Assessing Spatial, Temporal, and Analytical Variation of Groundwater Chemistry in a Large Nuclear Complex, USA

Statistical analyses were applied at the Hanford Site, USA, to assess groundwater contamination problems that included (1) determining local backgrounds to ascertain whether a facility is affecting the groundwater quality and (2) determining a ‘pre-Hanford' groundwater background to allow formulation of background-based cleanup standards. The primary purpose of this paper is to extend the random effects models for (1) assessing the spatial, temporal, and analytical variability of groundwater background measurements; (2) demonstrating that the usual variance estimate s ², which ignores the variance components, is a biased estimator; (3) providing formulas for calculating the amount of bias; and (4) recommending monitoring strategies to reduce the uncertainty in estimating the average background concentrations. A case study is provided. Results indicate that (1) without considering spatial and temporal variability, there is a high probability of false positives, resulting in unnecessary remediation and/or monitoring expenses; (2) the most effective way to reduce the uncertainty in estimating the average background, and enhance the power of the statistical tests in general, is to increase the number of background wells; and (3) background for a specific constituent should be considered as a statistical distribution, not as a single value or threshold. The methods and the related analysis of variance tables discussed in this paper can be used as diagnostic tools in documenting the extent of inherent spatial and/or temporal variation and to help select an appropriate statistical method for testing purposes.     

铝材Sn-Ni混合盐电解着枪色参数研究

首先对铝片试样进行预处理,随后在恒定的电流密度和相同的氧化时间下,在铝材表面形成厚度均匀的阳极氧化膜,然后采用方波交流电,对铝试样进行电解着色处理,通过改变铝材电解着色工艺的着色时间、电流密度、正负电流比、占空比等因素来研究这些因素与铝材明度值和色差之间的关系。实验结果表明获得枪色的最佳工艺条件是:着色时间6m in左右,着色电流密度为1.40 A/dm2左右,正向电流比负向电流大7%左右,占空比55%左右。     

Reducing the Effects of Dredged Material Levees on Coastal Marsh Function: Sediment Deposition and Nekton Utilization

Dredged material levees in coastal Louisiana are normally associated with pipeline canals or, more frequently, canals dredged through the wetlands to allow access to drilling locations for mineral extraction. The hydrologic impact on marshes behind the levee is of concern to coastal resource managers because of the potential impact on sediment transport and deposition, and the effect on estuarine organism access to valuable nursery habitat. This study examined the effects of gaps in dredged material levees, compared to continuous levees and natural channel banks, on these two aspects of marsh function. Field studies for sediment deposition were conducted biweekly for a year, and nekton samples were collected in spring and fall. Variation in nekton density among study arears and landscape types was great in part because of the inherent sampling gear issues and in part because of differences in characteristics among areas. Nekton densities were generally greater in natural compared to leveed and gapped landscapes. Differences in landscape type did not explain patterns in sediment deposition. The gaps examined appear to be too restrictive of marsh flooding to provide efficient movements of floodwaters onto the marsh during moderate flooding events. The “trapping” effect of the levees increases sediment deposition during extreme events. Gapping material levees may be an effective method of partially restoring upper marsh connection to nekton, but this method may work best in lower elevation marshes where nekton use is greater.     

利用等离子技术治理再生纤维汽车内衬生产过程中的烟气

利用等离子技术,治理树脂聚合法生产再生纤维汽车内饰材料过程中产生的烟气,对等离子净化装置的结构参数、操作参数进行了优化,并对等离子体净化机理进行了分析。利用等离子技术,能够处理常规工艺设备无法治理的极微细可吸入颗粒物和气溶胶烟气;并可同时净化可吸入颗粒物和气态污染物。该设备结构简单、运行费用极低,可在产生烟气的很多行业和领域推广应用。     

某市给水管网中铁释放现象影响因素与控制对策分析

针对某市管网水中铁浓度的变化规律进行了系统的研究,确定了管垢向管网水中释放出的铁是管网水中铁超标的主要原因.研究中发现铸铁管和镀锌钢管中管垢的主要化学组分为铁.在给水管网中,管网水的溶解氧和余氯浓度低时,对应的管网水中铁释放现象严重,其原因是还原条件使管垢表面的致密钝化层被破坏,造成二价铁的大量释放.根据试验结果提出了给水管网中铁释放和“红水”现象的控制对策.     

