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491.
渭河宝鸡市区段阴离子表面活性剂污染研究 总被引:2,自引:0,他引:2
本文采用改进的亚甲蓝分光光度法,对渭河宝鸡市区段阴离子表面活性剂进行监测分析。测定结果表明:渭河在进入宝鸡市至植物园断面时阴离子表面活性剂含量较低,日平均值为0.049mg/L,达到地面水环境质量I类标准(≤0.2mg/L)(GB3838-88.地面水环境质量标准);在流经市区新世纪桥、渭河桥断面时,由于分别有清姜河和金陵河两个支流的汇入,污染越来越严重.在这两个断面阴离子表面活性剂含量日平均值分别为0.34mg/L和0.54mg/L;在即将流出宝鸡市的斗鸡断面阴离子表面活性剂含量日平均值为0.424mg/L,已远远超过地面水环境质量V类标准(≤0.3mg/L)(GB3838-88,地面水环境质量标准)。从监测结果看:双休日阴离子表面活性剂含量普遍高于工作日;清姜河、金陵河污染严重,这两条支流的汇入对渭河水质影响巨大,要治理好渭河,须先治理好清姜河和金陵河这两条支流。 相似文献
492.
493.
494.
城市生活垃圾渗透系数测试研究 总被引:7,自引:0,他引:7
采用常水头测渗实验,对不同压实密度和水力梯度下的新鲜垃圾与陈垃圾的渗透系数进行测试,根据达西定律求得渗透系数值。由于垃圾的不均匀性、小颗粒的运动和大孔隙沟道流的形成和改变,实验初始阶段渗透系数值先增大至峰值,然后缓慢降低直至趋于稳定。实验稳定后,新鲜垃圾压实密度为0.75—0.95t/m^3时,渗透系数值约为1.26E-03~1.43E-03cm/s。陈垃圾在压实密度分别为1.2和1.4t/m^3时,渗透系数为8.29E-04和1.35E-04cm/s。 相似文献
495.
A classical way to obtain three-fluid retention curves in porous media from measured two-fluid retention curves is based on the Leverett concept, which states that the total volumetric liquid content in a water-wet porous medium, containing water, a nonaqueous-phase liquid (NAPL) and air, is a function of the capillary pressure across the interface between the continuous NAPL and air. This functional relationship results from the assumed condition that in a three-fluid porous medium, the intermediate wetting fluid spreads over the water-air interface. Application of Leverett's concept may not be valid, however, for nonspreading NAPLs like perchloroethylene (PCE). This paper discusses measurements of both PCE-air and water-PCE-air retention curves using a long vertical column in conjunction with a dual-energy gamma radiation system. The data indicate that the Leverett concept was applicable only until a critical PCE saturation had been reached. 相似文献
496.
Dirk Bunke 《Umweltwissenschaften und Schadstoff-Forschung》2003,15(2):106-114
Zusammenfassung Zur Quantifizierung des Gefahrstoffeinsatzes in der Produktion ist im Rahmen der integrierten ?kologischen Bewertung des ?ko-Institutes
(EcoGrade) eine eigene Methodik entwickelt worden. Indikator für den Gefahrstoffeinsatz sind Monoethylenglykol (‘MEG’)-?quivalente.
Sie erm?glichen einen direkten, schadstoffbezogenen Prozess- und Produktvergleich (Bunke 2001). Die Bewertung basiert auf
den R-S?tzen (Gefahrenhinweise) der Inhaltsstoffe. Die Methodik der MEG-?quivalente stellt eine Weiterentwicklung und Anwendung
des Wirkfaktorenmodells der Technischen Regel für Gefahrstoffe (TRGS) 440 dar (AGS 2001). Die zur Bewertung erforderlichen
Daten sind im Unternehmen vorhanden (Sicherheitsdatenbl?tter) bzw. ?ffentlich leicht zug?nglich (Gefahrstoffdatenbanken).
Die Bilanzierung von Gefahrstoffen mit Hilfe der hier vorgestellten Methode erm?glicht es auch, in ?kobilanziellen Untersuchungen
systematisch den Gefahrstoffeinsatz zu berücksichtigen. Die Methodik ist am Beispiel von Wohngeb?uden erprobt worden.
