La1-xKxMnO3催化剂同时消除柴油机尾气中NO和碳烟性能

采用溶剂热法制备La_1-xK_xMnO₃(x=0, 0.10, 0.15, 0.20, 0.25)钙钛矿型复合金属氧化物催化剂;通过XRD、FT-IR、SEM、H₂-TPR、XPS、NO-TPD等手段对催化剂的物相组成、表面形貌、氧化还原性能等进行了表征;在常压固定床微型反应装置中评价催化剂同时消除NO和碳烟催化性能.结果表明,制备的La_1-xK_xMnO₃催化剂均具有钙钛矿结构;K部分取代La-Mn钙钛矿结构中La后,颗粒结构得以改善,部分Mn³⁺价态升高为Mn⁴⁺,形成较多氧空位和Mn⁴⁺,提高氧化还原性能和吸附NO性能.活性评价结果表明,La_0.80K_0.20MnO₃催化剂表现出较好的同时消除NO和碳烟催化性能,NO最大转化率(Xmax NO)和对应反应温度(Tmax NO)分别为46.5%和436℃,碳烟起燃温度(T_ig)、CO₂浓度峰值温度(Tmax CO₂)和生成CO₂选择性(Smax CO₂)分别为341℃、454℃和98.8%.     

离子型稀土尾矿残留铵缓释性分析

为探究尾矿残留NH₄⁺的缓释性,以江西信丰离子型稀土矿为研究对象,柱浸制备浸出尾矿,去离子水淋洗尾矿.按照淋洗→封存→再淋洗的步骤,考察了淋洗尾矿不同含水率（1.3%,15%,35%,250%）,不同封存时间（15,30,60,120,180,195,210,240d）和不同传质机制（对流、扩散）下NH₄⁺的淋出量.结果表明：尾矿再淋洗仍能淋出NH₄⁺,NH₄⁺淋出量受含水率、封存时间和传质方式影响;含水率≥15%时,NH₄⁺淋出量整体随时间推移而递增;同时间下,NH₄⁺淋出量整体随含水率增大而增大;其他条件相同时,对流传质下NH₄⁺淋出量大于扩散.尾矿再次淋出的NH₄⁺是可交换态NH₄⁺向水溶态NH₄⁺转化的结果.     

Oversight of shale gas production in the United States and the disclosure of toxic substances

With the encouragement of shale gas production in the United States, governments have considered a range of legislative and regulatory proposals to manage health and environmental damages that may accompany extraction activities. Exceptions adopted by Congress to major federal environmental legislation have meant that individual US states have deemed it necessary to provide oversight through regulations to protect people and safeguard environmental quality. In responding, states have legal structures under which drilling firms may not need to disclose the toxic substances used in fracturing wells. Yet, with increasing numbers of drilling sites, more people are at risk from accidents and exposure to harmful substances used at fractured wells. To provide for meaningful health and safety protection, governments may need to reevaluate legal provisions offering trade secret protection for toxic substances used in fracturing.     

Nitrification performance evaluation of activated sludge under high potassium ion stress during high-ammonia nitrogen organic wastewater treatment

The recycling reverse osmosis（RO） membrane concentrate of some high-ammonia nitrogen（NH₄⁺-N） organic wastewater to the biological unit could cause potassium ion（K⁺） accumulation, thereby affecting the removal of NH₄⁺-N by activated sludge. Thus, the effects of high K⁺ stress on activated sludge nitrification performance was studied. The results showed that the high K⁺ stress promoted the floc sludge to produce more extr...     

INTERACTIVE DISTRIBUTED CONSERVATION PLANNING1

ABSTRACT: In the environmental and agricultural conservation planning process, more efficient and effective tools are needed for planners to assist private landowners with making wiser land use decisions. Current methods are slow, inefficient, and costly. Scientific techniques have not been fully implemented within the planning process, yet such plans are increasingly needed to meet water quality and Total Maximum Daily Load (TMDL) requirements. The objectives of this study are to (a) utilize the web for accessing an integrated science‐based land use decision support system; (b) link decision tools, models, and databases to the user via the web; (c) link distributed models and databases for enhanced planning efficiency; and (d) integrate the above into an easily usable and readily accessible system. The procedures resulting in the initial design involved planning expertise and focus groups' input. The system was developed in partnership with the Natural Resources Conservation Service of the U.S. Department of Agriculture and several state agencies. A survey of 150 certified conservation planners, the end users, was conducted to identify the data sets and planning tools needed. Data, tools, and models then were selected and integrated into a web accessible system. Specifically, the first generation used a web interactive Geographic Information System (GIS) that overlaid onto digital orthoquads and/or soils polygons field boundaries, transportation, hydrologic features (such as drains, rivers, lakes, etc.), and high pesticide risk runoff or infiltration areas. Conservation planners found they could save time with the system. Clients could access the system quickly to help them prepare for meeting with their planner. Previously acquiring GIS maps in some cases had been a lengthy process that limited use of the information in land use decisions.     

城市污水进行水稻免耕栽培减轻面源污染可行性研究

利用城市污水进行水稻免耕栽培，培育人工经济湿地，通过消耗城市污水中的污染物，减少化肥农药施用量，减轻滇池污染。既产生一定的经济效益，又有利于滇池面源污染治理工作开展和环滇沿岸农业经济的持续发展。     

富氧条件下氢部分选择性催化还原NO研究

研制成功了低钯含量活性非均布Pd Al2 O3催化剂 ,实现了富氧条件下 ,氢部分选择性催化还原NO过程。实验表明在该催化剂上 ,低温、富氧条件下NO的转化率高达 80 %～ 10 0 %。室温下 (～ 2 0℃ ) ,NO对氢氧反应有强烈的抑制作用 ,氢氧反应进行后 ,NO还原反应开始明显进行 ,其与氢氧反应为竞争的平行反应     

农业非点源模型——AGNPS计算

由于非点源污染产生机制的特殊性，导致实地调查和试验研究不易实行。而数学模型方法在这一领域尤其能够体现出它的优点，其中AGNPS模型是应用较为广泛者之一。介绍了AGNPS模型的基本结构，主要包括水文、侵蚀和化学污染物的迁移3部分。     

非调质钢的特性及在汽车上的应用

综述了非调质钢的工艺性能和力学性能及在汽车上的应用.说明非调质钢具有切削加工性能良好,可实施焊接和表面处理;节约能源、简化生产工序、大幅度降低成本等优点.     

化工项目无组织废气评价探讨

化工项目无组织废气具有排放量小、种类多、排放点广、难以量化等特点。无组织废气的评价是化工项目环评的重要组成部分，评价的主要思路是找出排放源、筛选出主要的排污环节和污染因子、确定排放源强、科学公正地作出评价结论。通过实例说明了做好无组织废气评价在实践环评工作中的重要性。