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171.
In present investigation, an attempt has been made for the synthesis of cupric oxide nanoparticles (CuONPs) through a green route by utilizing lemon juice extract as a bioreductant. The synthesized CuONPs were characterized through UV–visible spectroscopy, Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The CuONPs were utilized for Cr(VI) removal from water through adsorption method in batch mode at different initial Cr(VI) concentration, pH, temperature and CuONPs dosage. The maximum uptake capacity of CuONPs was found to be 16.63 mg of Cr(VI)/g at pH 4.0. Implementation of response surface methodology (RSM) followed by artificial neural network hybridized with genetic algorithm (ANN-GA) approach has resulted maximum Cr(VI) adsorption of 98.8% under the optimized conditions of initial metal concentration 22.5 mg/L, pH 3.81, CuONPs dose 1.28 g/L and temperature 37.1 °C. Under optimum conditions, adsorption isotherm study was conducted, which showed that the fitness of experimental data was well achieved with Langmuir isotherm model illustrating monolayer pattern of adsorption. Thermodynamic study revealed that the process was spontaneous and endothermic in nature, while adsorption kinetics was best explained by pseudo-second order kinetic model. 相似文献
172.
Chompoonoot Nanthamathee 《环境科学学报(英文版)》2019,31(7):68-79
In this research, for the first time, a series of Co(Ⅱ) doped copper terephthalate(Co X-Cu BDC,where X is doping percentage) were successfully synthesized via solvothermal method and were tested for dye removal application. The physical properties of Co X-CuBDC were studied by several techniques including X-ray diffraction(XRD), field emission scanning electron microscopy(FESEM), energy-dispersive spectroscopy(EDS), thermogravimetric analysis(TGA)and Brunauer–Emmett–Teller(BET) surface area analysis. The incorporation of Co(Ⅱ) dopant leads to isomorphic substitution of Cu(II) in the CuBDC framework with the maximum doping percentage of 22. Doping and parent MOFs which are non-porous were used for removal of Methylene Blue(MB) from aqueous solution. Adsorption capacity of Co22-CuBDC and CuBDC are 52 and 58 mg/g, respectively, both of which are higher than the adsorption capacity recorded from several high porosity MOFs. Adsorption kinetic studies indicate that adsorption process follows pseudo-second order model while the adsorption mechanism is dominated by electrostatic attraction. Overall, even though these materials show non-porous characteristic,it can be used effectively in wastewater treatment application. 相似文献
173.
174.
Ranked set sampling: an annotated bibliography 总被引:1,自引:1,他引:1
The paper provides an up-to-date annotated bibliography of the literature on ranked set sampling. The bibliography includes all pertinent papers known to the authors, and is intended to cover applications as well as theoretical developments. The annotations are arranged in chronological order and are intended to be sufficiently complete and detailed that a reading from beginning to end would provide a statistically mature reader with a state-of-the-art survey of ranked set sampling, including historical development, current status, and future research directions and applications. A final section of the paper gives a listing of all annotated papers, arranged in alphabetical order by author.This paper was prepared with partial support from the United States Environmental Protection Agency under a Cooperative Agreement Number CR-821531. The contents have not been subject to Agency review and therefore do not necessarily reflect the views or policies of the Agency and no official endorsement should be inferred. 相似文献
175.
聚结除油反应机理及其动力学分析 总被引:1,自引:0,他引:1
通过对几种聚结填料除油性能的对比试验,探讨分析了聚结除油反应机理及其动力学.结果表明,填料的空间构成形式对聚结除油效率有重要影响,当润湿聚结机理和碰撞聚结机理同时存在时,聚结效率可得到大幅度提高.当油珠颗粒尺寸超过10μm时,布朗运动聚结速率急剧减慢,而湍流的聚结速率急剧加快.聚结除油反应器内水力条件的紊动程度达到G≥500~700 s-1时,油珠颗粒的聚结速率和效率将得到大幅度提高. 相似文献
176.
Mace R 《Behavioral ecology and sociobiology》1996,38(2):75-81
Demographic data from 848 Gabbra households are used to examine the relationships between herd size and reproductive success
in relation to sex, in a traditional, pastoralist population. The number of camels in the household herd has a significant
positive effect on the reproductive success of both men and women, although the effect of wealth is greater for men, as predicted
from evolutionary theory. The greater the number of elder brothers a man has, the lower his reproductive success, as a result
of a smaller initial herd and a later age at marriage. This is not true for women –number of elder sisters does not have a
measurable effect on a woman’s fertility, although it does have a small, negative effect on the size of her dowry. These results
are interpreted as competition between same-sex siblings for parental investment, in the form of their father’s herd, which
is more intense between sons than daughters as parental investments are greatest in males.
Received: 30 June 1995/Accepted after revision: 23 October 1995 相似文献
177.
优序法用于环境质量的比较 总被引:4,自引:0,他引:4
应用优序法比较多个环境单元的环境质量优劣。通过实例计算,获得了与密切值法、模糊综合相似选择法和姚志麒指数法相一致的排序结果。实例分析表明,该方法概念明确、计算简便,实用性强。 相似文献
178.
目的实现平面场中主应变的测量不确定度评定。方法首先建立主应变的是非线性传播测量模型,然后应用基于二阶TAYLOR级数展开理论的不确定度传播方法(LPU方法),开展平面问题中主应变的测量不确定度评定。针对二种常用的应变花,建立以主应变为输出量、以应变花之三个方向测量应变为输入量的测量模型,并将二阶LPU方法应用于该模型。设计数值计算算例,以说明主应变不确定度的评定过程和方法,并与一阶LPU结果进行了比较。结果当应变花三个方向的应变测量结果相近时,文中方法与一阶LPU方法获得的主应变的不确定度评定结果存在明显的差异,主应变不确定度评定结果在数值上都大于应变花测量的不确定度。当应变花三个方向的应变测量结果相差较大时,文中方法和一阶LPU方法获得的主应变测量不确定度评定结果相差不大。结论特定情况下,主应变的测量不确定度值远大于应变花测量的不确定度,且与一阶LPU方法的评定结果有显著差异,二者可相差一倍。 相似文献
179.
行政机关提起的生态环境损害赔偿之法律范畴与路径是生态环境损害赔偿立法时需要解决的两个核心问题。我国目前将生态环境损害赔偿定位为民事范畴,该定位一定程度上违背了行政责任与民事责任的界分。本文从生态环境的属性切入,得出在公私法二分语境下,生态环境损害赔偿宜纳入行政法范畴的结论;其次,通过对比美国与欧盟的做法,展开行政法视角下强制性与非强制性二元路径的探讨。本文认为,我国可借鉴美国的做法,在未来立法时采用二元路径:违法排放污染物质需要清除的,行政机关可依法责令清除污染,或采用执法和解方式与责任人达成一致;生态环境服务功能损失的恢复则不宜采用强制性命令,行政机关可与责任人进行和解。 相似文献
180.