Experimental evaluation of PCDD/Fs and PCBs release and mass balance of a WTE plant

The behaviour of waste incineration plants with respect to organic toxic trace contaminants such as PCDDs, PCDFs and, to a minor extent, PCBs, is still a matter of concern for the public opinion and the decision makers. It is therefore very important, first, to evaluate the release of these organic toxic trace contaminants in the environment during waste incineration, not only through the stack gas emission but also with the solid and liquid residues, and then to compare the total release with the input through the treated waste in order to assess the plant behaviour as a “sink” rather than a “source” of organic toxic trace contaminants. The experimental investigation carried out on an Italian full scale incineration plant has shown a total 17 PCDD/Fs and 12 dioxin-like PCBs release of 5.5-27 μg WHO-TEQ per tonne of treated waste and an input flux of 1.6-44 μg WHO-TEQ per tonne of waste, with the difference between the input and the output fluxes rather small and the plant behaviour toward organic trace toxic contaminants in average neutral. Results are compared with similar evaluations conducted in the last decade on a number of waste-to-energy (WTE) plants operating in Italy.     

Rainfall Runoff Relationships for a Cloud Forest Watershed in Central America: Implications for Water Resource Engineering1

Caballero, Luis A., Alon Rimmer, Zachary M. Easton, and Tammo S. Steenhuis, 2012. Rainfall Runoff Relationships for a Cloud Forest Watershed in Central America: Implications for Water Resource Engineering. Journal of the American Water Resources Association (JAWRA) 48(5): 1022‐1031. DOI: 10.1111/j.1752‐1688.2012.00668.x Abstract: Understanding the basic relationships between rainfall and runoff is vital for effective management and utilization of scarce water resources. Especially, this is important in Central America with widespread potable water shortage during the dry months of the monsoon. Potential good water sources are cloud forests, but little information concerning its potential is available to water supply engineers. Our objective is to define rainfall‐runoff‐base flow relationships for a cloud forest catchment. Flumes were installed for measuring river flow in four subwatersheds in La Tigra National Park, Honduras. One of the four watersheds was a 636‐ha subwatershed (WS1) with 60% cloud forest coverage. Precipitation averaged 1,130 mm/yr over the entire basin. About half of the total rainfall became runoff for the cloud forest watershed whereas, for the adjacent undisturbed forested watershed, the total discharge was <20% of the amount of precipitation. Infiltration rates were generally greater than rainfall rates. Therefore, most rainfall infiltrated into the soil, especially in the upper, steep, and well‐drained portions of the watershed. Direct runoff was generated from saturated areas near the river and exposed bedrock. This research provides compelling evidence that base flow is the primary contributor to streamflow during both wet and dry seasons in cloud forest catchments. Protecting these flow processes over time is critical for the sustained provision of potable water.     

BETR global--a geographically-explicit global-scale multimedia contaminant fate model

We present two new software implementations of the BETR Global multimedia contaminant fate model. The model uses steady-state or non-steady-state mass-balance calculations to describe the fate and transport of persistent organic pollutants using a desktop computer. The global environment is described using a database of long-term average monthly conditions on a 15° × 15° grid. We demonstrate BETR Global by modeling the global sources, transport, and removal of decamethylcyclopentasiloxane (D5).     

内蒙古乌拉特后旗新兴矿业城市循环经济发展模式研究

内蒙古乌拉特后旗2001年之前一直是国家级贫困县,2003年以来,该旗将矿产资源优势转变为资产优势,通过发展矿业产业经济,一跃成为人均GDP超上海的富裕县,从农牧业为主县转变为工业为主县。这一转变是对草原及生态环境的巨大威胁。通过实地考察,调查研究齐华矿业公司经济发展经验,提出资源综合开发利用与生态平衡发展模式,该模式达到了工业发展起点高、污染破坏最小化的目标,同时经济得到了可持续发展。     

袋式除尘器运行中常见问题浅析

已广泛应用于各行业中的袋式除尘器在运行中存在如滤袋损坏、结露、箱体破损、运行阻力高、清灰装置失灵等诸多问题,本文就袋式除尘器在实际运行中存在的问题进行了详细的分析讨论。     

Comparison of Field Performance of Multiple Soil Moisture Sensors in a Semi‐Arid Rangeland1

Abstract:  Automated electronic soil moisture sensors, such as time domain reflectometry (TDR) and capacitance probes are being used extensively to monitor and measure soil moisture in a variety of scientific and land management applications. These sensors are often used for a wide range of soil moisture applications such as drought forage prediction or validation of large‐scale remote sensing instruments. The convergence of three different research projects facilitated the evaluation and comparison of three commercially available electronic soil moisture probes under field application conditions. The sensors are all installed in shallow soil profiles in a well instrumented small semi‐arid shrub covered subwatershed in Southeastern Arizona. The sensors use either a TDR or a capacitance technique; both of which indirectly measure the soil dielectric constant to determine the soil moisture content. Sensors are evaluated over a range of conditions during three seasons comparing responses to natural wetting and drying sequences and using water balance and infiltration simulation models. Each of the sensors responded to the majority of precipitation events; however, they varied greatly in response time and magnitude from each other. Measured profile soil moisture storage compared better to water balance estimates when soil moisture in deeper layers was accounted for in the calculations. No distinct or consistent trend was detected when comparing the responses from the sensors or the infiltration model to individual precipitation events. The results underscore the need to understand how the sensors respond under field application and recognize the limitations of soil moisture sensors and the factors that can affect their accuracy in predicting soil moisture in situ.     

