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941.
The influence of lubricants, UV stabilizers, antioxidants, and metal deactivators on the resistance of ABS to thermal oxidation was studied by means of the chemiluminescence technique. Neither of the additives seems to affect significantly the induction period of oxidation. At the same time, the influence of various additives on the oxidation rate constant is remarkably different: the introduction of lubricants and UV stabilizers increases its value, while antioxidants and metal deactivators have the opposite effect. For the particular systems studied durability is decreased in samples containing the lubricant and UV stabilizers and increased in samples stabilized with the antioxidant and metal deactivator. 相似文献
942.
The thermal oxidative stability of various ABS/PC compounds was studied by means of the chemiluminescence technique. Similarly to pure ABS, Irganox 1076 and Irganox MD 1024 perform as moderate antioxidants in ABS/PC and (ABS/PC + lubricant) blends. Neither Tinuvin 144, Irgaphos 168, nor their mixture affects the durability of the ABS/PC blend. At the same time, (Irgaphos 168 + Tinuvin 144) in combination with Irganoxes was found to provide a noticeable enhancement in durability to the (ABS/PC + lubricant) system. Titanium dioxide pigments by themselves have only a slight influence on the oxidative stability of the ABS/PC blend. Durability of the (ABS/PC + pigment) and (ABS/PC + lubricant) systems was found to be the same and the overall protective effect of Irganox 1076 was similar in both the (ABS/PC + lubricant) and the (ABS/PC + lubricant + pigment) systems. Certain modifiers significantly improve the durability of the ABS/PC compounds, although their function may differ in the systems with and without pigments.Guest Editor: Dr. Graham Swift, Rohm & Haas. 相似文献
943.
针对某木材加工企业生产废水高COD、高氨氮、高色度、含甲醛等特点,采用“芬顿氧化+A/O+沉淀+气浮”组合工艺对原废水处理厂进行扩容提标改造。该工程设计处理规模为600 t/d,总投资为340万元,直接运行成本为4.83元/t。运行效果表明:采用芬顿氧化预处理洗胶废水可有效降解甲醛等高毒性的有机物,增设载体的A/O工艺可提高COD去除效果与抗冲击负荷能力,组合工艺出水COD<400 mg/L,氨氮<20 mg/L,TN<40 mg/L,TP<2 mg/L,甲醛<2 mg/L。 相似文献
944.
英法炼油环保与清洁生产考察 总被引:3,自引:0,他引:3
英、法两国政府制订了既严格又切实可行的环保法规和标准,鼓励企业推行清洁生产。追求更好的环保业绩已成为企业经营活动的重要组成部分。“低压湿式氧化”技术可在低温、低压的条件下处理高浓度的有机废水。 相似文献
945.
Removal of airborne microorganisms emitted from a wastewater treatment
oxidation ditch by adsorption on activated carbon 总被引:1,自引:0,他引:1
Bioaerosol emissions from wastewater and wastewater treatment processes are a significant subgroup of atmospheric aerosols. Most
previous work has focused on the evaluation of their biological risks. In this study, however, the adsorption method was applied to reduce
airborne microorganisms generated from a pilot scale wastewater treatment facility with oxidation ditch. Results showed adsorption
on granule activated carbon (GAC) was an e cient method for the purification of airborne microorganisms. The GAC itself had a
maximum adsorption capacity of 2217 CFU/g for airborne bacteria and 225 CFU/g for fungi with a flow rate of 1.50 m3/hr. Over 85%
of airborne bacteria and fungi emitted from the oxidation ditch were adsorbed within 80 hr of continuous operation mode. Most of them
had a particle size of 0.65–4.7 m. Those airborne microorganisms with small particle size were apt to be adsorbed. The SEM/EDAX,
BET and Boehm’s titration methods were applied to analyse the physicochemical characteristics of the GAC. Relationships between
GAC surface characteristics and its adsorption performance demonstrated that porous structure, large surface area, and hydrophobicity
rendered GAC an e ective absorber of airborne microorganisms. Two regenerate methods, ultraviolet irradiation and high pressure
vapor, were compared for the regeneration of used activated carbon. High pressure vapor was an e ective technique as it totally
destroyed the microorganisms adhered to the activated carbon. Microscopic observation was also carried out to investigate original and
used adsorbents. 相似文献
946.
947.
948.
Bryan CE Davis WC McFee WE Neumann CA Schulte J Bossart GD Christopher SJ 《Chemosphere》2012,89(5):556-562
More than half of pygmy sperm whales (Kogia breviceps) that strand exhibit signs of cardiomyopathy (CMP). Many factors may contribute to the development of idiopathic CMP in K. breviceps, including genetics, infectious agents, contaminants, biotoxins, and dietary intake (e.g. selenium, mercury, and pro-oxidants). This study assessed trace elements in K. breviceps at various stages of CMP progression using fresh frozen liver and heart samples collected from individuals that stranded along US Atlantic and Gulf coasts between 1993 and 2007. Standard addition calibration and collision cell inductively coupled plasma mass spectrometry (ICP-MS) were employed for total Se analysis and pyrolysis atomic absorption (AA) was utilized for total Hg analysis to examine if the Se/Hg detoxification pathway inhibits the bioavailability of Se. Double spike speciated isotope dilution gas chromatography ICP-MS was utilized to measure methyl Hg and inorganic Hg. Immunoblot detection and colorimetric assays were used to assess protein oxidation status. Data collected on trace elements, selenoproteins, and oxidative status were evaluated in the context of animal life history and other complementary histological information to gain insight into the biochemical pathways contributing to the development of CMP in K. breviceps. Cardiomyopathy was only observed in adult pygmy sperm whales, predominantly in male animals. Both Hg:Se molar ratios and overall protein oxidation were greater in males than females and increased with progression of CMP. 相似文献
949.
The presence of disinfection byproducts (DBPs) such as trihalomethanes (THMs) and haloacetic acids (HAAs) in drinking water is of great concern due to their adverse effects on human health. Emerging regulation limiting the concentration of DBPs in drinking water has increased demands for technologies and processes which reduce the formation of DBPs in drinking water. In this study, UV-H2O2 based advance oxidation process (AOP) was used to treat raw surface water. Experiments were conducted using low pressure mercury vapor UV lamps in collimated beam and flow-through annular photoreactors. The effect of UV fluence (0–3500 mJ cm−2) and hydrogen peroxide concentration (0–23 mg l−1) in reducing the concentration of THMs and HAAs was examined. The UV-H2O2 AOP was then coupled with a downstream biological activated carbon (BAC) treatment to assess the synergetic benefits of combining the two treatments. It was observed that UV-H2O2 AOP was only effective at reducing DBPs at UV fluences of more than 1000 mJ cm−2and initial H2O2 concentrations of about or greater than 23 mg l−1. However, the combined AOP–BAC treatment showed significant reductions of 43%, 52%, and 59% relative to untreated raw water for DBPs, TOC, and UV254, respectively. 相似文献
950.
生化—光催化氧化工艺处理印染废水中污泥活性研究 总被引:1,自引:0,他引:1
从生物处理单元中污泥活性的角度,研究了生物氧化-光催化氧化过程中各相关因素的影响。采用BOD测定仪连续测定了驯化前后污泥耗氧曲线,采用第一段斜率表征污泥呼吸活性。并通过电镜观察驯化过程生物相的状况。实验结果表明,微生物呼吸活性的变化与微观生物相的变化一致,并与处理效果具有良好的相关性。 相似文献