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《环境科学学报(英文版)》2023,35(4):494-505
Single particle-inductively coupled plasma mass spectrometry (SP-ICP-MS) is a powerful tool for size-characterization of metal-containing nanoparticles (MCNs) at environmentally relevant concentrations, however, coexisting dissolved metal ions greatly interfere with the accuracy of particle size analysis. The purpose of this study is to develop an online technique that couples hollow fiber ultrafiltration (HFUF) with SP-ICP-MS to improve the accuracy and size detection limit of MCNs by removing metal ions from suspensions of MCNs. Through systematic optimization of conditions including the type and concentration of surfactant and complexing agent, carrier pH, and ion cleaning time, HFUF completely removes metal ions but retains the MCNs in suspension. The optimal conditions include using a mixture of 0.05 vol.% FL-70 and 0.5 mmol/L Na2S2O3 (pH = 8.0) as the carrier and 4 min as the ion cleaning time. At these conditions, HFUF-SP-ICP-MS accurately determines the sizes of MCNs, and the results agree with the size distribution determined by transmission electron microscopy, even when metal ions also are present in the sample. In addition, reducing the ionic background through HFUF also lowers the particle size detection limit with SP-ICP-MS (e.g., from 28.3 to 14.2 nm for gold nanoparticles). This size-based ion-removal principle provided by HFUF is suitable for both cations (e.g., Ag+) and anions (e.g., AuCl4−) and thus has good versatility compared to ion exchange purification and promising prospects for the removal of salts and macromolecules before single particle analysis. 相似文献
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脉冲电晕等离子法烟气脱硫脱硝的研究 总被引:1,自引:0,他引:1
本文探讨了脉冲电晕等离子法脱硫脱硝的基本原理,较系统地研究了影响脉冲电晕等离子烟气脱硫脱硝的主要因素,进行了加NH3脱硝的探索试验。实验表明:该法能有效地去除烟气中的SO2,但脱硝效果不明显,加NH3后可大量提高脱硝的效率;湿度对脱硫影响较大,湿度越高,脱硫效率也越高,当相对湿度达80%时,脱硫率基本达到最大,而湿度对脱硝的影响不如脱硫明显;脉冲电压越高,功率越大,脱硫脱硝效率越高;增加放电极长度 相似文献
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Tobias J. Legler Zhong Liu Ariadni Mavrou Kirstin Finning Ilona Hromadnikova Silvia Galbiati Cathy Meaney Maj A. Hultén Francesco Crea Martin L. Olsson Deborah G. Maddocks Dorothy Huang Sylvia Armstrong Fisher Markus Sprenger-Haussels Aicha Ait Soussan C. Ellen van der Schoot 《黑龙江环境通报》2007,27(9):824-829
Objective Cell free foetal DNA (cff DNA) extracted from maternal plasma is now recognized as a potential source for prenatal diagnosis but the methodology is currently not well standardized. To evaluate different manual and automated DNA extraction methods with a view to developing standards, an International Workshop was performed. Methods Three plasma pools from RhD-negative pregnant women, a DNA standard, real-time-PCR protocol, primers and probes for RHD were sent to 12 laboratories and also to one company (Qiagen, Hilden, Germany). In pre-tests, pool 3 showed a low cff DNA concentration, pool 1 showed a higher concentration and pool 2 an intermediate concentration. Results The QIAamp DSP Virus Kit, the High Pure PCR Template Preparation Kit, an in-house protocol using the QIAamp DNA Blood Mini Kit, the CST genomic DNA purification kit, the Magna Pure LC, the MDx, the M48, the EZ1 and an in-house protocol using magnetic beads for manual and automated extraction were the methods that were able to reliably detect foetal RHD. The best results were obtained with the QIAamp DSP Virus Kit. The QIAamp DNA Blood Mini Kit showed very comparable results in laboratories that followed the manufacturer's protocol and started with ≥ 500 µL plasma. One participant using the QIAamp DNA Blood Midi Kit failed to detect reliably RHD in pool 3. Conclusions This workshop initiated a standardization process for extraction of cff DNA in maternal plasma. The highest yield was obtained by the QIAamp DSP Virus Kit, a result that will be evaluated in more detail in future studies. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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降低汽油机冷起动阶段有害排放的技术措施 总被引:2,自引:0,他引:2
在汽油机的一个测试循环中,约占排放污染物总量70%~80%的非甲烷碳氢化合物是在汽油机冷起动阶段没有经催化转化而直接排入大气中,造成严重污染。研究探讨了使用高效汽油添加剂、催化器减少汽油机冷起动排放污染物的机理和实况,进而提出了一些可行的实用方案。 相似文献
710.