府主管部门急需通过金属回收企业绿色供应链绩效评价,了解企业的绿色供应链管理状况,以适应越来越激烈的市场竞争。因而建立一个金属回收企业绿色供应链绩效评价模型不仅对绿色供应链的实践具有指导意义,而且还能对金属回收企业绿色供应链的绩效作出评价,改善其绿色供应链管理。     

重金属在淀山湖沉积物上的吸附研究

本文以淀山湖沉积物作为研究对象 ,研究了 Cu、Zn、Pb和 Cd在淀山湖沉积物上的等温吸附和沉积物对重金属吸附的影响因素。结果表明 ,重金属 Cu、Zn、Pb和 Cd在淀山湖沉积物上的等温吸附符合 L angmuir模型 ,淀山湖沉积物对重金属饱和吸附量的大小顺序为 Zn>Cu>Pb>Cd。淀山湖沉积物的组成对重金属吸附有较大的影响 ,其中沉积物中粘粒对 Cu、Zn、Pb和 Cd的吸附最强。沉积物中有机质对 4种重金属也有较强的吸附 ,特别对 Zn的吸附最强。碳酸盐对 Zn的吸附较弱 ,而对 Cu、Pb和 Cd有较强的吸附。 p H值对重金属吸附也有较大的影响 ,吸附量随着 p H值的升高而增大。温度对吸附的影响则较小     

长江铜陵段表层水中重金属含量及存在形态分布研究

通过测定长江铜陵段枯、丰水期江水中cu、Pb、Zn和cd不同形态的含量,分析了4种金属在江水中的存在形态分布,不同水期含量变化,水中悬浮物对金属吸附能力大小,以及近20年来含量的变化情况。结果表明,长江铜陵段江水中各重金属总量丰水期时大于枯水期,重金属各形态含量之间均有差异:丰水期时,各金属会被悬浮物以不同的方式携带进入水体中,cu、zn、Pb以活跃态和稳定态为主,Cd以活跃态为主;枯水期时,Zn主要以溶解态和稳定态为主,Pb以稳定态方式被携带,而80％的Cu、Cd是以溶解态形式存于水中。悬浮物(丰水期)对重金属的吸附能力大小顺序为Pb>Cu>Zn>Cd。与近20年江水中的重金属背景值比较,长江铜陵段重金属含量有普遍升高的趋势。     

Chemical Composition and Acidity of Rain at the Gulf of Iskenderun,North-East Mediterranean

The purpose of the present work was to investigate the chemistry of rain in the Gulf of Iskenderun, North East Mediterranean, Turkey. The Gulf region has a large number of industries. Main industries existing in the region are iron and steel works, fertilizer plants, a cement plant, and several medium and mini size steel mills in addition to the international pipe line terminals. This study aims to apportion the local sources contributing to the overall pollution of the region. To this end a precipitation sampling program was started in January 2000, and over 48 precipitation samples were collected from each of 5 stations located at Iskenderun city center, Iskenderun industrial zone, Payas city center, the campus of Iskenderun Technical College and the campus of Mustafa Kemal University. Samples were analysed for pH, NO₃ ⁺, Cl^-. Ca, Al, Ba, Na, Cd, Co, Cr, Cu, Pb, Li, Mg, Mn, Ni, Zn, Fe, K. Concentrations of metal ions were determined by ICP-AES. NO₃ ^- ions and pH were determined by using NO₃ ^- selective electrode and pH meter, respectively.pH values of the collected samples at the industrial zone and at Payas city center, ranged between 5.02 and 7.38, respectively. NO₃ ^- and metal ions concentrations were highly variable. Concentrations of Ca and Fe ions were higher in the industrial zone and Payas city center. In the other three stations, concentrations of metal ions and NO₃ ^- ion were lower than that of industrial zone and the values of pH ranged between 6 and 7.4. The average pH values at Iskenderun Gulf showed that the precipitation was not acidic, because of the high concentration of Ca. The highest concentrations of Na and Cl ions were recorded in the University campus because the campus is located by the Mediterranean Sea.