臭氧联用技术深度处理腈纶废水的效果对比

将臭氧分别与超声波、H2O2、紫外光等联用,深度处理干法腈纶生产厂生化池出水,对各种联用技术的处理效果进行了研究。实验结果表明：在进水流量2 L/min、反应时间30 min、臭氧加入量3.5 g/（L?h）的条件下,当超声功率为300 W时,臭氧-超声联用技术的COD去除率为30.0%;当H2O2加入量为0.4 mL/L时,臭氧-H2O2联用技术的COD去除率为50.7%;当紫外灯功率为40 W时,臭氧-紫外光联用技术的COD去除率为49.9%;在各种联用技术中,臭氧-H2O2联用技术的运行成本最低（为7.5 元/t）,且处理后出水COD为143 mg/L,达到《<污水综合排放标准>（GB8978—1996）中石化工业COD标准值修改单》中的一级排放标准。综合考虑,臭氧-H2O2联用技术是深度处理干法腈纶废水的最优工艺。     

Using multivariate regression modeling for sampling and predicting chemical characteristics of mixed waste in old landfills

Municipal solid waste landfills pose a threat on environment and human health, especially old landfills which lack facilities for collection and treatment of landfill gas and leachate. Consequently, missing information about emission flows prevent site-specific environmental risk assessments. To overcome this gap, the combination of waste sampling and analysis with statistical modeling is one option for estimating present and future emission potentials. Optimizing the tradeoff between investigation costs and reliable results requires knowledge about both: the number of samples to be taken and variables to be analyzed.This article aims to identify the optimized number of waste samples and variables in order to predict a larger set of variables. Therefore, we introduce a multivariate linear regression model and tested the applicability by usage of two case studies. Landfill A was used to set up and calibrate the model based on 50 waste samples and twelve variables. The calibrated model was applied to Landfill B including 36 waste samples and twelve variables with four predictor variables.The case study results are twofold: first, the reliable and accurate prediction of the twelve variables can be achieved with the knowledge of four predictor variables (Loi, EC, pH and Cl). For the second Landfill B, only ten full measurements would be needed for a reliable prediction of most response variables. The four predictor variables would exhibit comparably low analytical costs in comparison to the full set of measurements. This cost reduction could be used to increase the number of samples yielding an improved understanding of the spatial waste heterogeneity in landfills.Concluding, the future application of the developed model potentially improves the reliability of predicted emission potentials. The model could become a standard screening tool for old landfills if its applicability and reliability would be tested in additional case studies.     

干式厌氧消化过程挥发酸对硫酸盐还原菌的影响

在牛粪干式厌氧消化过程中,通过添加不同挥发酸(乙酸、丙酸、丁酸),考察消化稳定阶段,挥发性脂肪酸的分布特征,挥发性脂肪酸酸组成变化对硫酸盐还原菌(SRB)的影响,微生物种群组成和种群间关系。实验结果表明,挥发性脂肪酸对SRB还原速率的贡献依次为:丙酸丁酸乙酸。相比乙酸和丁酸,添加一定量的丙酸,更有利于激活SRB的活性,从而加强SRB与产甲烷菌(MB)的种间协同,保证厌氧系统的稳定运行。     

高铝粉煤灰提取氧化铝后硅钙渣用作水泥混合材

为了使高铝粉煤灰提取氧化铝后所产生的硅钙渣被大量的用作水泥混合材,通过水泥强度、水化放热和干缩性实验研究了原状硅钙渣和脱碱硅钙渣对水泥强度和稳定性的影响。结果表明,当硅钙渣掺量达30%时,硅钙渣水泥强度仍可满足P·C 32.5水泥要求。且随硅钙渣掺入量的增加,水泥早期水化放热速率增加的同时水泥累计水化放热量和干缩率还会显著降低。与原状硅钙渣相比,在同等掺量的情况下,脱碱硅钙渣更有利于保持水泥强度,降低其水化热和改善干缩性。     

