铁路运输含硫原油过程中H_2S挥发规律模拟试验研究

以塔河12区含硫原油为研究对象,通过模拟铁路运输原油工况,研究罐内原油中H_2S挥发规律.结果表明,铁路运输过程中原油里H_2S析出浓度与时间的关系近似为6次多项式,并建证了H_2S浓度随时间变化的曲线方程;对影响罐内原油中H_2S挥发的2个主要因素罐内原油温度和罐车振动强度进行了分析.结果表明,罐内原油温度是原油中H_2S挥发的主要影响因素,升高罐内原油温度可以明显增加H_2S的挥发浓度.加大罐车振动强度对原油中H_2S挥发有促进作用,但不明显.     

辽河稠油热采现场硫化氢的防范与治理建议

硫化氢是一种剧毒和较强腐蚀性的气体,近年来在辽河油田一些地区相继出现,特别是稠油热采区块出现了较高浓度的硫化氢。硫化氢的存在已经威胁到油田的安全生产,并成为油气勘探开发过程中必须解决的问题。本文对辽河油气稠油热现场硫化氢的预防与治理提出了一些建议。     

Effects of long-term amendment of organic manure and nitrogen fertilizer on nitrous oxide emission in a sandy loam soil

To understand the effects of long-term amendment of organic manure and N fertilizer on N2O emission in the North China Plain, a laboratory incubation at different temperatures and soil moistures were carried out using soils treated with organic manure （OM）, half organic manure plus half fertilizer N （HOM）, fertilizer NPK （NPK）, fertilizer NP （NP）, fertilizer NK （NK）, fertilizer PK （NK） and control （CK） since 1989. Cumulative N2O emission in OM soil during the 17 d incubation period was slightly higher than in NPK soil under optimum nitrification conditions （25℃ and 60% water-filled pore space, WFPS）, but more than twice under the optimum denitrification conditions （35℃ and 90% WFPS）. N2O produced by denitrification was 2.1-2.3 times greater than that by nitrification in OM and HOM soils, but only 1.5 times greater in NPK and NP soils. These results implied that the long-term amendment of organic manure could significantly increase the N2O emission via denitrification in OM soil as compared to NPK soil. This is quite different from field measurement between OM soil and NPK soil. Substantial inhibition of the formation of anaerobic environment for denitrification in field might result in no marked difference in N2O emission between OM and NPK soils. This is due in part to more rapid oxygen diffusion in coarse textured soils than consumption by aerobic microbes until WFPS was 75% and to low easily decomposed organic C of organic manure. This finding suggested that addition of organic manure in the tested sandy loam might be a good management option since it seldom caused a burst of N2O emission but sequestered atmospheric C and maintained efficiently applied N in soil.     

Transformations of particles, metal elements and natural organic matter in different water treatment processes

Characterizing natural organic matter （NOM）, particles and elements in different water treatment processes can give a useful information to optimize water treatment operations. In this article, transformations of particles, metal elements and NOM in a pilot-scale water treatment plant were investigated by laser light granularity system, particle counter, glass-fiber membrane filtration, inductively coupled plasma-optical emission spectroscopy, ultra filtration and resin absorbents fractionation. The results showed that particles, NOM and trihalomethane formation precursors were removed synergistically by sequential treatment of different processes. Preozonation markedly changed the polarity and molecular weight of NOM, and it could be conducive to the following coagulation process through destabilizing particles and colloids; mid-ozonation enhanced the subsequent granular activated carbon （GAC） filtration process by decreasing molecular weight of organic matters. Coagulation-flotation and GAC were more efficient in removing fixed suspended solids and larger particles; while sand-filtration was more efficient in removing volatile suspended solids and smaller particles. Flotation performed better than sedimentation in terms of particle and NOM removal. The type of coagulant could greatly affect the performance of coagulation-flotation. Pre-hydrolyzed composite coagulant （HPAC） was superior to FeCl3 concerning the removals of hydrophobic dissolved organic carbon and volatile suspended solids. The leakages of flocs from sand-filtration and microorganisms from GAC should be mitigated to ensure the reliability of the whole treatment system.     

