中国红色粘土型金矿成矿特征

中国的红色粘土型金矿是 90年代初发现并开始研究的 ,基本上产于南方特别是西南地区。由于特殊的地质构造条件和气候、地貌条件 ,该类型金矿与国外的红土型金矿存在明显的差异 :红色粘土型金矿剖面发育差 ,红土化程度低 ;对源岩依存度高 ;铁铝含量低、硅含量高 ;矿石处在富粘土矿物阶段 ,少见三水铝石 ,一般为伊利石和高岭石共存。金在红色粘土中以微细粒分散形式存在 ,且在红色粘土剖面中由于表生淋滤作用而发生活化、迁移和再沉淀。     

赣东北地区的成矿环境与成矿作用

本文剖析了赣东北地区的三维地质结构，概述了该区的地质构造演化与主要成矿事件和金属矿床成矿系列。指出区内存在前震旦纪的富幔质岩壳，对区内的隆（起）坳（陷）成矿差异、德兴矿集区燕山期岩浆－成矿时序及德兴铜矿田定位等提出了若干认识。     

我国建筑装饰材料的发展趋势

本文以现代的新型建筑装饰材料和人们未来的发展需要为依据，论述未来我国建筑装饰材料发展的趋势。     

宁蒗地区铜厂河铜矿控矿条件与热液成矿模式探讨

宁蒗地区铜厂河铜矿系喜山期隐伏斑岩体外接触带玄武岩系热液型铜矿床 ,其主要含矿、赋矿层位为上二叠统玄武岩组 (P2 β)与黑泥哨组 (P2h)玄武岩系 ,主干控矿构造为南北向断裂体系。矿区NWW向F1断裂为阻矿构造 ,铜矿化均产于其下盘 (南盘 ) ;NE向F2 、F3 断裂将本区分成三个不同矿化特征的矿段。通过对矿区铜矿的碳、氧、硫等稳定同位素和包裹体分析及成矿热液演化特征探讨 ,建立了铜厂河铜矿热液成矿模式     

氯乙酰胺类除草剂微生物降解研究进展

主要介绍了几种氯乙酰胺类除草剂的微生物降解机制和相关降解酶．目前没有一种纯菌培养物或混合菌群能完全矿化异丙甲草胺和甲草胺，它们只能被细菌和真菌共代谢．毒草胺能被纯菌或混合菌群完全矿化，且有几种不同的矿化途径．乙草胺是我国生产量和使用量最多的三大除草剂之一，然而关于其微生物降解方面的研究在国内外报道的非常少，因此关于乙草胺被微生物降解和矿化的研究工作还有待于进一步加强．参45     

Ferrioxalate-mediated photodegradation and mineralization of 4-Chlorophenol

INTENTION, GOAL, SCOPE, BACKGROUND: Advanced oxidation processes are powerful methods which are capable of transforming refractory, nonbiodegradable and/or toxic organic compounds into harmless end products such as carbon dioxide and water. However, one commen problem of all advanced oxidation processes is the high demand of electrical energy for ultraviolet lamps, which causes high operational costs. Minimization of the required irradiation time, and therefore the energy consumption, by optimization of other reaction conditions such as catalyst-oxidant type and concentration, pH, temperature, pollutant/oxidant ratio etc., therefore continues to gain importance. OBJECTIVE: The main objective of this study was the minimization of the required irradiation time through optimization of the use of a newly patented catalyst, ferrioxalate, and also to compare the performance of this catalyst with the performance of other AOPs. METHODS: Oxidation of 4-chlorophenol by photo-Fenton process using potassium ferrioxalate as a mediator was studied in a lab scale photoreactor. The influence of parameters such as hydrogen peroxide and ferrioxalate concentrations, initial pH, power-output, oxalate/iron ratio and different iron sources was evaluated. An upflow photoreactor equipped with a 1000 Watt high-pressure mercury vapour lamp and operating in a recirculation mode was used during photodegradation experiments. The extent of the reduction of 4-chlorophenol, Total Organic Carbon and Chemical Oxygen Demand was used to evaluate the photodegradation reaction. RESULTS AND DISCUSSION: The optimum pH range observed was found to be 2.7-3. The efficiency of 4-chlorophenol oxidation increased with increasing concentrations of hydrogen peroxide and ferrioxalate, reaching a plateau after the addition of 10 and 0.072 mM of those reagents, respectively. Using an Oxalate/iron ratio of 12 was 18% less efficient than using a ratio of 3:1. The efficiency increased with increasing radiation power. However, this increase was not linear. The UV/ferrioxalate/H2O2 process, by which complete mineralization of 100 mg l(-1) 4-chlorophenol was achieved in 20 min of total reaction time, was the most efficient process among the alternatives applied. CONCLUSIONS: The use of ferrioxalate as the catalyst was found to be more efficient than the use of Fe(II) and Fe(III) iron species. It was possible to completely mineralize 4-chlorophenol. RECOMMENDATION AND OUTLOOK: The results of this study demonstrate that the ferrioxalate-mediated degradation of 4-chlorophenol requires less irradiation times than other advanced oxidation processes. There are mainly 19 phenol isomers and other toxic and nonbiodegradable organic compounds. We recommend that similar studies should be performed on many such compounds in order to attain a clear understanding of the performance of this catalyst. Because of its light sensitivity, this catalyst should be used immediately after its preparation. The use of low pressure mercury vapour lamps in this process should also be considered, since low power outputs may be enough for the process.     

汉江干流水质现状与变化趋势分析

对汉江干流水质现状进行了分析评价并探讨了主要监测指标的变化趋势。指出汉江水质以 、 类为主,总体较好,襄樊白家湾以上河段的水质明显好于下游河段,水质相对较差的断面主要是城镇控制断面。汉江主要污染物是总磷。水质在不同水期的变化为:平水期好于丰水期,丰水期好于枯水期。16年间,高锰酸盐指数和氨氮分别有37.5%和25%的断面年均值呈上升趋势。     

论永梅会多层、多类型成矿集中区大型铜、金、银、锡矿床成矿远景

近10多年来东南沿海找矿具突破性意义的一批矿床中，有5个各具特色的矿床及与之相类似的一批矿床（点）和矿化层位，集中分布在闽粤赣三省交界处面积约为8万km2的永定一梅县－会昌地区（简称永梅会地区），构成一成矿集中区．其特点是矿床集中且规模大、埋藏浅、多类型和多层性。该区处于不同构造单元的交接、叠置地带，自晋宁期至晚燕山期漫长的地质历史为形成多层、多类型矿床提供了良好的成矿环境；频繁的火山一侵入活动揭示了壳幔分离、地幔物质多次注入、地壳物质多次循环，特别是石炭纪以来（C1、J1、K1）三次双峰式火山活动所反映的位张环境，造就了本区成矿元素多、丰度高的地球化学场和构造应力环境；可能存在的地幔热流柱对地壳的作用是构成矿床集中的深部构造因素；区内石炭系岩相古地理特征显示本区具有与长江中下游地区石炭系铜矿含矿层位相当的合矿层位；本区中等剥蚀程度有利于寻找火山根部带或基底中的矿床。在分析该区上述成矿远景基础上，提出了该区有可能成为我国南方继德兴之后及维长江中下游地区之后的另一个铜、多金属成矿区。     

呼和浩特市地表水水质变化趋势分析

对黄河(过境)、大黑河水系及浑河水系十年水质检测结果进行综合分析,揭示其变化趋势,并针对各河流污染断面提出急需解决的问题.     

Combined effects of two sulfonylurea herbicides on soil microbial biomass and N-mineralization

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