北京山区公路地质灾害应急与防治对策

北京是地质灾害较严重的城市之一,具有灾种多、活动频繁、群发性强的特征。北京山区公路所遭受的地质灾害主要有滑坡、滑(崩)塌、泥石流、岩溶、采空地面塌陷等。为了防止山区公路地质灾害可能造成的危害,笔者通过对北京山区公路所遭受的地质灾害类型、发育特征、分布规律等特点及其所造成的危害进行分析、研究,提出了山区公路地质灾害应急与防治对策,以提高北京市的防灾减灾能力,减少和避免地质灾害造成的损失。     

泵串联水灭火系统在森林防火方面的应用

现阶段为了适应国际及国内防火形势,出现了以水灭火为主要形式的灭火方式,并且在实际灭火中体现出巨大的优势.其中泵串联水灭火就是一种很好的形式.林海集团设计了一套远距离接力水泵串联供水灭火系统,尝试以手抬水泵(消防泵)接力供水的方式,从有水源的地方经过消防泵的增压,通过消防水带输送到火场,为水灭火工作提供条件,以实现水灭火.     

石油化工生产火灾隐患及预防对策

石油化工企业自身的生产、设备等特点决定了这类企业存在着一些特有的火灾隐患,这些隐患给安全生产带来了极大的威胁.因此,正确剖析和认识石油化工企业特有的火灾隐患,积极采取预防对策是石油化工企业安全工作的一项重要内容.     

Metabolic fate of the 14C-labeled herbicide clodinafop-propargyl in soil

The metabolic fate of ¹⁴C-phenyl-labeled herbicide clodinafop-propargyl (CfP) was studied for 28 days in lab assays using a soil from Germany (A_p horizon, silt loam, and cambisol). Mineralization amounted to 12.40% of applied ¹⁴C after 28 days showing a distinct lag phase until day 7 of incubation. Portions of radioactivity extractable by means of 0.01 M CaCl₂ solution (bioavailable fraction) decreased rapidly and were 4.41% after 28 days. Even immediately after application, only 57.31% were extracted with the aqueous solvent. Subsequent extraction using accelerated solvent extraction (ASE; acetonitrile/water 4:1, v/v) released 39.91% of applied ¹⁴C with day 0 and 26.16% with day 28 of incubation from the samples. Non-extractable portions of radioactivity thus, increased with time amounting to 11.99% (day 0) and 65.00% (day 28). A remarkable increase was observed between 14 and 28 days correlating with the distinct increase of mineralization. No correlation was found throughout incubation with general microbial activity as determined by DMSO reduction. Analysis of the CaCl₂ and ASE extracts by radio-TLC, radio-HPLC and GC/MS revealed that CfP was rapidly cleaved to free acid clodinafop (Cf), which was further (bio-) transformed; DT₅₀ values (based on radio-TLC detection of the parent compound) were far below 1 day (CfP) and about 7 days (Cf). TLC analysis pointed to 2-(4-hydroxyphenoxy)-propionic acid as further metabolite. Due to fractionation of non-extractable residues, most of the ¹⁴C was associated with fulvic and humic acids, portions in humin fractions and non-humics were moderate and low, respectively. Using a special strategy, which included pre-incubation of the soil with CfP and then mineralization of ¹⁴C-CfP as criterion, a microorganism was isolated from the soil examined. The microorganism grew using CfP as sole carbon source with concomitant evolution of ¹⁴CO₂. The bacterium was characterized by growth on commonly used carbon sources and by 16S rDNA sequence analysis. The sequence exhibited high similarity with that of Rhodococcus wratislaviensis (99.56%; DSM 44107, NCIMB 13082).     

Mobility and sulfidization of heavy metals in sediments of a shallow eutrophic lake, Lake Taihu, China

The technique of DGT (diffusive gradients in thin films) using three diffusive gel thicknesses was applied to estimate the mobility and bioavailability of heavy metals in sediments and porewater of Lake Taihu, China. The DGT results showed significantly positive correlations between Co, Pb, Cd and Mn, and Ni and Fe concentrations in porewater. Cu and Zn showed a significantly negative correlation with Mn, due to Cu combination with carbonates and Zn derived from agricultural pollution, respectively. The rank order of average concentrations of Co, Ni and Cd at each station was DGT_1.92 > DGT_0.78 > DGT_0.39, suggesting stronger resupply from sediments to porewater when using thicker diffusive gels. Comparing centrifugation and DGT measurements, Co, Ni and Cd are highly labile; Mn and Fe are moderately labile; and Cu, Zn and Pb are slightly labile. The variations of AVS concentrations in sediment cores indicate that metal sulfides in deeper layers are easily diffused into surface sediments.     