滇池流域磷循环系统的物质流分析

研究营养元素在社会经济系统中的物质代谢结构及特征,是有效预防和控制地表水体富营养化的关键性分析技术之一.以滇池流域磷循环为研究案例,运用物质流分析方法建立了2000年流域静态物质流模型(PHOSFAD),并在此基础上识别出流域磷循环系统的总体结构特征,以及资源开采、化工生产、农业种植、畜禽养殖、居民生活等生产和消费部门的物质利用效率特征,为科学防治滇池水体富营养化提供了重要决策依据和参考.     

钙法提钒尾渣的浮选脱硫试验

根据钙法提钒尾渣的矿物特性,采用浮选法分离其中的石膏以实现脱硫,分别考察了矿浆pH、矿浆液固比、捕收剂添加量及浮选中水循环次数等因素对浮选指标的影响,并进行了理论分析,确定了钙法提钒尾渣浮选脱硫的优选工艺参数.试验结果表明,在矿浆pH为7、矿浆液固比为5:1、捕收剂添加量为0.6～0.8 kg/t的条件下,可获得w(S...     

Ti3C2纳米层状材料对废水中Cr（Ⅵ）的光催化去除性能

以Ti₃AlC₂为原料,采用HF刻蚀工艺制备出12种Ti₃C₂纳米层状材料,对其形貌进行了表征,并考察了以其作为光催化剂对废水中Cr（Ⅵ）的处理效果。实验结果表明：HF体积分数为80%、刻蚀时间为48 h时得到的MX-80-48的形貌较好;MX-80-48具有类似石墨烯的二维层状结构,纳米层厚度约20~50 nm,孔径2~10 nm,比表面积14.8 m²/g,在400~700 nm可见光范围内表现出强烈的吸光性;当Cr（Ⅵ）的初始质量浓度为40.00 mg/L、MX-80-48投加量为200 mg/L、pH=2、反应时间4 h（暗反应1 h+光照3 h）时,Cr（Ⅵ）去除率可达100%。     

锐钛矿-金红石混合晶型TiO2降解气相苯

用溶胶-凝胶法并通过控制煅烧温度合成不同晶相比的混合晶型纳米TiO_2,在紫外光光照下降解气相苯。考察了苯初始质量浓度、紫外灯光照强度和催化剂加入量对苯去除率的影响;探究了光催化降解气相苯的动力学特征。结果表明:450℃煅烧制备的催化剂降解苯效率最高,此催化剂金红石相质量分数为6.30%;在苯初始质量浓度为74.39 mg/m~3、催化剂加入量为7 g、光照强度为2.18 klux的最佳条件下反应84 min,苯去除率达99.73%;光催化降解率与光照强度之间符合0.5级动力学特征;当催化剂加入量为3 g时,单位时间单位质量催化剂降解苯的质量最多;苯的光催化降解反应均符合一级动力学方程。     

预处理垃圾焚烧飞灰作为碱胶凝材料混合材的研究

试验分析了垃圾焚烧飞灰的主要化学成分及矿物组成,探讨了预处理垃圾焚烧飞灰作为碱胶凝材料混合材的可能性.研究表明,垃圾焚烧飞灰主要由黏土类矿物组成,飞灰直接作为混合材参与水化过程会产生明显膨胀现象,加入30%(质量分数)飞灰制成的矿渣/飞灰试块在成型1 d脱膜时膨胀率达到15.7%,标准养护28 d后无侧压抗压强度只有12.4 MPa.对飞灰进行热活化预处理,900℃条件下活化效果最佳,同样的飞灰掺量下,试块在标准养护28 d后无侧压抗压强度达到46.0 MPa,膨胀现象消失,且碱胶凝材料中重金属稳定性良好.