The Use of Carbon and Nitrogen Isotopes to Study Watershed Erosion Processes1

Abstract:  Tracer studies are needed to better understand watershed soil erosion and calibrate watershed erosion models. For the first time, stable nitrogen and carbon isotopes (δ¹⁵N and δ¹³C) and the carbon to nitrogen atomic ratio (C/N) natural tracers are used to investigate temporal and spatial variability of erosion processes within a sub‐watershed. Temporal variability was assessed by comparing δ¹⁵N, δ¹³C, and C/N of eroded‐soils from a non‐equilibrium erosion event immediately following freezing and thawing of surface soils with two erosion events characterized by equilibrium conditions with erosion downcutting. Spatial variability was assessed for the equilibrium events by using the δ¹⁵N and δ¹³C signatures of eroded‐soils to measure the fraction of eroded‐soil derived from rill/interrill erosion on upland hillslopes as compared to headcut erosion on floodplains. In order to perform this study, a number of tasks were carried out including: (1) sampling source‐soils from upland hillslopes and floodplains, (2) sampling eroded‐soils with an in situ trap in the stream of the sub‐watershed, (3) isotopic and elemental analysis of the samples using isotope ratio mass spectrometry, (4) fractioning eroded‐soil to its upland rill/interrill and floodplain headcut end‐members using an unmixing model within a Bayesian Markov Chain Monte Carlo framework, and (5) evaluating tracer unmixing model results by comparison with process‐based erosion prediction models for rill/interrill and headcut erosion processes. Results showed that finer soil particles eroded during the non‐equilibrium event were enriched in δ¹⁵N and δ¹³C tracers and depleted in C/N tracer relative to coarser soil particles eroded during the equilibrium events. Correlation of tracer signature with soil particle size was explainable based on known biogeochemical processes. δ¹⁵N and δ¹³C were also able to distinguish between upland rill/interrill erosion and floodplain headcut erosion, which was due to different plant cover at the erosion sources. Results from the tracer unmixing model highlighted future needs for coupling rill/interrill and headcut erosion prediction models.     

SEDIMENT ROUTING FOR AGRICULTURAL WATERSHEDS1

ABSTRACT: A sediment routing technique was developed to route sediment yield from small watersheds through streams and valleys to the outlet of large watersheds. The technique is based on the modified universal sol loss equation and a first order decay function of travel time and particle size. Deposition is dependent upon settling velocities of sediment particles, travel time, and the amount of sediment in suspension. Sediment routing increases sediment yield prediction accuracy and allows determination of subwatershed contributions to the total sediment yield. Also, the locations and amounts of floodplain scour and deposition can be predicted. Another advantage of sediment routing is that measured sediment yield data are not required. The procedure performed satisfactorily in test routings on two Texas blackland watersheds Sediment routing will be useful in flood control evaluation, reservoir and channel design, water quality calculations, environmental impact assessment, and land-use planning.     

THE SUSPENDED SEDIMENT REGIME OF AN OREGON COAST RANGE STREAM1

ABSTRACT: Armored stream segments may affect the suspended sediment regime of small mountain streams in western Oregon by the release of fine sediments stored in the bed gravels. Sieve analysis of bed materials indicated that at least 30 percent of the suspended sediment yield for the 1975–76 winter had been stored in the streambed. Suspended sediment concentrations during storm-generated runoff were influenced by stream discharge and hydrograph characteristics. Sediment-discharge relations for individual storms were characterized by hysteresis loops. A seasonal flushing of fines was shown by a progressive decrease in the ratio of suspended sediment to stream discharge during the winter runoff period.     

RIDGE REGRESSION TECHNIQUES APPLIED TO LANDSAT INVESTIGATION OF WATER QUALITY IN LAKE OKEECHOBEE1

ABSTRACT: Landsat radiance values were processed at two different (single and double) levels of accuracy to estimate chlorophyll a, turbidity, and suspended sediment in Lake Okeechobee, Florida. Both ordinary least square and ridge regression analyses were used to establish a relationship between water quality parameters and Landsat radiance. Radiance measurements made at greater precision (double level) gave a better solution in this application. The ridge regression analysis for double level not only can reduce the total mean square error about 13–20 percent and confidence interval about 6–28 percent as compared to ordinary least square analysis, but it can also change the interpretation of analysis results.     

ESTIMATING THE SUSPENDED SEDIMENT LOAD IN RESERVOIRS1

ABSTRACT: The total suspended sediment loads of four north Mississippi reservoirs were determined from measurements of concentrations of suspended sediment in a vertical profile at several locations on each reservoir made during the year. These data were combined with the stage-height and known stage-volume relationships for each reservoir in a numerical integration to determine the total suspended sediment in the water body. Total suspended sediments were estimated using the product of the suspended sediment concentration in the surface water by the appropriate reservoir volume. The averaged ratios of the estimated to measured suspended sediment loads for each reservoir exceeded 0.90. Since the concentration of suspended sediments in surface waters of north Mississippi reservoirs has been shown as highly correlated with spectral reflectance, estimating the total suspended sediment of these reservoirs using remotely sensed spectral reflectance data is possible.     