Anmerkung: Als Gefahrstoffe, Schadstoffe, gef?hrliche Inhaltsstoffe bzw. gef?hrliche Stoffe werden in dieser Arbeit solche
Stoffe definiert, die eines der Gef?hrlichkeitsmerkmale nach § 3 Chemikaliengesetz besitzen.
OnlineFirst: 19. 12. 2001 相似文献
497.
Mixtures of dense non-aqueous phase liquids (DNAPLs) trapped in the subsurface can act as long-term sources of contamination by dissolving into flowing groundwater. In general, the components of higher solubility are removed more quickly, thus altering the composition of the remaining DNAPL, and possibly leading to changes in its physical properties. Through the development of a simple compositional model, Roy et al. [J. Contam. Hydrol. 2002 (59) 163] showed that preferential dissolution of a mixed DNAPL could potentially result in changes in density and interfacial tension that could subsequently lead to remobilization of an initially static DNAPL pool. The laboratory experiments presented in this next paper provide a proof-of-concept for the previously presented theory, demonstrating and quantifying this process of remobilization. In addition, the experiments provide a data set for evaluation of the model presented by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. In the four experiments, a DNAPL pool comprised of tetrachloroethene and benzene was created as an open pool overlying glass beads within a water-saturated 2-D flow box. Experiments included rectangular and triangular pools. In each of the experiments, remobilization (as breakthrough) was observed more than 2 weeks after formation of the initial pool. During each experiment, the pool height declined as mass was lost by dissolution, while sampling indicated a decrease in the mole fraction of benzene, the more soluble component. Small protuberances formed along the bottom of the pool as its composition changed with time and the displacement pressure was achieved for various pore throats. Eventually one of the protuberances extended further, forming a finger (breakthrough). In general, the pool emptied as the finger proceeded further into the beads. It was also shown theoretically and experimentally that remobilization will occur sooner for pools with a triangular (pointing down), rather than rectangular, shape. The experimental results were simulated using the model developed by Roy et al. [J. Contam. Hydrol. 2002 (59) 163]. The model matched the observations well, suggesting that it accurately represents the primary mechanisms involved with natural remobilization under the conditions of the study. 相似文献
498.
焚烧法处理环己酮生产中的皂化液 总被引:1,自引:0,他引:1
用环已烷氧化生产环已酮的生产过程中会产生大量的皂化液 ,它含有大量的有害物质 ,是一种难处理的高污染有机废水。某石化厂在借鉴造纸行业的黑液焚烧技术的基础上 ,采用焚烧法来处理皂化液 ,并得到副产蒸气和回收了碳酸钠 ,实现了皂化液的无害化与资源化 ,具有良好的社会效益、环境效益和经济效益 ,每处理 1t皂化液可盈利 10 0~ 2 0 0元 相似文献
499.
500.
The effect of methanol of low concentration on adsorption and leaching of atrazine and tebuconazole was studied in this paper. The adsorption coefficients and the retardation factors (Rm) of pesticides on EUROSOIL 3# log-linearly decreased as volumetric fraction of methanol (fc) was increased in the binary solvent mixtures of methanol and water. These data are consistent with solvophobic theory formerly outlined for describing the adsorption and transport of hydrophobic organic chemicals from mixed solvents. Nevertheless, the adsorption of these pesticides in soil–water system slightly increased when the soil was pre-washed with methanol in comparison with that pre-washed with water (pure water system). Furthermore, their adsorption coefficients were still higher in binary solvent systems with methanol of very low concentrations, i.e. fc<0.03 for atrazine and fc<0.01 for tebuconazole, than those in pure water system. The adsorption coefficients (logKw) of atrazine and tebuconazole predicted by solvophobic theory were 0.5792 and 1.6525, respectively, and their experimental logKw were 0.3701 and 1.6275 in pure water system. Obviously, the predicted logKw of the two pesticides was higher than the experimental log Kw in pure water system. The predicted Kw and the retardation factor (Rw) in pure water system by solvophobic theory are thus possibly inaccurate. 相似文献