聚合物驱采出水中聚丙烯酰胺的微生物联合降解作用研究

通过对2株细菌的培养降解实验研究聚丙烯酰胺(hydrolyzed polyacrylamide,HPAM)降解菌对水环境下聚丙烯酰胺的降解作用,讨论协同降解机理。2株降解聚丙烯酰胺的菌株假单胞菌CJ419、枯草芽孢杆菌FA16在初始30℃废水样品上培养,定期测量细菌生物量和HPAM降解率。培养30 d后CJ419和FA16对聚合物的降解率最大值分别达到30.4%和25%,而以1∶1比例的混合菌降解率最大值达到80.3%。对2株菌胞外各组分研究表明:混合菌降解HPAM的机理主要由胞外降解酶系水解聚合物侧链基团导致HPAM降解为小分子物质,同时生长过程中降解菌还会释放非蛋白还原性物质引发氧化反应共同参与HPAM降解。     

多孔镁铝复合氧化物对水溶液中Cr（VI）的吸附性能

摘要以镁盐、铝盐、纯碱和烧碱为原料制备了一种多孔镁铝复合氧化物（P—Mg3.1AlO4.6）,其比表面积、平均孔径和总孔容分别为206．3m2／g、8．961nm和0．4208cm3／g。研究了这种多孑L材料对水溶液中cr（VI）的吸附性能,在25～45qC时,静态吸附量为82．32～141．7mg／g;当初始浓度100mg／L、流速5mL／min、床层高度10cm和pH=6时,半穿透时间、半穿透吸附量和饱和吸附量分别为406rain、49．28ing／g和51．30Ing／g;拟合参数及误差分析表明,cr（Ⅵ）在P—M敬。AIO4.6上的静态吸附过程符合Freundlich等温方程式和伪二级动力学方程,Yoon·Nelson模型能很好地预测cr（Ⅵ）在P—Mg3.1A104.6上的动态穿透曲线。     

堇青石负载Pd和过渡金属氧化物催化剂的表征及其对CO的催化氧化活性

以堇青石蜂窝陶瓷(CC)为载体,采用浸渍法制备了堇青石负载Pd和过渡金属混合氧化物催化剂,记作Pd-M-Mn(M=Cu,Co,Fe,Ni)/CC。实验结果表明:Pd-Co-Mn/CC催化剂的催化活性最高;随着Pd负载量的增加,CO转化率提高;当Pd负载量为1.00%时,反应温度为150℃时CO转化率达到98%,200℃时CO转化率达到100%;在反应温度150℃条件下,Pd-Co-Mn/CC催化剂(Pd负载量1.00%)的CO转化率在前30h内小幅度下降,随后稳定在90%以上,反应100h后,催化剂表面颜色由黑色变为棕褐色。     

A NEW LOOK AT FLOOD RISK DETERMINATION1

ABSTRACT: The probability distributions of annual peak flows used in flood risk analysis quantify the risk that a design flood will be exceeded. But the parameters of these distributions are themselves to a degree uncertain and this uncertainty increases the risk that the flood protection provided will in fact prove to be inadequate. The increase in flood risk due to parameter uncertainty is small when a fairly long record of data is available and the annual flood peaks are serially independent, which is the standard assumption in flood frequency analysis. But standard tests for serial independence are insensitive to the type of grouping of high and low values in a time series, which is measured by the Hurst coefficient. This grouping increases the parameter uncertainty considerably. A study of 49 annual peak flow series for Canadian rivers shows that many have a high Hurst coefficient. The corresponding increase in flood risk due to parameter uncertainty is shown to be substantial even for rivers with a long record, and therefore should not be neglected. The paper presents a method of rationally combining parameter uncertainty due to serial correlation, and the stochastic variability of peak flows in a single risk assessment. In addition, a relatively simple time series model that is capable of reproducing the observed serial correlation of flood peaks is presented.     

COUPLING OF NONPARAMETRIC FREQUENCY AND L-MOMENT ANALYSES FOR MIXED DISTRIBUTION IDENTIFICATION 1

ABSTRACT: Both L-moment and nonparametric frequency analyses were performed on a series of annual maximum floods from New Brunswick, Canada. The L-moment analysis concluded that the data were generated from a unimodal Generalized Extreme Value (GEV) distribution. However, the nonparametric frequency analysis indicated that a majority of stations followed nonunimodal mixed distributions since peak flows occur during different seasons and are the result of different generating mechanisms. The coupling of L-moment and nonparametric analyses facilitates mixed distribution identification. Thus, the nonparametric method helps in identifying underlying probability distribution, especially when samples arise from mixed distributions.     

