Nitrate (NO3−) has been the dominant ion of secondary inorganic aerosols (SIAs) in PM2.5 in North China. Tracking the formation mechanisms and sources of particulate nitrate are vital to mitigate air pollution. In this study, PM2.5 samples in winter (January 2020) and in summer (June 2020) were collected in Jiaozuo, China, and water-soluble ions and (δ15N, δ18O)-NO3− were analyzed. The results showed that the increase of NO3− concentrations was the most remarkable with increasing PM2.5 pollution level. δ18O-NO3− values for winter samples (82.7‰ to 103.9‰) were close to calculated δ18O-HNO3 (103‰ ± 0.8‰) values by N2O5 pathway, while δ18O-NO3− values (67.8‰ to 85.7‰) for summer samples were close to calculated δ18O-HNO3 values (61‰ ± 0.8‰) by OH oxidation pathway, suggesting that PM2.5 nitrate is largely from N2O5 pathway in winter, while is largely from OH pathway in summer. Averaged fractional contributions of PN2O5+H2O were 70% and 39% in winter and summer sampling periods, respectively, those of POH were 30% and 61%, respectively. Higher δ15N-NO3− values for winter samples (3.0‰ to 14.4‰) than those for summer samples (-3.7‰ to 8.6‰) might be due to more contributions from coal combustion in winter. Coal combustion (31% ± 9%, 25% ± 9% in winter and summer, respectively) and biomass burning (30% ± 12%, 36% ± 12% in winter and summer, respectively) were the main sources using Bayesian mixing model. These results provided clear evidence of particulate nitrate formation and sources under different PM2.5 levels, and aided in reducing atmospheric nitrate in urban environments. 相似文献
Objective: The probability of crash occurrence on horizontal curves is 1.5 to 4 times higher than that on tangent sections. A majority of these crashes are associated with human errors. Therefore, human behavior in curves needs to be corrected.
Methodology: In this study, 2 different road marking treatments, optical circles and herringbone patterns, were used to influence driver behavior while entering a curve on a 2-lane rural road section. A driving simulator was used to perform the experiment. The simulated road sections are replicas of 2 real road sections in Flanders.
Results: Both treatments were found to reduce speed before entering the curve. However, speed reduction was more gradual when optical circles were used. A herringbone pattern had more influence on lateral position than optical circles by forcing drivers to maintain a safe distance from opposing traffic in the adjacent lane.
Conclusion: The study concluded that among other low-cost speed reduction methods, optical circles are effective tools to reduce speed and increase drivers’ attention. Moreover, a herringbone pattern can be used to reduce crashes on curves, mainly for head-on crashes where the main problem is inappropriate lateral position. 相似文献
The majority of wildfires in the Mediterranean Basin are caused directly or indirectly by human activity. Many biophysical and socioeconomic factors have been used in quantitative analyses of wildfire risk. However, the importance and effects of socioeconomic factors in spatial modelling have been given inadequate attention. In this paper, we use different approaches to spatially model our data to examine the influence of human activity on wildfire ignition in the south west of the Madrid region, central Spain. We examine the utility of choropleth and dasymetric mapping with both Euclidean and functional distance surfaces for two differently defined wildfire seasons. We use a method from Bayesian statistics, the Weights of Evidence model, and produce ten predictive maps of wildfire risk: (1) five maps for a two-month fire season combining datasets of evidence variables and (2) five maps for the four-month fire season using the same dataset combinations. We find that the models produced from a choropleth mapping approach with spatial variables using Euclidian and functional distance surfaces are the best of the ten models. Results indicate that spatial patterns of wildfire ignition are strongly associated with human access to the natural landscape. We suggest the methods and results presented will be useful to optimize wildfire prevention resources in areas where human activity and the urban-forest interface are important factors for wildfire ignition. 相似文献