Evapotranspiration in the Meso‐Scale Forested Watersheds in Minjiang Valley,West China1

Abstract: Information on evapotranspiration (ET) can help us understand water balance, particularly in forested watersheds. Previous studies in China show that ET was relatively low (30‐40% of total precipitation) in the Minjiang Valley located in the upper reach of the Yangtze River Basin. However, this conclusion was derived from research on small‐scale watersheds (<100 km²). The objective of this paper was to present ET information on meso‐scale watersheds in the Minjiang Valley. Four meso‐scale watersheds (1,700‐5,600 km²) located in the Minjiang Valley were used to estimate ET using the water balance approach. We first generated forest vegetation variables (coniferous forest percentage, forest cover percentage, and derived forest vegetation index) using remote sensing data. Landsat 5 TM satellite images, acquired on June 26, 1994, were selected for the vegetation classification. Actual annual ET was calculated based on 11‐year estimated precipitation and measured streamflow data (1992‐2002). We also calculated potential ET (PET) using an improved Thornthwaite model for all four watersheds for the period of 1992‐1998. PET can provide additional information about potential capacity of water flux to atmosphere in the region. Seasonal (dry and rainy) PET and ET for all studied watersheds were also estimated for comparison purposes as the water balance approach, at shorter than annual scales, would likely provide inaccurate estimates of ET. The dominant vegetations in the Minjiang Valley were grasslands, conifer forests, and shrub‐lands. Our results confirmed that both ET and PET for three studied meso‐scale watersheds in the Minjiang Valley is relatively low (39.5‐43.8 and 28.2‐47.7% for ET and PET, respectively), with an exception of ET in the Yuzixi watershed being 71.1%. This result is generally consistent with previous research at small watershed scales. Furthermore, the low ET across various scales in the Minjiang Valley may be related to the unique deeply cut valley environment.     

Seasonal air-water exchange fluxes of polychlorinated biphenyls in the Hudson River Estuary

Polychlorinated biphenyls (PCBs) were measured in the air and water over the Hudson River Estuary during six intensive field campaigns from December 1999 to April 2001. Over-water gas-phase SigmaPCB concentrations averaged 1100 pg/m3 and varied with temperature. Dissolved-phase SigmaPCB concentrations averaged 1100 pg/L and displayed no seasonal trend. Uncertainty analysis of the results suggests that PCBs with 5 or fewer chlorines exhibited net volatilization. The direction of net air/water exchange could not be determined for PCBs with 6 or more chlorines. Instantaneous net fluxes of SigmaPCBs ranged from +0.2 to +630 ng m(-2) d(-1). Annual fluxes of SigmaPCBs were predicted from modeled gas-phase concentrations, measured dissolved-phase concentrations, daily surface water temperatures and wind speeds. The net volatilization flux was +62 microg m(-2) yr(-1), corresponding to an annual loss of +28 kg/yr of SigmaPCBs from the Hudson River Estuary for the year of 2000.     

Mass balance and long-term fate of PCDD/Fs in a lagoon sediment and paddy soil, Niigata, Japan

Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in a sediment core and in samples of surface sediment and paddy soil collected from the Toyano lagoon and Kameda basin in Niigata, Japan, were analyzed to elucidate the temporal trends of their concentrations in the lagoon sediment and the relationship between the sediment and the paddy soil. The mass balance of these pollutants was also estimated to determine their long-term fate in surface waters. An analysis by chemical mass balance identified the agrochemicals pentachlorophenol and 2,4,6-trichlorophenyl 4-nitrophenyl ether as the major sources of PCDD/Fs. On the basis of the findings regarding the mass balance in the Kameda basin over the last 40 years, we estimate that more than half the input of PCDD/Fs to the Kameda basin has disappeared. We suggest that the PCDD/Fs that flowed out from the paddy fields have been transferred to the lower basin.     

转型期的资源与环境管理：基于市场-政府-社会三角制衡的分析

在经济体制转型期，伴随着经济的持续快速增长，我国出现了前所未有的资源破坏和环境恶化现象，严重制约未来经济社会的可持续发展。由此，构建解决经济发展需求与资源环境供给矛盾的有效机制，成为政界及学术界共同关注的重点课题。从中国经济转型期存在的主要资源与环境问题分析入手，提出资源环境管理制度构建的理想框架，通过进一步评价我国在市场机制、政府干预、公众参与3个方面的经验及教训，分别提出未来改进的方向。研究结果表明：“市场—政府—社会”三足鼎立的制度结构是我国资源环境管理制度构建的理想目标，也是适应世界资源环境保护发展的潮流。最后提出协调政府和市场作用、构建市场运作平台、营造公众参与氛围等方面的政策建议。