Investigation of the complexation of metal-ions by strong ligands in fresh and marine water

SCOPE: The detection and investigation of metal ions bound in strong complexes in natural waters is a difficult task, due to low concentration of the metal ions themselves, and also of the strong ligands, which, moreover, are often not of a well-defined composition. Here, a method is proposed for the investigation of the speciation of metal ions in natural waters. OBJECTIVE AND METHOD: It is based on the sorption of metal ions on strongly sorbing ion exchange resins, i.e. complexing resins. For this reason the method is called Resin Titration. It has been shown in previous investigations that the concentration of metal ion totally sorbed by a particular resin, and its reaction coefficient in the solution phase in the presence of the resin, can be determined from the sorption data using a simple relationship. Here, a data treatment (the Ruzic linearization method) is proposed for also determining the concentration of the ligands responsible for the complex in equilibrium with the resin. RESULTS: The method was applied to data obtained by Resin Titration of a freshwater and a seawater. Copper(II) and aluminium(III) were considered, using Chelex 100 as a titrant, due to its strong sorbing properties towards these metal ions. The results were: the total metal concentration in equilibrium with the resin, the side reaction coefficients, and the concentration of ligands. In all these cases the ligands forming very strong complexes were found to be at concentration lower than that of the metals. CONCLUSION: The Ruzic linearization method allows the determination of the concentration of the ligands forming very strong complexes in equilibrium with Chelex 100. The reaction coefficient was better determined by the calculation method previously proposed for RT. The ligands responsible for the strong complexes were found to be at low concentration, often lower than that of the metal ions considered. The metal in the original sample is partly bound to these ligands, since the complexes are very strong. Only a part of the metal is linked to weaker ligands, or free.     

自然生态系统中含硫气体的产生机理与环境归趋

基于当前可获得的与该课题相关的资料 ,本文综述了陆地生态系统产生挥发性含硫气体的微观和宏观机理过程。讨论了控制生物硫气体产生的环境因素。阐述了含硫气体释放进入大气后的环境归趋     

农业蔬菜废物处理方法研究进展和探讨

目前我国农业蔬菜废物污染问题正日益加重 ,蔬菜废物和其他固体废物相比具有高含水率、高营养成分和基本无毒害的特性 ,适宜于单独收集处理。本文介绍了国内外蔬菜废物处理方法的研究进展 ,包括好氧堆肥法、厌氧消化法、好氧 -厌氧联合处理法 ,并对这些方法的适用条件进行了论述。同时 ,探讨了接种微生物自然堆沤法的初步研究结果     

模糊综合评价在天然水体水质评价中的应用研究

采用模糊数学方法,对河网地区面源污染影响较大的代表性河流的水质状况进行综合评价研究。根据监测断面水质污染特点,确定了8个指标作为评价因子,建立了评价因素矩阵,计算出影响因子的权重。在此基础上,提出了模糊综合评价的水质级别,证明该河网地区的污染物主要是氮、磷和有机物。     

淡水鱼类种质资源信息系统的研制

采用人工智能和多媒体技术、建成了淡水鱼类种质资源信息系统。本系统完整、准确地保存了鲢、鳙、草鱼、团头鲂、方正银鲫、兴国红鲤、散鳞镜锂、尼罗罗非鱼、奥利亚罗非鱼等十种淡水鱼类种质标准参数及其性状图形、图像集、,包括鱼类可量和可数性状;鱼类年龄与生长特征;鱼类性成熟和怀卵量特征;鱼类耗氧量、耗氧率和窒息点指标;鱼类肌肉成份;鱼类染色体核型图像;鱼类同工酶酶谱组成指标,为进行种质鉴别和保存探索了一条新路     

Sustainable Agriculture: New Paradigms and Old Practices? Increased Production with Management of Organic Inputs in Senegal

Farmers in Sahelian countries are confronted with a variety of soil fertility and management problems. During the last two decades, NGOs have worked with farmers and research institutions to develop and test practices that will increase food production, while at the same time enhance the natural resource base.Since 1987, The Rodale Institute (RI) has worked closely with farmers' associations and government institutions to promote regenerative agriculture-farming systems that prioritize the use of local resources while improving them as they are used to grow food, using agro-ecological methods. The Senegalese Agricultural Research Institute has collaborated in this program as a partner of RI. The Senegal Regenerative Agriculture Resource Center model has been applied as a new and viable approach that builds on traditional knowledge and farmer-to-farmer exchange.Research results on soil conservation and improvement have shown that fields spread with amended animal manure or compost yield greater harvests than fields farmed with traditional methods.     

