现代分析技术在水质氨氮监测中的应用分析

在水质监测中,氨氮的监测是十分重要且常见的项目之一。氨氮是释放游离氨的主要源头,而游离氨的含量上升是导致水体富营养的元凶之一,因此,监测水体中氨氮的含量是水环境监测工作的主要内容之一。随着环保意识的增强,我国开始越来越重视对自然环境的监测工作,也逐渐认识到氨氮在水体中导致的危害,开始积极开发和应用分析技术,用于监测水体中氨氮的含量及其变化趋势,为后续的资源保护、污染质量工作奠定基础。本文从常见的现代分析技术入手,分析并探讨现代分析技术在水质氨氮监测中的具体应用方式,希望可以为提升我国水质监测工作质量提供一些思路。     

Environmental Impact on Coastal Waters off Rio De Janeiro Due to Sewage Discharge via Submarine Outfall

A survey was made in an area of 28 km² around the outlest of Ipanema's submarine outfall in order to evaluate the impact of the raw domestic sewage effluent on coastal waters. Nutrient concentrations, dissolved oxygen, particulate matter and other physico-chemical parameters were measured monthly for 15 months. Copper and lead concentrations were also determined for two of the samplings.

The outfall has been in operation for 18 years, and the parameters measured within the observation area appear to be in steady state. From the observed radial concentration gradients within the survey area, a real extension of the steady state distribution of particulate matter and of sewage-derived nitrogen was estimated. the stationary cloud of particulate organic matter was about 150 km². From its total inventory and the discharge rate, a mean residence time of the particles in the sea of 56 days is estimated, prior to their being decomposed by bacterial action or settling to the bottom. for sewage derived N (as ammonia or nitrate), the steady state amount (above background) covers an area of about 60 km² and leads to a mean residence time of 5 ± 1 days in the ocean. Phosphorus is readily absorbed by the phytoplankton.

The presence of temperature gradients established by cold upwelling waters controls the dispersion of the sewage material and the rising of the sewage plume to the surface waters.     

La_(2-x)Sr_xCuO_(4±λ)系列催化剂的合成、表征及NO分解催化性能的研究

合成了x值不同的 La_2.x_Sr_xCuO_(4±λ)(x=0.0—1.0)系列复合氧化物催化剂.用XRD、IR,XPS和化学分析等方法对催化剂的组成、结构进行了表征,并对NO分解的催化性能和作用机理进行了研究.结果表明:在x=0.0—1.0范围内.所有样品都具有A_2BO_4结构.发现NO分解活性与氧空位(缺陷)的浓度有关,与不同价态的Cu离子含量之间无直接关系.     

Variations in the chemical properties of landfill leachate

Landfill leachates were collected and their chemical properties analyzed once every two months over a ten-month period from the Gin Drinkers' Bay (GDB) and Junk Bay (JB) landfills. The contents of solids, and inorganic and organic components fluctuated considerably with time. In general, the chemical properties of the two leachates correlated negatively (P<0.05) with the amounts of rainfall prior to the sampling periods. However, magnesium and pH of the leachates remained relatively constant with respect to sampling time. The JB leachate contained higher average contents of solids and inorganic and organic matter than those of GDB with the exception of trace metals. Trace metals were present in the two leachates in trace quantities (<1.0 mg/liter). The concentrations of average ammoniacal nitrogen were 1040 and 549 mg/liter, while chemical oxygen demand (COD) values were 767 and 695 mg/liter for JB and GDB leachates, respectively. These results suggest that the leachates need further treatment before they can be discharged to the coastal waters.     

被动扩散技术在环境空气监测中的应用

被动扩散监测技术以其成本低、布点灵活、操作简单，易于掌握等特点在世界各地广泛应用于环境空气质量监测。辽宁省环保局通过欧盟项目引入，盘锦市试点表明SO2和NO2各月变化趋势和各功能区监测结果与我市自动站监测结果相一致。可以弥补自动监测点位不足和开展大范围多点位监测。     

连续流间歇曝气工艺的氮磷脱除功能研究

连续流间歇曝气工艺是在对传统活性污泥法的改造中发展起来的一种工艺。本文针对该工艺的氮磷脱除功能进行了小试研究 ,由试验结果可看出 ,连续流间歇曝气工艺简便易行 ,去除有机物及氨氮的效果稳定 ,在碳源满足脱氮除磷要求的条件下 ,可达到良好的氮磷脱除效果     

土壤氮素及其环境效应

本文概述了土壤中含氮化合物的排放源、通量及其对环境的主要影响 ,并就这些氮素污染物与土壤理化因子和氮肥施用量之间的关系进行了简要的分析     

徐州市奎河河流--地下水渗流系统处理水体中氮

基于污水土地处理系统可以渗漏形式补给地下水的特点，利用现场调查分析的方法，提出了一种新的污水土地处理方式－河流－地下水渗流系统去除污水中氮。结果表明，河流－地下水饱和渗流系统对氮污染组分具有很高的去除作用，在距河流４０ｍ处对污水中氮的去除率达９５％以上，且不受季节变化的影响。     

悬浮态污泥的SRT对复合式A2/O工艺性能的影响

采用厌氧/缺氧/好氧复合工艺(复合式A2/O工艺)及其对照工艺(传统A2/O工艺),进行了悬浮态污泥SRT的变化对系统性能影响的试验研究结果表明,悬浮态污泥浓度与其SRT的关系仍符合劳伦斯-麦卡蒂方程式的导出公式所反映的变化趋势,但其同时和反应器中填料上的生物膜数量呈相反变化趋势在总HRT为12.76 h、COD容积负荷小于1.5kg·m-3·d-1、TKN容积负荷小于0.13kg·m-3·d-1、悬浮态污泥SRT为25～5 d、水温为12～15 ℃时,悬浮态污泥SRT的变化对COD的去除几乎没有影响,出水COD均小于50 mg·L-1;但SRT的变化对氮和磷的去除有较大的影响,当悬浮态污泥SRT大于10 d时,出水NH4+-N和TN浓度分别低于15 mg·L-2和20mg·L-1,随SRT的增大,TP的去除效率下降;附着态生物膜参与硝化过程,能够提高系统总的NH4+-N去除率20%～30%.悬浮态污泥SRT宜控制为10～15 d,这可在一定程度上解决或缓解传统A2/O工艺中硝化和除磷过程对污泥龄要求的矛盾.