FARMERS’ATTITUDES TOWARD GOVERNMENT INVOLVEMENT IN PREVENTING AGRICULTURAL NONPOINT SOURCE WATER POLLUTION1

ABSTRACT: Concern over the pollution of our lakes and streams has become a major issue in the United States. Sedimentation from sigricultural lands has been identified as a significant factor in water pollution. Some citizens suggest that government should force compliance with soil loss standards, while others suggest that we ask farmers to voluntarily comply. Related questions are “DO farmers think government should be involved in controlling erosion and protecting water quality?”“To what extent should government be involved?” What level of government should be involved? Federal? State? Local?“Why should pay for water quality projects?” Farmers from a small watershed in northeastern Indiana were interviewed before and after a major demonstration project. Their responses suggest that farmers feel that individual landowners should be responsible for controlling erosion and agricultural nonpoint source water pollution. However, over 60 percent of the study fanners indicated that the federal government should play an important role, in terms of both technical and financial assistance.     

RESERVOIR SEDIMENTATION1

ABSTRACT: Reservoirs, as well as lakes and estuaries, are subject to sediment accumulation. The rate at which sedimentation occurs is accelerated or diminished by man's activities. Acceptable rates of sedimentation are considered on the basis of costs of sediment storage and removal and a review of reservoirs constructed with sediment removal capabilities is given. The rates of reservoir sedimentation in the United States are summarized based on reliable data obtained from all sizes of reservoirs. Problems confronting the engineer concerning reservoir construction and maintenance are discussed on the basis of these data.     

THE FATE OF NITRATE IN LAKE SEDIMENT COLUMNS1

ABSTRACT: To investigate the magnitude of denitrification and assimilatory nitrate reduction as these reactions relate to the fate of nitrate reaching sediments via groundwater seepage, undisturbed core samples of sediments (40 cm length) from two lakes (Mendota and Tomahawk) were leached from the bottom (at 1.4 cm/day) with a solution of ¹⁵N-nitrate (10 mg N/liter). The sediment columns were fitted with Pt electrodes to measure the oxidation-reduction (Eh) potential. While leaching removed considerable ammonium-N and soluble organic N, essentially no ¹⁵N had passed through the columns by 50 days. The Eh readings indicated that denitrification was occurring in the lower portions of the columns. The ¹⁵N distribution of the sediment N after 50 days showed that about 15 to 26% of the added nitrate-N was converted to organic N and ammonium-N. The data show that denitrification can be a significant N sink in seepage lakes.     

Risk assessment and binding mechanisms of potentially toxic metals in sediments from different water levels in a coastal wetland

The excessive accumulation of potentially toxic metals (Pb and Cd) in coastal wetlands is among the main factors threatening wetland ecosystems. However, the effects of water table depth (WTD) on the risk and binding mechanisms of potentially toxic metals in sediments remain unclear. Here, sediments from different WTD obtained from a typical coastal wetland were evaluated using a newly developed strategy based on chemical extraction methods coupled with high-resolution spectroscopy. Our findings indicated that the WTD of the coastal wetland fluctuates frequently and the average enrichment factor for Pb was categorized as minor, whereas Cd enrichment was categorized as moderate. High-resolution spectroscopy techniques also demonstrated that organic functional groups and partly inorganic compounds (e.g., Fe-O/Si-O) played a vital role in the binding of Pb and Cd to surface sediments. Additionally, mineral components rather than organic groups were mainly bound to these metals in the bottom sediments. Collectively, our findings provide key insights into the potential health effects and binding characteristics of potentially toxic metals in sediments, as well as their dynamic behavior under varying sediment depths at a microscale.     

Metal Concentration in Oyster, Crassostrea Gigas, and Sediment in Ann-Ping Mariculture Ground, Taiwan

This study was to assess the metal contamination in oyster tissue grown in the Ann-ping mariculture ground in Taiwan. the information generated from this work also revealed general metal pollution problem for Taiwan's oyster farmers. Oysters, Crassostrea gigas, and surficial sediments collected from ten locations in Ann-ping mariculture ground in Taiwan for metals concentration (Cu, Zn, Pd, Cd, Fe and Mn) were performed. Analytical results indicated that the yearly averaged oyster copper concentrations (μg g^-1, wet weight) in oyster soft parts from Ann-ping increased from 21.3±4.1 in 1993; 24.1±6.8 in 1994; 36.8±11.9 in 1995 to 43.9±23.1 μg g^-1, wet weight, in the 1996 raising season. the mean oyster copper concentration reached a level of 50 μg g^-1, wet weight, in December 1996. This increasing trend of metal concentration in oyster tissue indicates a potential pollution source which may pose a potential disaster as green oyster incidence, which occurred on the Charting coast in 1986, in Taiwan. Sediment samples in Ann-ping mariculture ground were also collected and examined. the seasonal variation of the copper concentration in surficial sediment from Ann-ping did not show an increasing trend as observed in oyster tissue.