利用城市生活垃圾制取有机复合肥

用城市生活垃圾经好氧高温制成堆肥,并向其中加入无机化肥和微量元素添加剂可制成有机复合肥。本文简要阐述了好氧高温堆肥的生产工艺,推荐了用垃圾生产有机复合肥的两类配方。     

EMMC process for combined removal of organics, nitrogen and an odor producing substance

In order to improve the process performance regarding the removal of organics, nitrogen, and an odor-causing compound (sulfide) contained in domestic wastewater, an entrapped-mixed-microbial cell (EMMC) with and without humic substances for both fixed and moving carrier reactors and conventional suspended growth culture (i.e. conventional activated sludge process) were investigated simultaneously. Both synthetic (simulated to the organics concentration of general domestic sewage) and actual domestic wastewater were investigated under operational conditions of 12 h of hydraulic retention time (HRT) with 1 h of aeration and 1 h of non-aeration, and 6 h of HRT with continuous aeration, at a room temperature of 25 +/- 2 degrees C. It was found that entrapping humic substances in the EMMC carriers had no impact on the removal of organics, nitrogen, and the odor-producing compound. Additionally, the performance of the EMMC moving carrier system for the removal of these pollutants is similar to that of the EMMC fixed carrier system. In general, the EMMC associated systems which provide high solids retention time achieve a better removal of chemical oxygen demand (COD), nitrogen, and the odor-producing substance than the suspended growth system for both HRTs of 6 h (continuous aeration) and 12 h (1 h of aeration and 1 h of non-aeration). Both the fixed and moving carrier EMMC processes, therefore, have the potential for improvement or replacement of the existing conventional activated sludge process with regard to improving the effluent qualities (such as COD, nitrogen and odor-producing compound) for reuse/disposal.     

碗窑碾压混凝土坝变形成因分析及监控指标的拟定

鉴于碗窑碾压混凝土重力坝个别变形测点测值异常现象,依据大坝变形观测资料,通过变形规律时空分析和统计模型的建立,以及影响因子的分解,合理地解释了其变形成因,从而得出碗窑水库大坝变形性态总体正常的结论。为确保大坝安全运行,通过建立有限元力学模型和混合模型,拟定了典型坝段坝顶水平位移的一级监控指标,进而更有效地监控大坝的安全性态。另外,就个别测点坝段时效有呈逐年缓慢上升的趋势,建议管理单位加强观测,并及时分析,确保工程安全运行。     

Water Network Synthesis Using Mutation-Enhanced Particle Swarm Optimization

Different techniques for the synthesis of industrial water reuse/recycle networks have been developed in recent process integration research. These tools range from graphical pinch analysis approaches to mathematical programming models. The latter have the advantage of being flexible enough to incorporate various water network constraints, but in many cases these are often non-linear, thus making the identification of global optima difficult. Recent work has demonstrated the effectiveness of metaheuristic algorithms such as particle swarm optimization (PSO), for finding good solutions these problems. This work describes the use of a modified PSO for solving mixed integer non-linear programming (MINLP) models for water network synthesis. By incorporating a mutation operator for the binary variables in the model, the algorithm is able to escape sub-optimal network topologies and proceed towards better solutions than can be found with ordinary PSO. Two case studies involving water recycle/reuse are used to demonstrate the new design methodology.     

兼氧混合菌对亚甲基蓝废水生物降解实验研究

采用厦门某生物科技有限公司提供的兼氧混合菌为研究对象,利用相关设备进行中试实验,验证了该项技术的可行性。同时探究了重金属对该混合菌种生物降解能力的影响,通过中试实验研究后发现5mg/L的重铬酸钾和硫酸铜均对该混合菌种的生物降解能力有一定的影响,并且硫酸铜的影响大于重铬酸钾。此外该技术对甲基橙、刚果红废水也有一定的生物降解能力,这为兼氧混合菌用于印染废水处理提供了实验依据。