MULTICOMPONENT GEOCHEMICAL TRANSPORT MODELING USING HYDRUS-1D AND HP11

Abstract: The transport of reactive contaminants in the subsurface is generally affected by a large number of nonlinear and often interactive physical, chemical, and biological processes. Simulating these processes requires a comprehensive reactive transport code that couples the physical processes of water flow and advective-dispersive transport with a range of biogeochemical processes. Two recently developed coupled geochemical models that are both based on the HYDRUS-1D software package for variably saturated flow and transport are summarized in this paper. One model resulted from coupling HYDRUS-1D with the UNSATCHEM module. While restricted to major ion chemistry, this program enables quantitative predictions of such problems as analyzing the effects of salinity on plant growth and the amount of water and amendments required to reclaim salt-affected soil profiles. The second model, HPI, resulted from coupling HYDRUS-1D with the PHREEQC biogeochemical code. The latter program accounts for a wide range of instantaneous or kinetic chemical and biological reactions, including complexation, cation exchange, surface complexation, precipitation dissolution and/or redox reactions. The versatility of HP1 is illustrated in this paper by means of two examples: the leaching of toxic trace elements and the transport of the explosive TNT and its degradation products.     

联合开发荒山之初探

搞好小流域综合治理,加强水土保持,是贫困山区经济开发的基础性工作,也是山区人民脱贫致富奔小康的可靠途径。怎样进一步搞好水土治理和有效地开发贫困山区的资源呢?必须加大投资力度,在国家财政紧张的情况下,要多渠道、多层次的集资,采取股份制联合开发荒山,效益分成,以促进山区荒山的治理速度。青龙满族自治县的大石岭、谢庄的经验告诉我们:股份制联营开发治理荒山、荒坡是山区水土流失综合治理的可行途径,应大力推广。     

Use of Natural 35S to Trace Sulphate Cycling in Small Lakes,Flattops Wilderness Area,Colorado, U.S.A.

Measurements of the cosmogenically-produced ³⁵S, a radioisotope of sulphur (t_1/2 = 87 days), are reported for the Ned Wilson Lake watershed in Colorado. The watershed contains two small lakes and a flowing spring presumed to be representative of local ground water. The watershed is located in the Flattops Wilderness Area and the waters in the system have low alkalinity, making them sensitive to increases in acid and sulphate deposition. Time series of ³⁵S measurements were made during the summers of 1995 and 1996 (July–September) at all three sites. The system is dominated by melting snow and an initial concentration of 16–20 mBq L^-1 was estimated for snowmelt based on a series of snow samples collected in the Rocky Mountains. The two lakes had large initial ³⁵S concentrations in July, indicating that a large fraction of the lake water and sulphate was introduced by meltwater from that year's snowpack. In 1995 and 1996, ³⁵S concentrations decreased more rapidly than could be accounted for by decay, indicating that other processes were affecting ³⁵S concentrations. The most likely explanation is that exchange with sediments or the biota was removing ³⁵S from the lake and replacing it with older sulphate devoid of ³⁵S. In September of 1995 and 1996, ³⁵S concentrations increased, suggesting that atmospheric deposition is important in the sulphate flux of these lakes in late summer. Sulphur-35 concentrations in the spring water were highly variable but never higher than 3.6 mBq L^-1 and averaged 2 mBq L^-1. Using a simple mixing model, it was estimated that 75% of the spring water was derived from precipitation of previous years.     

Deposition and Storage of Spheroidal Carbonaceous Fly-Ash Particles in European Mountain Lake Sediments and Catchment Soils

Spheroidal carbonaceous particles(SCPs) are produced only from high temperaturecombustion of fossil-fuels. In mountain lakesystems, they provide an unambiguous indicator ofatmospheric deposition. In order to comparedepositional fluxes of SCPs between mountainareas experiencing various pollutant regimes,intensive bulk deposition sampling was undertakenat five sites across Europe. Catchment soil coresand lake sediment cores were also taken at eachsite to compare SCP storage over the post-industrial period. Atmospheric, sediment and soilSCP data showed similar patterns. Highestcontamination was found in Scotland, Slovakia andSpain with the Austrian site intermediate and themid-Norwegian site least contaminated. A highproportion of accumulated SCPs were found to bestored in catchment soils at each site.Therefore, a significant increase in soilerosion, possibly as a result of future climatechange, could lead to the input of largequantities of catchment stored SCPs and, byimplication, other atmospherically depositedcontaminants to the lake ecosystem.     

构造运动与中国沿岸平原的地质灾害

中国海岸穿过构造沉降带和隆起带，沉降带及隆起带断陷盆地的持续下降吸引了源远流长的大河在此人海，而隆起带内入海的河流多为近源小河，从而引起河流泥沙沿岸分配的不均和海岸沉积物的差异。沉降带内每公里海岸线接受的沉积物是隆起带的数十倍，且以砂质沉积物为主．隆起带河流泥沙来量少．而且砂质沉积物占了压倒的优势．河流泥沙沿岸分配的不均决定了中国沙质和淤泥质海岸的基本类型和分布格局、沉降带和隆起带松散沉积层的厚度和结构，山此产生了中国沿岸与第四纪沉积层有关的灾害和环境问题的有规律的分布。地面沉降主要分布于沉降带内，而地下海水入侵多出现在依赖地下水的隆起带内，底辟构造、浅层天然气往往在大河三角洲构成灾害和潜在的地质灾害．沉降带和隆起带断陷盆地内的海岸低地通常是海平面上升的主要脆弱地区．此外，丰富的河流泥沙使中国海岸对全球海平面上升的响应也不相同，如海岸湿地的再生和海岸侵蚀原因的复杂性等．     

