大巴山区早古生代地层和石煤中硒的化学活动性的初步研究

通过对大巴山区主要分布的早古生代地层中的碎屑岩，碳酸盐岩和石煤的原岩，风化岩，原生土壤的硒含量及其相关关系分析，及对南秦岭早古生代地层和石煤中硒的化学活动性进行了研究。结果表明：其岩石和石煤中的硒在地层环境下有较大的活动性，不同类型岩石中硒淋失率和硒的淋失量不同，富硒而淋失率低但淋失量高的下寒武统鲁家坪组和早志留世大贵坪组的炭质板岩和石煤的分布区土壤（主要为当地岩石的风化残积物）的含硒量可达10mg/kg，甚至更高，是大巴山的富硒带和硒中毒带，含硒低而且淋失率高的志留系砂岩和粉砂岩以及寒武系统砾屑灰岩分布区是大巴山区的低硒带。     

涕灭威等三种农药在土壤中的移动性

涕灭威、呋喃丹和拉索三种农药在土壤中的淋溶结果表明，经过３０ｃｍ土柱下渗到收集器中的涕灭威为８８．０％，呋喃丹为６９．１％，拉索为１．８４％；农药在四种土壤中的淋溶速度，砂土＞砂壤土＞粘壤土＞粘土；土壤性质对农药移动的影响比农药自身性质的影响要小。     

Cross-Hauling of Polluting Factors

This paper analyzes the investment/environment overlap using a two stage model of two jurisdictions. Capital exports are modeled as choice variables for capital owners who weigh income considerations against the effects of capital exports on the quality of their local environments and on environmental policy. This framework reveals that capital owners have an incentive to cross-haul polluting factors across jurisdictions when direct controls are used to regulate emissions and that this cross-hauling induces policymakers to ratchet up environmental policies in both locations. The importance of instrument type and commitment on environmental policy is also analyzed.     

甲基异柳磷等四种农药在土壤薄板上的移动性能

在室内模拟条件下，研究了４种农药在土壤薄板上的移动性能。结果表明，甲基异柳磷与嘧啶氧磷属不易迁移的Ⅱ级农药；克草胺属中等迁移性的Ⅲ级农药；单甲脒属可移动性农药。     

Cyhalofop‐p‐butyl mobility and distribution of residues in soil at various depths

This study was conducted to evaluate cyhalofop‐p‐butyl mobility in a sandy loam soil and subsequent distribution of residues at various depths under field conditions. Soil samples were taken from 0 to 150 cm depths at 3–90 d after rains in lysemeter of 1 and 2 m depths. Cyhalofop‐p‐butyl application at two rates and subsequent precipitation had a significant impact on soil, physico‐chemical properties and herbicide mobility. Precipitation caused substantial mobility of cyhalofop‐p‐butyl in the soil and 1.1–7.6 μg L^?1 of cyhalofop‐p‐butyl was found in leachates. Cyhalofop‐p‐butyl residues in the leachates were probably due to preferential flow through the soil. Cyhalofop‐p‐butyl residues were detected in significant amounts from the soil up to 10 d, later, residues were found below the detection limit but its three transformation products viz., cyhalofop acid, diacid, and phenol were detected.     

Mobility and Methylation of Mercury in Forest Soils Development of an In-Situ Stable Isotope Tracer Technique and Initial Results

A method for investigating in-situmethylation and mobility of mercury has beendeveloped and applied to forest soil. The methodis based on additions of stable ¹⁹⁹Hgisotopes to forest soil plots followed bysampling and analysis of isotope ratios of totalmercury and MeHg using ICP-MS. Initial resultsindicate that a fraction (30%) of the mercuryadded to the forest soils is immobilised over atime scale of 16 months. A small but significantfraction of the mercury is methylated during thesame time scale. Higher methylation rates werefound in wetland soil than in dry forest podzolsoil.     

Use of different organic wastes in reducing the potential leaching of propanil,isoxaben, cadusafos and pencycuron through the soil

In this study, we examined the effect of four different organic wastes (OW)—composted sheep manure (CSM), spent coffee grounds (SCG), composted pine bark (CPB) and coir (CR)—on the potential groundwater pollution of propanil and isoxaben (herbicides), cadusafos (insecticide) and pencycuron (fungicide) under laboratory conditions. For this purpose, leaching studies were conducted using disturbed soil columns filled with a clay loam soil (Hipercalcic calcisol). The addition of organic matter (OM) drastically reduced the movement of the studied pesticides. The results obtained point to the interest in the use of agro-industrial and composted OW in reducing the groundwater pollution by pesticide drainage.     

