多点法测定可燃物质自燃特性的可靠性研究

多点法是一种新提出的自热反应动力学分析方法。采用实验研究和理论分析相结合的方式对多点法的操作过程以及实验结果的可靠性展开研究。通过构建一维导热系统、采用不同形式的热电偶布设方式,对烟叶粉末的自燃临界环境温度、活化能以及反应热与指前因子的乘积等参数进行了测定。研究表明:所构建的一维系统能较好地模拟一维导热;热电偶的分布方式对测量结果有较大影响,对称分布状况下,温度结果与经典的F-K对称模型一致;多点法相比于传统方法省时省力,测定结果有较好的线性拟合相关度,求解的动力学参数较为可靠。     

The derivation of radionuclide transfer parameters for and dose-rates to an adult ringed seal (Phoca hispida) in an Arctic environment

Radionuclide transfer parameters and dose-rates for an adult ringed seal from Svalbard have been determined based on empirical and estimated tissue activity concentrations and detailed dietary and habitat information. Whole-body equivalent concentration factors determined for anthropogenic radionuclides ranged from 10(1) ((90)Sr) to 10(2) ((137)Cs, (238)Pu and (239,240)Pu), while natural radionuclides ranged from 10(2) ((210)Pb) to 10(4) ((210)Po). Employing a dietary composition of 40% fish, 40% zooplankton and 20% benthic invertebrates, a whole-body biological half-life of 29 days was derived for (137)Cs. A total dose-rate of approximately 0.19microGyh(-1) (1.7mGya(-1)) was derived for an adult ringed seal; this dose-rate is virtually entirely attributable to the internal components of (210)Po and (40)K. The dose-rates associated with the presence of anthropogenically derived radionuclides in the present assessment fall many orders of magnitude below the dose-rates at which any biological effects would be expected.     

Respirometric Monitoring for the Determination of Effective Height and Reaction Rate Constant in Up-Flow Autotrophic Denitrification Reactor Packed with Sulfur

A novel technology for the removal of nitrogen from wastewater, autotrophic denitrification process with sulfur particle, has been developed. A respirometer was employed for the monitoring of nitrogen gas produced in the reactor. It was found that the autotrophic denitrification studied by gas production rate and nitrate depletion rate followed a first order reaction from the relationship. The reaction rate constant based on effective volume, k_N was ranged from 2.67 to 3.07 h^–1. The effective height was around 23.8 and 50% of the total height for 11.8 and 5.9 h of packed bed contact time, respectively. It was assumed that the reaction rate constants were similar in each experimental condition, PBCT = 11.9 and 5.9 h because there was little gradient of biomass concentration within 50% of the total height. The respirometry was found to be a simple and fast way to monitor the denitrification process. The method was especially useful for the determination of kinetic parameters.     

兰江流域水文动力参数变化与兰江防洪

本文根据钱塘江重要干流兰江的地面蓄水累计曲线SPER、流域入渗曲线Holton公式参数(入渗率f、稳定入渗率fc、入渗比例系数k)、Maskingum指数(流水河段传播时间k、楔蓄系数x)、水位与水量等近30年的抽样数据,分析了兰江流域河槽导流环境、植被条件、土地性质、气象因素的变化,指出了该河段近年来洪水频发的原因,提出了治理建议.     

长江南通段江面风的观测分析

通过在长江南通段江面、江岸建立风观测站,并在江岸建设80m高的风梯度观测塔,与邻近气象站开展了较长时间的风同步观测,获得了实地观测数据.利用同步风观测数据进行对比分析,揭示出长江南通段江面风的观测事实,并利用风梯度观测资料,分析给出了风随高度的变化规律.在此基础上,结合邻近气象站长年的风观测资料,推算了该处的设计基本风速及其他工程设计风参数.分析表明,该处江面风况明显有别于邻近气象站,风参数计算结果也明显高于风工程理论推算值.     

MapInfo在合肥遥测台网地震速报中的初步应用

MapInfo是目前流行的地理信息系统 (GIS)应用软件之一 ,由于其强大的地图功能 ,在地震监测预报中得到了越来越广泛的应用。安徽省地震局合肥遥测台网不久前完成了台网自己的速报软件的开发研制工作 ,其中运用了MapInfo部分图形操作功能。本文介绍MapInfo技术在台肥遥测台网地震速报中的一些具体应用     

液相络合-铁粉还原-酸吸收回收法脱除烟气中NO

提出了Fe2+螯合剂络合-铁粉还原-酸吸收回收法脱除烟气中NO的新工艺,重点研究了模拟烟气中O₂含量对NO络合量的影响,以及铁粉用量、铁粉粒径和搅拌速度对脱氮效率的影响,确定了最佳的铁粉脱氮工艺条件,并对铁粉和铁屑的脱氮效果进行了比较.结果表明:烟气中φ(O₂)从0增加到4.2%,NO络合量下降90.2%;脱氮效率随铁粉用量和反应器搅拌速度的增加而增加,随铁粉粒径的增加而降低;最佳工艺参数为,铁粉用量0.8 g,铁粉粒径≥200目(≤0.077 mm),搅拌速度900 r/min,在该条件下,对φ(O₂)为5%的模拟烟气在搅拌反应器中可取得90%以上的脱氮效率;用铁粉在1台搅拌反应器中取得的脱氮效率和用铁屑在2个鼓泡反应器串联时所取得的效率相当.      

Metal pollution status of Tajan River – Northern Iran

The monitoring of surface water quality of rivers is crucial to protect aquatic life and receiving water bodies of economic importance. The aim of the current study was to examine selected physicochemical parameters of River Tajan due to its ecological importance in Iran. Water samples from nine points covering the entire Tajan River and Caspian Sea estuary were collected and analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS), carbonates, chlorides and selected heavy metals including zinc, cadmium, lead and chromium. The pH and levels of EC, TDS, chlorides, carbonates and all metals were within the USEPA reference guidelines for surface water quality standards. Although these water quality parameters are considered safe, continuous monitoring and assessment is recommended in order to protect the coastal receiving waters of Caspian Sea which serves as a tourist attraction in northern Iran.     

汽车尾气的初期扩散与扩散参数

通过风洞模拟实验,分析研究汽车尾流区的流场特性,确定了汽车机械扰动产生的尾气初期扩散范围,提出了一种考虑初期扩散影响的确定近距离扩散参数的简易方法。现场示踪实验和实测资料的验证表明,用该方法确定尾气扩散参数是可靠的。     

溶剂萃取法提取电镀污泥氨浸出渣中的金属资源

研究硫酸浸出Ｐ５０７－煤油－硫酸体系萃取分离铁,钠皂－Ｐ２０４－煤油－硫酸体系共萃铬、铝、反萃取分离铬、铝工艺回收电镀污染氨浸渣中的金属。通过优化实验,确定了全流程的最佳工艺参数。结果表明,铁铬渣中的金属铬、铝和铁均可以高纯度盐类形式回收,可作为化学试剂使用,回收率达９５％以上。