Non-UV based germicidal activity of metal-doped TiO2 coating on solid surfaces

A stain-based screening method was developed to screen different catalyst coatings for their germicidal activity. A Baclight dead/live bacteria viability kit （invitrogen, molecular probes） was used for staining the cell. The screening was carried out following a standard procedure. This included loading cell suspension to solid surface and maintaining contact for 30 min, then staining with a mixture containing dyes. The stained cells were observed using an epifluorescent microscope and photographed with a CCD camera under UV. Metal-doped TiO2 coatings on AI plates were prepared and tested for non-UV germicidal activity without using UV. It was tested using model microorganisms such as Bakers Yeast （Saccharomyces cerevisiae）, Bacillus subtilis, Pseudomonas putida, and Escherichia coli. On the basis of the germicidal activity of catalyst and the degree of damage caused to the cells, the stained cells may appear green （viable）, green with red or yellow nuclei and yellow （compromised） or red （nonviable）. According to their stained color, cells were counted to calculate the percentage of dead, live, and compromised cells. Compromised cells are cells that grow very slowly after reculturing indicating a degree of reversible cell damage. Screening the germicidal activity using this staining method is accurate and efficient, and requires less time than the culture-based method. A modification to the procedure for measuring germicidal activity of rough surfaces or fibrous coatings was developed. Both TiO2 and metal-doped TiO2 （Ag, Pt, Au, Cu） possess non-UV based germicidal activity. The germicidal activity of TiO2 was found to be related with its wetting property and can be improved by UV irradiation before testing. It is not greatly affected by contact time, indicating a fast acting germicidal activity.     

城市产业部门CO2排放三层次核算研究

城市是人类生产和生活的中心,超过75%的温室气体从城市产生,其中又以城市产业部门能源消费和工业过程非能源产生的CO2为主。本文基于投入产出模型,评价城市产业部门3个不同层次的CO2排放。以重庆为案例,核算其2002-2008年产业部门三个层次的CO2排放,包括能源消费直接排放、购买电力间接排放和全生命周期排放,并进行多层次对比。结果显示传统能源消耗和购买电力为对象的核算方法低估了产业部门CO2排放水平。2002-2008年,重庆各产业部门排放量逐年增加,碳排放强度整体呈现下降趋势。煤炭开采和洗选业、非金属矿采选业、非金属矿物制品业、电力、热力的生产和供应业,化学工业、金属冶炼及压延加工业、交通运输、仓储及邮电通讯业部门共7大行业是重庆碳排放的重点行业。部门交通设备制造业是重庆的优势产业,排放总量大,但是排放强度却相对较小,因此应大力发展该产业以促进重庆市低碳经济的发展。     

云南省能源消费及二氧化碳排放分析

根据云南省能源消费量,计算了由能源消费产生的CO2排放量及单位GDP碳排放强度。结果表明:近10年来,随着社会经济的快速发展,云南省能源消费及能源消费导致的CO2排放总量也呈现出显著上升的趋势。云南的碳排放强度高于全国平均水平,但人均碳排放量低于全国平均水平。以工业为主的第二产业是能源消费及碳排放的主体,其碳排放占总量的75%。     

高铁扣件弹条疲劳断裂原因分析

通过对WJ-7型扣件中60Si2MnA弹条在拉伸-扭转试验过程发生断裂的原因进行分析和数值模拟研究,得出弹条断裂的原因.对60Si2MnA弹条承受的荷载进行分析可知,WJ-7型扣件在铁垫板与弹条后端接触区域内弯处应力集中最大,是造成弹条断裂破坏的主要原因之一,而弹条断裂的根本原因是弹条长期处于极限强度下工作,使弹条最终...     

A study on oxidative degradation of polyacrylamide in wastewater with UV/FENTON/C4H4O62−

The degradation of polyacrylamide (PAM) in simulate wastewater was studied in UV/Fenton/C₄H₄O₆^2? system. The factors such as molecular ratio of H₂O₂/Fe²⁺/C₄H₄O₆^2?, pH, and the dosage of Fenton reagent that could affect the PAM degradation in the UV/Fenton/C₄H₄O₆^2? system were investigated. The experimental results showed that adding C₄H₄O₆^2? to UV/Fenton system could form photosensitive ferrous complexes, which led to higher degradation efficiency of PAM. The degradation rate of PAM could be up to 95.2% under the following conditions: the concentration of H₂O₂, Fe²⁺, and C₄H₄O₆^2? were 22.5, 2.25, and 2.25 mmol/L, respectively (i.e., molecular ratio of H₂O₂/Fe²⁺/C₄H₄O₆^2? was 10:1:1), the pH value was 3.0.     

洪泛区林地的开发对鱼类栖息地面积的影响模拟

洪泛区的开发利用,必然会导致洪泛区林地糙率的改变。河漫滩也是河流洪泛区的一部分。洪泛区糙率的减小,会使河水流速增大,从而减小鱼类可用栖息地面积。因此,在洪水发生时,为了给鱼类提供避险场所,保护有效栖息地面积,需研究洪泛区林地的开发对鱼类的影响。利用River 2D软件模拟在一定频率的洪水条件下,不同的河漫滩糙率对应的鱼类栖息地加权可用面积(WUA),分析了糙率的改变对河流鱼类栖息地的影响。结果表明:随着河漫滩糙率的降低,加权可用面积(WUA)逐渐减小,河漫滩范围内WUA的变化幅度比较大,河漫滩的特性对鱼类栖息地面积的影响很大。洪泛区植被的砍伐,会使鱼类栖息地面积减小。因此,应防止洪泛区的过度开发,保护河流生态环境。