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排序方式: 共有806条查询结果,搜索用时 15 毫秒
1.
Morsheda Akhter Sagar Kumar Dutta Palash Kumar Dhar Jamil Ahmed Mohammed Nazrul Islam Khan Md. Khairul Amin Jahidul Islam 《环境质量管理》2023,32(4):149-160
Catalytic activity of spinel ferrite in breaking down toxic dye materials are promising due to their uniqueness. In this study, aluminum-doped copper zinc ferrite, Cu0.4Zn0.6-xAlxFe2O4 (x = 0.0, 0.2, 0.4, 0.6), a catalyst for toxic dye degradation is synthesized through chemical co-precipitation route. The formation of the spinel ferrite catalyst is initially confirmed by Fourier transform infrared spectra, which shows the frequency of metal-oxygen bond vibration at 539 and 427 cm−1 attributed to the tetrahedral and octahedral sites respectively. Higher intensity sharp peak of X-ray diffraction for (311) plane is the evidence for the phase purity and the formation of spinel ferrite. The crystallite size is found to decrease with the increase of Al3+ ion. The surface structure of the obtained particles is investigated using a scanning electron microscope. Analyses of the material's magnetic characteristics using a vibrating sample magnetometer (VSM) revealed that it is, in fact, a soft magnet, as evidenced by the loop of its hysteresis, which is narrow. The catalytic degradation of methylene blue dye under the mechanism of the photo-Fenton process is studied with the obtained spinel ferrites and the result is found to be as high as 96.5%. The process follows pseudo-second order kinetics and the Langmuir isotherm. 相似文献
2.
Effluent from dyeing and finishing processes is an important source of water pollution. The effectiveness of bentonite, kaolinite and sediment from a local deposit in removing methylene blue as a cationic dye from aqueous solutions has been investigated. The adsorption equilibrium (isotherm) has been determined according to Freundlich and Langmuir equations. The optimum amount is 0.5 g for all adsorbents, and the optimum pH ranges are 2-8 for bentonite and 2-6 for kaolinite and sediment. With respect to kinetic modelling, the adsorption of methylene blue on various adsorbents was fitted to a second-order equation. Also, the thermodynamic parameters were determined. The negative free energy values indicate the feasibility of the process and spontaneous nature of adsorption. The positive ΔH° values indicate the endothermic nature of the process. Thus, Egyptian clay minerals and sediments have a great tendency to remove the dye from solutions. 相似文献
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采用微波辐射技术,通过接枝共聚反应制备了阿拉伯胶(GA)-g-2-丙烯酰胺-2-甲基丙磺酸(AMPS)/丙烯酸(AA)/海泡石黏土(ST)(GA-g-PAMPS/AA/ST)复合水凝胶,利用FTIR、XRD、SEM对复合水凝胶进行了表征,研究了水凝胶对水溶液中亚甲基蓝(MB)染料的吸附性能.结果显示:GA、ST和AA与AMPS发生了接枝共聚反应,形成具有均匀三维网络结构的复合水凝胶.0.025g水凝胶可以使体积为50mL、pH值为6.4、浓度为600mg/L的MB溶液的吸附量和吸附率分别达1146mg/g和95.5%,水凝胶具有较好的重复利用性能.Freundlich等温模型和准二级动力学模型能更好地描述吸附过程.热力学研究表明水凝胶对亚甲基蓝吸附是自发、吸热和不可逆的过程.该水凝胶可用作阳离子染料和阳离子型污染物的潜在候选生物质吸附剂. 相似文献
4.
本文研究了钴(Ⅱ)催化过氧化氢氧化苯基荧光酮的褪色反应,测定了反应级数和表观活化能,建立了测定痕量地的新方法。25℃时本法检出限为29×10-13g/ml,线性范围为0.04~2ng/10ml,催化反应表观活化能为56.15KJ/mol。该方法己用于维生素B12、人发和茶叶中痕量钴的测定.结果满意,相对标准偏差为2.4~3.4%。 相似文献
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研究了表面活性剂(乳化剂OP)存在下,铁、邻菲罗啉、曙红的显色反应.该离子缔合物的最大吸收波长为545 nm,摩尔吸光系数为9.4×104 L·mol-1·cm-1,铁含量在0-0.4 mg/L内符合比耳定律.以自来水为基体进行铁的回收实验,回收率在99%以上. 相似文献
7.
对铜的 3条谱线 (2 49.2 nm、2 61 .4nm,3 2 4.8nm ) ,铅的 2条谱线 (2 83 .3 nm、2 1 7.0 1 nm )以及锌的 2条谱线(3 0 7.6nm、2 1 3 .9nm ) ,共 7条谱线的灵敏度、检测限、线性范围进行了归纳性总结 ,并对多种共存元素可能存在的干扰情况进行了研究 ,认为利用元素不同分析谱线的分析灵敏度差异 ,根据被测元素在样品消解液中含量 ,选择合适的谱线进行分析 ,既降低工作强度 ,又能获得满意结果 相似文献
8.
Toral MI Beattie A Santibañez C Richter P 《Environmental monitoring and assessment》2002,76(3):263-274
A first derivative spectrophotometric method has been developedfor the determination of parathion and p-nitrophenol in vegetabletissues. Ethanol was used as solvent for extracting the compoundsfrom the tissues and subsequently the samples were evaluated against a vegetable tissue blank, directly by derivative spectrophotometry. The simultaneous determination of these compounds can be carried out using the zero-crossing approach for parathion at 253.0 nm and for p-nitrophenol at 273.1 nm. In the samples each analyte was determined in the presence of one another in the ranges between 4.9 to 3883.5 g g-1 forparathion and 4.9 to 3285.3 g g-1 for p-nitrophenol.The detection limits (3) were found to be 1.5 and 1.4 g g-1 for parathion and p-nitrophenol, respectively. The relative standard deviations were in all instances less than1.8%. The proposed method was applied to the determination ofthe analytes in spiked leafs of corn. The results show a goodrecovery and they are in agreement with those obtained bypolarography. 相似文献
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