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111.
112.
Monoclinic bismuth vanadate(BiVO4) thin film was fabricated on indium-tin oxide glass from an amorphous heteronuclear complex via dip-coating.After annealation at 400,500,and 600°C,the thin films were characterized by X-ray diffraction,field emission scanning electron microscopy,X-ray photoelectron spectroscopy,and UV-Vis spectrophotometry.The BiVO4 particles on the ITO glass surface had a monoclinic structure.The UV-Visible diffuse reflection spectra showed the BiVO4 thin film had photoabsorption propertie... 相似文献
113.
The toxicity of naphthalene to a freshwater microalga, Chlorella pyrenoidosa, and the subsequent recovery of algae from the damage
were investigated under two nutrient conditions, either enriched with nitrogen (N) and phosphorus (P), or starved of N and P. Results
showed that C. pyrenoidosa was more sensitive to naphthalene under N,P-enriched condition, and the inhibitory rate generally increased
at first and then decreased gradually with the evaporation of naphthalene under both nutrient conditions. Enriched N, P reduced the
inhibitory rate at initial naphthalene concentration of 5 and 10 mg/L, but enhanced it at 100 mg/L, at which more severe ultrastructure
damages were found than those under N,P-starved condition. Observed damages included partly or totally disappearance of nucleolus,
nuclear, and plasma membranes. According to the chlorophyll content and cell density measurements, C. pyrenoidosa could recover
from naphthalene damage with initial concentrations 6 50 mg/L in 7 days under both nutrient conditions, while they could not recover
if the initial concentration of naphthalene was at 100 mg/L. Under the N,P-starved condition, the inability of C. pyrenoidosa to recover
from the naphthalene damage was consistent with the results of high inhibitory rate, low value of specific growth rate (SGR, 0.05
day??1), and the severe destruction of cell structure. However, under the N,P-enriched conditions, the observed lower inhibitory rate,
higher value of SGR (0.55 day??1), and the intact cell structure of most cells suggested that algae could potentially recover from the
naphthalene damage. 相似文献
114.
Qin Zhang Xiaodi Cheng Chen Zheng Xionghan Feng Guohong Qiu Wenfeng Tan Fan Liu 《环境科学学报(英文版)》2011,23(11):1904-1910
The effect of crystal structure on photocatalytic activities of manganese oxides and underlying reaction mechanism were investigated. 相似文献
115.
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117.
An organo-montmorillonite-supported nanoscale zero-valent iron material(M-NZVI) was synthesized to degrade decabromodiphenyl ether(BDE-209). The results showed that nanoscale zero-valent iron had good dispersion on organo-montmorillonite and was present as a core-shell structure with a particle size range of nanoscale iron between 30–90 nm, characterized by XRD, SEM, TEM, XRF, ICP-AES, and XPS. The results of the degradation of BDE-209 by M-NZVI showed that the efficiency of M-NZVI in removing BDE-209 was much higher than that of NZVI. The efficiency of M-NZVI in removing BDE-209 decreased as the pH and the initial dissolved oxygen content of the reaction solution increased, but increased as the proportion of water in the reaction solution increased. 相似文献
118.
Aim of the present study was to synthesize titanium dioxide nanoparticles (YiO2 NPs) from marine actinobacteria and to develop an eco-friendly azo-dye degradation method. A total of five actinobacterial isolates were isolated from Chennai marine sediments, Tamilnadu, India and analyzed for the synthesis of TiO2 NPs using titanium hydroxide. Among these, the isolate PSV 3 showed positive results for the synthesis of TiO2 NPs, which was confirmed by UV analysis. Further characterization of the synthesized TiO2 NPs was done using XRD, AFM and FI'-IR analysis. Actinobacterial crude extract and synthesized TiO2 NPs was found efficient in degrading azo dye such as Acid Red 79 (AR-79) and Acid Red 80 (AR-80). Degradation percentage was found to be 81% for AR-79, 83% for AR-80 using actinobacterial crude extract and 84% for AR-79, 85% for AR-80 using TiO2 NPs. Immobilized actinobacterial ceils showed 88% for AR-79 and 81% for AR- 80, dye degrading capacity. Degraded components were characterized by FT-IR and GC-MS analysis. The phytotoxicity test with 500 μg/mL of untreated dye showed remarkable phenotypic as well as cellular damage to Tagetes erecta plant. Comparatively no such damage was observed on plants by degraded dye components. In biotoxicity assay, treated dyes showed less toxic effect as compared to the untreated dyes. 相似文献
119.
四环素光催化降解特性与选择性研究 总被引:3,自引:1,他引:2
研究了盐酸四环素的光催化降解行为,结果表明四环素光催化降解反应符合一级反应动力学方程,吸附过程为整个光催化降解的控制步骤,推断四环素的主要降解途径是吸附在二氧化钛(TiO2)表面发生光催化氧化反应.同时,通过对四环素与磺胺甲唑或阿莫西林混合样品的降解实验表明,改变pH、TiO2投加量等因素,两种抗生素的降解表现出了明显的选择性. 相似文献
120.
对硝基苯胺耐盐降解菌S8的筛选及特性研究 总被引:3,自引:1,他引:2
从江苏农药厂活性污泥中筛选出1株能以对硝基苯胺为唯一碳源和氮源生长代谢的耐盐降解菌S8.通过对其形态特征、生理生化特性以及16S rDNA序列分析,确定为枯草芽孢杆菌(Bacillus subtilis).研究表明,该菌株具有较强的对硝基苯胺降解能力.当温度31℃和pH 6.0时,S8在72 h内对60 mg·L-1和120 mg·L-1对硝基苯胺的降解率分别为65.6%和55.8%.在高盐条件下,S8仍有较强的降解能力,当盐含量为7%时,对硝基苯胺降解率为49.5%(72 h);当盐含量为10%时,对硝基苯胺降解率为27.4%(72 h).利用LC-MS法分析降解产物时,共发现6种分子量不同的化合物,其中两种为苯酚及对苯二酚.此为首次关于对硝基苯胺耐盐菌株的研究报道,菌株S8可用于含有对硝基苯胺的高盐工业废水的微生物修复. 相似文献