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781.
云南省酸雨控制区二氧化硫污染现状及综合防治措施 总被引:2,自引:0,他引:2
能源结构的特点,使酸雨控制区的二氧化硫排放量高居不下,"西电东送"将进一步增加酸雨控制区的二氧化硫排放量.必须采取严格的、切实有效的综合防治措施削减二氧化硫排放量,确保"十五"期间酸雨控制区总目标的实现. 相似文献
782.
以钛酸四丁酯为原料 ,膨胀珍珠岩为载体 ,用溶胶 -凝胶法制备可漂浮于水面的负载型TiO2 。利用该负载型TiO2 对罗丹明B(RB)进行光催化脱色实验 ,结果表明 ,浸渍 3次的负载型TiO2 光催化活性最高 ,催化剂最佳用量为 5 0 0mg/10 0mLRB ,经 5h光照 ,对 10 0mL浓度为 1mg/L和 2 .5mg/LRB脱色率分别为 76 .6 7%和 4 7.2 7% ;该催化剂使用寿命长 ,2 5h后催化剂脱色性能没有减弱 ,可重复使用 ;经 8h光照 ,染料废水脱色效果好。 相似文献
783.
Euglena gracilis as a model for the study of Cu and Zn toxicity and accumulation in eukaryotic cells
Marcelo Einicker-Lamas Gustavo Antunes Mezian Thiago Benevides Fernandes Fabio Leandro S. Silva Flvio Guerra Kildare Miranda Marcia Attias Mecia M. Oliveira 《Environmental pollution (Barking, Essex : 1987)》2002,120(3)
We have observed the effect of copper and zinc on the biology of Euglena gracilis. The cells displayed different sensitivities to these metals, as the apparent LC50 for Cu2+ was 0.22 mM, and for Zn2+ it was 0.88 mM. While Zn2+ was able to increase cell proliferation even at 0.1 mM, the minimal CuCl2 concentration tested (0.02 mM) was sufficient to impair cell division. Higher concentrations of these metals not only inhibited cell division in a concentration-dependent manner, but also interfered with the metabolism of E. gracilis. A higher accumulation of proteins and lipids per cell was observed at the DI50 concentration for metal-treated cells. These results suggest that the test concentration of both metals leads to a failure in completing cell division. Ultrastructural analysis indicated a chloroplast disorganization in copper-treated cells, as well as the presence of electron dense granules with different shapes and sizes inside vacuoles. Microanalysis of these granules indicated an accumulation of copper, thus suggesting a detoxification role played by the vacuoles. These results indicate that E. gracilis is an efficient biological model for the study of metal poisoning in eukaryotic cells. They also indicate that copper and zinc (copper being more poisonous) had an overall toxic effect on E. gracilis and that part of the effect can be ascribed to defects in the structure of chloroplast membranes. 相似文献
784.
Breakthrough curves, on a semi-log scale, from tests in porous media with block-input of viruses, bacteria, protozoa and colloidal particles often exhibit a typical skewness: a rather slowly rising limb and a smooth transition of a declining limb to a very long tail. One-site kinetic models fail to fit the rising and declining limbs together with the tail satisfactorily. Inclusion of an equilibrium adsorption site does not seem to improve simulation results. This was encountered in the simulation of breakthrough curves from a recent field study on the removal of bacteriophages MS2 and PRD1 by passage through dune sand. In the present study, results of laboratory experiments for the study of this issue are presented. Breakthrough curves of salt and bacteriophages MS2, PRDI, and phiX174 in 1 D column experiments have been measured. One- and two-site kinetic models have been applied to fit and predict breakthrough curves from column experiments. The two-site model fitted all breakthrough curves very satisfactorily, accounting for the skewness of the rising limb as well as for the smooth transition of the declining limb to the tail of the breakthrough curve. The one-site model does not follow the curvature of the breakthrough tail, leading to an overestimation of the inactivation rate coefficient for attached viruses. Interaction with kinetic site 1 is characterized by relatively fast attachment and slow detachment, whereas attachment to and detachment from kinetic site 2 is fast. Inactivation of viruses and interaction with kinetic site 2 provide only a minor contribution to removal. Virus removal is mainly determined by the attachment to site 1. Bacteriophage phiX174 attached more than MS2 and PRD1, which can be explained by the greater electrostatic repulsion that MS2 and PRD1 experience compared to the less negatively charged phiX174. 相似文献
785.