Antecedents and outcomes of employee perceptions of intra‐organizational mobility channels

Employees' beliefs about how promotions are awarded within their organizations can have important consequences. We conducted two studies that focus on perceptions of the criteria used to make promotion decisions. In Study 1, we identified two types of perceived promotion criteria, performance‐based and nonperformance‐based. Then we use justice and social exchange theories to develop a model linking employee perceptions of promotion criteria to performance via their relationships with promotional justice and organizational commitment. In a sample of 305 employee–supervisor pairs, we found that both promotional justice and organizational commitment mediated between perceptions of promotion criteria and supervisor rated in‐role and extra‐role performance, and that having received a promotion in the past predicted attributions that promotions were based relatively more on performance or nonperformance criteria. Study 2 further examined the role of promotions themselves in the formation of perceptions of promotion criteria. Drawing from image and attribution theories, we hypothesized that the relationship between having received a promotion or not and perceptions of promotion criteria depends on ego defensiveness. In a sample of 145 employees, we found that those who scored high on ego defensiveness and who had not been promoted were especially likely to attribute promotion decisions to nonperformance criteria. Copyright © 2012 John Wiley & Sons, Ltd.     

On the potential of iPhone significant location data to characterize individual mobility for air pollution health studies

● We evaluated the accuracy of iPhone data in capturing time-activity patterns. ● iPhone data captured the most important microenvironments and time spent in them. ● iPhone data also accurately captured daily exposure to ambient PM pollution. ● A considerable fraction of the population in the USA may have iPhone data available. ● iPhone data has great potential in air pollution health studies. In many air pollution health studies, the time-activity pattern of individuals is often ignored largely due to lack of data. However, a better understanding of this location-based information is expected to decrease uncertainties in exposure estimation. Here, we showcase the potential of iPhone’s Significant Location (iSL) data in capturing the user’s historical time-activity patterns in order to estimate exposure to ambient air pollutants. In this study, one subject carried an iPhone in tandem with a reference GPS tracking device for one month. The GPS device recorded locations in 10 second intervals while the iSL recorded the time spent in locations the subject visited frequently. Using GPS data as a reference, we then evaluated the accuracy of iSL data in capturing the subject’s time-activity patterns and time-weighted air pollution concentration within the study time period. We found the iSL data accurately captured the time the subject spent in 16 microenvironments (i.e. locations the subject visited more than once), which was 93% of the time during the study period. The average error of time-weighted aerosol optical depth value, a surrogate of particle pollution, is only 0.012%. To explore the availability of iSL data among iPhone users, an online survey was conducted. Among the 349 surveyed participants, 72% of them have iSL data available. Considering the popularity of iPhones, iSL data may be available for a significant portion of the general population. Our results suggest iSL data have great potential for characterizing historical time-activity patterns to improve air pollution exposure estimation.     

Assessment of Coarse Sediment Mobility in the Black Canyon of the Gunnison River,Colorado

The Gunnison River in the Black Canyon of the Gunnison National Park (BCNP) near Montrose, Colorado is a mixed gravel and bedrock river with ephemeral side tributaries. Flow rates are controlled immediately upstream by a diversion tunnel and three reservoirs. The management of the hydraulic control structures has decreased low-frequency, high-stage flows, which are the dominant geomorphic force in bedrock channel systems. We developed a simple model to estimate the extent of sediment mobilization at a given flow in the BCNP and to evaluate changes in the extent and frequency of sediment mobilization for flow regimes before and after flow regulation in 1966. Our methodology provides a screening process for identifying and prioritizing areas in terms of sediment mobility criteria when more precise systematic field data are unavailable. The model uses the ratio between reach-averaged bed shear stress and critical shear stress to estimate when a particular grain size is mobilized for a given reach. We used aerial photography from 1992, digital elevation models, and field surveys to identify individual reaches and estimate reach-averaged hydraulic geometry. Pebble counts of talus and debris fan deposits were used to estimate regional colluvial grain-size distributions. Our results show that the frequency of flows mobilizing river bank sediment along a majority of the Gunnison River in the BCNP has significantly declined since 1966. The model results correspond well to those obtained from more detailed, site-specific field studies carried out by other investigators. Decreases in the frequency of significant sediment-mobilizing flows were more pronounced for regions within the BCNP where the channel gradient is lower. Implications of these results for management include increased risk of encroachment of vegetation on the active channel and long-term channel narrowing by colluvial deposits. It must be recognized that our methodology represents a screening of regional differences in sediment mobility. More precise estimates of hydraulic and sediment parameters would likely be required for dictating quantitative management objectives within the context of sediment mobility and sensitivity to changes in the flow regime.