自然资源资产审计制度的供给侧改革

自然资源是可持续发展的基础。完善自然资源资产审计制度,是保护自然资源、践行生态文明的要求。自然资源资产审计的前提是自然资源的确权和量化,是自然资源与自然资源资产在审计上的“融合”。作为自然资源资产审计的依据,相关制度应该对自然资源的确权、计量和有效利用作出合理安排,才能有效抑制资源滥用冲动。但立足于自然资源资产审计实践,综合运用文献研究、个案调查、跨学科研究等方法,分析现行的自然资源制度,没有发现可操作性的自然资源产权制度、计量制度和评价制度,已有制度存在权责不匹配、责任界定不清晰、公众参与有困难、审计指标不健全;制度系统呈现存量不足、增量困难、实践不力,不能适应新时代要求和自然资源合理利用需要。因此,可以从制度存量、增量和协同三条路径实施制度供给侧改革;在完善制度存量方面,可以在经济责任审计规定中嵌入自然资源资产审计内容,完善自然资源资产评价标准、责任制度和审计结果运用办法等;在提高制度增量方面,完善自然资源资产的权利制度、计量制度、信息公开制度和公众参与制度等;同时,通过适时修订审计法、制定自然资源资产法,强化制度协调,以突破自然资源资产的制度瓶颈,方便审计算好“生态账”、把好“生态关”。在自然资源资产制度改革过程中,需要借助决策层和专家力量,摆脱部门立法局限,强化制度协调;同时,制度改革也是一个不断优化的过程,要兼顾公众、个人、政府及其职能部门等多方利益,才能有效满足资源节约型和环境友好型社会的需要。     

基于复式记账的土地资源资产核算与报表编制研究

借鉴会计学复式记账核算的优点,在国际资源核算体系的基础上,根据我国自然资源资产核算需求,提出土地资源资产核算的复式记账体系和报表编制框架。研究认为,基于复式记账的土地资源资产核算和报表编制要以“摸清家底、反映自然资源负债、提供土地资源审计和绩效考核信息”为目标,明确区、县级自然资源局为土地资源资产受托管理和进行土地资源资产核算与报表编制的核算单位。在界定土地资源资产、负债和权益相关概念的基础上,提出土地资源资产属性变化的核算内容和每次土地资源资产实物量变化必须遵循占补平衡的基本原则,进行过程核算。以YC县土地资源资产变化为例,对土地资源资产变化进行了基于复式记账的土地资源资产核算与报表编制实证研究,确定核算的事项类型和特征及其借贷核算流程,编制出土地资源资产负债表,并同时进行实物量核算和价值量核算的报表编制,结果表明:YC县土地资源资产实物量1485 km^2,2018年末价值量5639874.22万元、经济权益5271874.22万元、生态权益367991.6万元,土地资源负债8.40万元,通过土地资源资产用途调整,土地资源资产价值量增加21319.42万元,但在调整过程中,形成了土地资源负债0.07 km^2(8.4万元),在以后土地整治中需要增加园地。     

中国自然资源资产负债表编制及运用的关键问题

完善的自然资源资产负债表编制体系,能为国家和各级政府摸清“家底”,进行宏观经济管理、资源配置等工作提供重要的数据信息。党的十八届三中全会提出探索编制自然资源资产负债表之后,与此相关的理论研究迅速增加,但针对自然资源资产负债表编制和运用的理论与实践仍存在一些模糊认识;诸如自然资源负债等难以确定的问题。着眼于此,本文对我国自然资源资产负债表的编制现状进行了认真的思考,总结出自然资源资产负债表编制和运用的六个关键问题,即对国际规范SEEA2012和SNA2008的认识问题,对以县级单位为起点的编制主体的认识问题,对单式和复式表格根本区别的认识问题,对实物量和价值量转换难点的认识问题,对自然资源资产负债表信息渠道与平台建设的认识问题,对自然资源资产负债表编制中各部门权责关系的认识问题。以此为基础,本文从国际做法和国内实践两个角度进行了分析,并提出了本文观点:编制和运用自然资源资产负债表,应全面理解、充分借鉴SEEA2012和SNA2008的国际规范;确立以县级及以下政府层级为起点的编制主体;转变为“从单式到复式”的编表思路,坚持使用复式表格;迈出实物量向价值量转化的重要一步,重视价值量核算;建设自然资源数据收集的信息渠道与平台;处理好自然资源资产负债表编制中各部门间的权责关系。本文研究有利于推进自然资源资产负债表编制与运用工作,发挥自然资源资产负债表在我国的生态文明建设中的重要作用。     

中国经济的“阿基米德支点”

资源是经济发展的“阿基米德支点”：世界十大经济国每年能源的生产占全球的６２．１％，消费为７１．０％。重要矿产资源的生产多排在世界前１０名生产国之，外面是消费则多排在１０名之内，且对这些矿产资源的消费量多在９５％以上。