电改袋技术在回转窑窑头烟气净化中的应用

在对水泥生产线篦冷机尾气除尘进行分析的基础上,提出了电除尘改袋式除尘的必要性,可有效控制新型干法窑烟尘和粉尘的排放浓度;针对具体案例的使用结果进行了阐述。     

新农村建设污水处理工程实例

山海关区新民居污水治理工程采用水解酸化+接触氧化+曝气生物滤池为主的工艺进行污水治理,实际运行结果表明:系统运行稳定,处理出水COD≤48 mg.L-1,BOD5≤9 mg.L-1,SS≤10 mg.L-1,NH3-N≤4.5 mg.L-1,TP≤0.47 mg.L-1,处理出水达到《城镇污水处理厂污染物排放标准》(GB 18918-2002)一级A标准,出水用于农村绿化和农灌,经济效益和环境效益明显。     

Plant steroid hormones produced under Ni stress are involved in the regulation of metal uptake and oxidative stress in Brassica juncea L

Brassinosteroids (BRs) are involved in the amelioration of various biotic and abiotic stresses. With an aim to explore the role of BRs under heavy metal stress, plants of Brassica juncea L. were grown in pots. The plants were subjected to various concentrations of Nickel metal (0.0, 0.2, 0.4 and 0.6 mM) and harvested on 60th day in order to observe the expression of these hormones. The isolated BRs from the leaves of Brassica plants characterized by GC-MS include 24-Epibrassinolide (24-EBL), Castasterone, Dolicholide and Typhasterole. The effect of isolated 24-EBL was studied on Ni metal uptake and antioxidative defense system in 60 d old plants of Brassica. It was observed that 24-EBL significantly increased the activities of stress ameliorating enzymes and lowered the metal uptake in plants. This is the first report in B. juncea L. plants showing the expression of BRs under metal treatments and effect of the isolated 24-EBL on metal uptake and in oxidative stress management.     

人力资本、社会资本与市民化抑制

新生代农民工问题的终结是市民化,但是目前许多新生代农民工存在市民化阻碍,这不利于我国城市化进程的推进和经济的持续健康发展。对沈阳和余姚两地区进行了案例调查,得到了两地区新生代农民工的调查数据。运用调查数据,首先采用需求可识别的biprobit模型对新生代的农民工市民化抑制程度进行了测度,并预测出新生代农民工个体的市民化抑制程度。在对新生代农民工个体的市民化抑制程度指标进行分位数回归分解的基础上,分析了人力资本和社会资本对新生代农民工市民化抑制程度的影响,以期促进新生代农民工的城市融入。研究发现:新生代农民工的社会资本水平是影响其市民化的关键因素,人力资本水平的提高只有在市民化抑制程度高于80%时才会使市民化抑制程度下降。因此,相应的政策建议为,政府应加强新生代农民工城市公共服务的享用水平;发展和健全农民工工会组织;在市民化抑制程度较高的地区应特别加强新生代农民工职业技能的培训。     

江苏沿海风能资源禀赋与开发利用研究

江苏沿海地区拥有丰富的风能资源,开发前景十分广阔,尤其是中部、南部地区拥有广阔的沿海滩涂和辐射沙洲,建设沿海风电场的条件优越,是打造江苏"海上三峡"新能源基地的希望所在。阐述了江苏沿海风能资源开发的重要意义,分析了沿海风能资源的禀赋与时空分布特点,指出江苏沿海岸区风能资源丰富,且沿海滩涂宽广,是建立大型风力发电场的理想之地,在此基础上提出发展江苏沿海绿色能源基地的构想。     

中小型工业窑炉NOx废气的净化技术与应用

介绍了中小型工业窑炉生产过程中排放NOx的现状,并针对NOx的治理问题,从工程应用角度,简述了湿法和干法净化NOx的原理和化学反应过程。讨论了NOx排放特性和NOx废气中NO2/NOx比例的问题。提出了影响NOx治理的主要因素,包括吸收剂、吸附剂、催化剂和设备的部分应用参数,并结合工程实例指出工程需要注意的问题。介绍了多项采用湿法和干法净化NOx的工程应用项目,丰富了中小工业窑炉NOx废气的治理的实践经验,为中小工业窑炉排放NOx治理奠定了基础。