江汉平原湖区农田防护林的小气候效应研究

在区域开发中,平原湖区的林业发展潜力很大,同时,湖区农田防护林的建设,也是促进生态平衡的一项重要措施,防护林能进一步改善湖区小气候环境,尤其对保障农业生产有着相当重要的意义。通过对江汉平原湖区的农田防护林网内的小气候效应温度,湿度,风速等要素的观测数据进行研究,我们得出的结果表明：江汉平原湖区农田林网的建设,除提供工农业生产所需的林木外,随着林木的增多,林网的完善,还可调节气候,保持水土,防风固沙     

泥石流与人类经济活动

山地是泥石流与人类共存的环境,泥石流作用于山地环境,强烈地影响人类经济活动：人类经济活动也作用于山地环境,强烈地影响泥石流。泥石流对山地环境的危害,主要为破坏地表、破坏生态系统和淤堵江河;泥石流对人类及其经济活动的危害,主要为破坏城镇,村庄,工矿,交通水利水电工程,农田和人类自身的安全。泥石流危害的结果,能导致山地坡面破碎化、沟口沙石化、河床宽浅化和植被逆向演替化,以及耕地贫瘠化、经济发展滞后化和     

A composite medium approximation for unsaturated flow in layered sediments

Saturated-unsaturated flow in strictly layered sediments proceeds via conductors in parallel in the direction parallel to bedding, and via resistors in series in the direction perpendicular to bedding. On sufficiently small scales of space and time, flow in such media will be subject to approximate capillary equilibrium locally, which provides a basis for approximating the effective hydraulic conductivity of a composite multi-layer medium in terms of the conductivities of the individual layers. Equations for the hydraulic conductivity tensor in "composite medium approximation" (COMA) are given in a coordinate system aligned with bedding. Hydraulic conductivity parallel to bedding is generally larger than in the perpendicular direction. The anisotropy depends on the spread of the conductivity distribution, and tends to increase for dryer conditions. The COMA model was implemented in a multi-phase flow simulator and tested by comparison with high-resolution simulations in which all layering heterogeneity is resolved explicitly. Under favorable conditions, COMA is found to accurately represent sub-grid scale flow and transport processes, providing a practical method for simulating field-scale flow and transport in layered media. The approximation improves when layers are thinner, and when flow rates are smaller.     

Human impacts on the stream-groundwater exchange zone

Active exchanges of water and dissolved material between the stream and groundwater in many porous sand- and gravel-bed rivers create a dynamic ecotone called the hyporheic zone. Because it lies between two heavily exploited freshwater resources—rivers and groundwater—the hyporheic zone is vulnerable to impacts coming to it through both of these habitats. This review focuses on the direct and indirect effects of human activity on ecosystem functions of the hyporheic zone. River regulation, mining, agriculture, urban, and industrial activities all have the potential to impair interstitial bacterial and invertebrate biota and disrupt the hydrological connections between the hyporheic zone and stream, groundwater, riparian, and floodplain ecosystems. Until recently, our scientific ignorance of hyporheic processes has perhaps excused the inclusion of this ecotone in river management policy. However, this no longer is the case as we become increasingly aware of the central role that the hyporheic zone plays in the maintenance of water quality and as a habitat and refuge for fauna. To fully understand the impacts of human activity on the hyporheic zone, river managers need to work with scientists to conduct long-term studies over large stretches of river. River rehabilitation and protection strategies need to prevent the degradation of linkages between the hyporheic zone and surrounding habitats while ensuring that it remains isolated from toxicants. Strategies that prevent anthropogenic restriction of exchanges may include the periodic release of environmental flows to flush silt and reoxygenate sediments, maintenance of riparian buffers, effective land use practices, and suitable groundwater and surface water extraction policies.     

长江流域生态环境的意义及生态功能区段的划分

中国加入WTO之后,中国经济进一步与国际市场接轨,融入世界经济体系,机遇和挑战同在。欧美各国近年大力推行的环境标志产品认证,对第三世界商品质量设置入关的环境门槛。长江产业带作为世界最大的内河产业带和制造业基地,现在世界通行的环境管理认证体系和环境标志产品的认证,对长江流域产业尤其是外贸出口产业有长远而深刻的影响。这种认证制度,一方面对我出口商品设置了新的障碍,另一方面又将环境保护压力直接施加到企业。重视流域生态环境将从政府行为、公民压力扩展到企业行动,由于流域生态环境的负荷愈来愈重,流域生态环境的自我调节和恢复功能大幅下降,引起了日益严重的流域性生态安全问题。根据长江流域生态环境特征、不同的生态功能及存在的主要生态安全问题,将长江流域划性生态安全问题。根据长江流域生态环境特征、不同的生态功能及存在的主要生态安全问题,将长江流域划分成以下五个不同的生态功能区段,即长江源地区、金少江段（直门达至宜宾）、长江上游段（宜宾至宜昌）、长江中游段（宜昌至湖口段）、长江下游段（湖口至入海口）。针对不同区段主要的生态安全问题,应因地制宜采取相应的防范和整治措施。为保护与恢复生态功能服务。