露天矿山岩质边坡台阶的平台宽度优化

矿山发生局部破坏的边界条件主要是由台阶的几何特征所决定,台阶边坡几何特征主要有台阶坡面角、台阶高度、台阶的平台宽度和台阶组合4要素。在对整体边坡角优化的同时,同样需要对台阶的宽度进行优化。通过分析台阶边坡特征,计算出不同规模破坏的边界条件,进而对矿山台阶的宽度进行优化。通过对一个矿山边坡算例的优化分析,在不改变整体边坡角的前提下,对台阶宽度进行优化,可以避免某些大规模的台阶破坏可能,提高矿山边坡的稳定性。     

石英砂加工企业职业病危害防护措施与管理对策研究

通过对安徽省石英砂加工企业生产工艺流程和现场进行调查分析,得出矽尘和噪声是两种最主要的职业病危害因素,发现石英砂生产企业矽尘和噪声危害十分严重,生产作业现场未配备任何防护装备和个人防护用品,作业人员接触职业病危害的比率非常高。分析了石英砂加工企业在职业病危害防护与管理方面的欠缺与不足,提出了针对矽尘和噪声危害因素的具体工程防护措施与管理对策,从源头控制和消除职业病危害,保护劳动者的生命安全与健康。     

综放工作面沿空留巷支护阻力研究

为了计算综放工作面沿空留巷支护阻力,以结构力学理论为基础,分析综放工作面沿空留巷支护阻力计算模型,建立沿空留巷围岩和支护体的结构力学模型,应用超静定结构和静定结构分析支护体与沿空留巷围岩相互作用机制,推导出巷旁支护阻力的计算公式.结果表明,进行沿空留巷支护阻力力学分析时,要考虑顶板极限断裂前和断裂后两种状态下的受力情况,支护阻力与岩层厚度、容重、煤体极限平衡区宽度、跨距、支护体宽度和巷道宽度等因素密切相关.工业性试验表明,该技术的应用是成功而有效的.因此,综放巷内沿空留巷围岩结构力学模型和支护阻力计算公式是合理的,可在类似条件的综放工作面中应用.     

离子液体对CO2吸收性能的研究进展

CO2引起的气候变暖已成为全球最关注的环境问题之一,利用离子液体固定CO2引起了众多学者的关注。介绍了近年来离子液体吸收CO2的研究进展,包括常规离子液体和含氨基离子液体、氨基酸离子液体、聚离子液体及其他离子液体等4种功能化离子液体,并简要分析了吸收机理。综合分析了每种离子液体的吸收性能,离子液体对CO2的吸收能力均随温度上升而减小,随压力升高而增加。烷基链的增长以及含氟基团的增加有利于对CO2的吸收。功能化离子液体由于引入了功能化基团,相同条件下,其对CO2的吸收力几乎是常规离子液体的两倍。此外,将离子液体与有机溶液(特别是醇胺溶液)混合能提高离子液体对CO2的吸收能力,且能降低生产费用。最后指出了高吸收性能、低黏度、低毒以及低成本是未来离子液体的研究方向。     

生物表面活性剂产生菌处理水体石油污染物的研究

为研究水体石油污染物的生物处理方法,通过富集培养、蓝色凝胶平板分离初筛、摇瓶复筛等方法从长期被石油污染的油泥中筛选生物表面活性剂产生菌.采用薄层层析显色法和红外光谱法鉴定该菌所产表面活性剂种类,测定表面活性剂的乳化性能、表面张力和临界胶束浓度等性能,并对菌株降解水体石油污染物的影响因素及效果进行了研究.结果表明,筛选出的生物表面活性剂高产菌株LJ2所产表面活性剂为糖脂,其乳化指数为33％,25℃下可将水的表面张力从71.14 mN/m降至27.22 mN/m,临界胶束质量浓度为5 mg/L;当表面活性剂水溶液质量浓度为100 mg/L时,其乳化指数可达50％.温度、降解时间以及NaCl质量分数对菌株LJ2处理水体石油污染效果影响很大.在34℃条件下处理5d,菌株LJ2对质量浓度为2 g/L的水体石油污染物的降解率高达99.5％.研究表明,生物表面活性剂产生菌L J2对水体石油污染物有良好的降解效果,而且该菌还对水体中较高浓度的NaCl有一定的耐受性.