附载型复合光催化剂TiO2·SiO2/beads降解有机磷农药 总被引:5,自引:0,他引:5
研究以四异丙醇钛 [Ti( iso- O C3 H7) 4]、硅酸乙酯为原料 ,以空心玻璃微球为载体 ,用溶胶—凝胶法制备可漂浮附载型复合光催化剂 Ti O2 · Si O2 / beads的过程 ,利用附载型复合光催化剂降解有机磷农药。结果表明 ,复合型光催化剂 Ti O2 · Si O2 摩尔比存在最佳值 ,n ( Ti O2 ) / m ( Si O2 ) =30 / 70时 ,光催化剂活性最高 ,其活性是同样降解条件下、同样含量 Degussa P- 2 5Ti O2 的 2倍左右。该光催化剂比表面大 ,吸附性强。并用 XRD和 SEM对附载型复合光催化剂进行表征 相似文献
786.
Urs Baumann Hanspeter Indermaur und Ernst Pletscher 《Umweltwissenschaften und Schadstoff-Forschung》2000,12(2):63-67
Zusammenfassung Zur ?kotoxikologischen Beurteilung von belastetem Wasser werden h?ufig einfache Biotests eingesetzt. Nicht selten werden dabei
toxische Effekte festgestellt. Es stellt sich dann die Frage nach den verantwortlichen Wasserinhalts-stoffen. Durch Festphasenextraktion
(SPE) werden diese angereichert, gewonnen und dünnschichtchromatographisch unter Verwendung der automatisierten Mehrfachentwicklung
aufgetrennt. Von der DC-Platte wird ein Streifen abgetrennt und darauf direkt die biologische Detektion mit Mikroorganismen
(Bacillus subtilis, Leuchtbakterien) durchgeführt. Dadurch k?nnen toxische Banden erkannt werden, Auf dem DC-Plattenrest wird von der toxischen
Bande mit einem DC-scanner ein UV-Spektrum aufgenommen, die entsprechende Bande herausgekratzt, der toxische Stoff eluiert
und infrarotspektroskopisch untersucht. Durch Spektrenvergleich gelingt es meistens, den Stoff zu charakterisieren.
In der vorliegenden Arbeit wird am Beispiel eines Zitzengummieluates das Analysenkonzept vorgestelit. Es zeigte sich, dass
dieser Gummiartikel einen Vulkanisationsbeschleuniger (2-Mercaptobenzothiazol) freisetzt.
Online-Publikation am: 21.12.1999 相似文献
787.
In silicone rubber crosslinked with bis(2,4-dichlorobenzoyl) peroxide (DCBP) as initiator about 0.1% of DCBP is converted into polychlorobiphenyls (PCBs). The PCB content in silicone rubber determined by high resolution gas chromatography (HRGC) after its destruction by HF is around 10 mg/kg. 29 PCB congeners were detected. Instead of the expected PCB-47, lower chlorinated congeners are predominant. Some possible pathways of their origin are presented. 相似文献
788.
Rainer Haas 《Umweltwissenschaften und Schadstoff-Forschung》1998,10(4):198-199
Zusammenfassung 2-Chlorvinylarsindichlorid (Lewisit I) und 2,2′-Dichlordivinylarsinchlorid (Lewisit II) reagieren bei Raumtemperatur in einer
Substitutionsreaktion schnell und quantitativ mit Dithiolen. Die Derivate wurden massenspetrometrisch identifiziert. Sie sind
mit GC/ECD detektierbar. Diese Reaktionen k?nnen zur gaschromatographischen Bestimmung von Lewisiten in Wasser-und Bodenproben
eingesetzt werden.
相似文献
789.
790.
Takayuki Kameda Koji Inazu Yoshiharu Hisamatsu Norimichi Takenaka Hiroshi Bandow 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):7742-7751
The formation of mutagenic nitro-polycyclic aromatic hydrocarbons (NPAHs) 1- and 2-nitrotriphenylene (1- and 2-NTP) via gas-phase OH or NO3 radical-initiated reactions of triphenylene was demonstrated for the first time using a flow reaction system. In contrast with the results of conventional electrophilic nitration, 2-NTP was formed in larger yield than 1-NTP, but this is consistent with the mechanism proposed for gas-phase radical-initiated nitration of PAH. In diesel exhaust particle (DEP) samples, both 1- and 2-NTP were identified and their concentrations determined, as well as 1-nitropyrene (1-NP), which is a representative combustion-derived NPAH: the mean concentrations of 1-NTP, 2-NTP, and 1-NP were 4.7, 1.9, and 32 pmol mgDEP–1, respectively. The mean 2-NTP/1-NTP, 1-NTP/1-NP, and 2-NTP/1-NP ratios in samples of airborne particles collected in a residential area in Osaka, Japan, were>1.55,<0.25, and 0.37, respectively; these values are much higher than those of the DEP samples. This finding indicates that there is another source for airborne NTPs, especially 2-NTP, apart from diesel exhaust. These results strongly suggest that airborne NTPs originate from atmospheric processes such as radical-initiated reactions of triphenylene, and this has a significant influence on the atmospheric occurrence of NTPs. 相似文献