入冬水生高等植物的衰亡对河流水质的影响

上海市郊河流水体中有很高的氮、磷和有机负菏，由于受水生高等植物生灭的影响，初春河流中的氮、磷和有机负菏明显高于上一年的初冬，河流中的水生高等植物能大量地吸收水体中的氮、磷，抑制藻类生长，净化水质；但其植株残体在水中的腐解，又会重新释出营养元素，造成对水体的二次污染。在冬季，随着水生高等植物的大量死亡这种污染更加明显，应加强对水生高等植物的利用，尝试建立既能净化水质，又有创造经济效益的生态工程模式，使市郊受污水体得到资源化利用。     

水解酸化-好氧工艺处理感光材料有机废水研究

感光材料有机生产废水含有多种合成有机物，其BOD5／CODer比值为0．46～0．48，可生化性良好，经水解酸化处理后该废水的BOD5／CODcr的比值可提高至0．54～056，平均增加了17％左右。水解酸化－好氧串联工艺对该废水总的处理效果表明：在废水CODer进水浓度2000～2500mg／L范围内，CODer总去除率可达95％左右，BOD5总去除率可达97％左右；水解酸化后好氧生化系统的动力学半速度常数Ks＝103mg／L，最大比降解速度K＝5．0／日。     

强化混凝去除黄浦江水有机物的试验研究

强化混凝去除有机物的效果与水源的分子量分布特性有着密切的关系.由于黄浦江水中低分子量的溶解性有机物占多数,因此,强化混凝处理有机物效果有限.对于＜1k分子量区间的有机物.增加混凝剂投量可有效去除紫外吸光值(UV254),但去除溶解性有机碳(DOC)的效果很差.尽管增加混凝剂投量和降低pH都能有效地去除有机物,但决定强化混凝效果的主要因素是pH,去除黄浦江水有机物的最佳pH范围为6～5.     

典型北方高碱度微污染水体强化混凝的示范研究

以高碱度、受有机物污染的典型北方水体为例,探索适宜的强化混凝技术.在水质调查的基础上,提出适合水质特征的强化混凝目标.研究了高碱度水体强化混凝技术方法.研究表明,可以通过3条技术途径提高水体中有机物的去除效率.其一在混凝前优化pH,促进絮凝剂水解形成中聚体,AlCl3在pH 6左右,FeCl3在pH 5左右时,有机物去除率可以提高一倍左右;其二是强化沉淀软化;其三是絮凝剂优化.结合我国实际情况,通过对传统絮凝剂进行改性,研制出了适合我国北方水质特征的高效絮凝剂,能较传统絮凝剂将有机物去除率提高30%以上.     

Simultaneous determination of dissolved organic nitrogen, nitrite, nitrate and ammonia using size exclusion chromatography coupled with nitrogen detector

Accurate quantification of dissolved organic nitrogen (DON) has been a challenge due to the cumulative analytical errors in the conventional method via subtracting dissolved inorganic nitrogen species (DIN) from total dissolved nitrogen (TDN). Size exclusion chromatography coupled with an organic nitrogen detector (SEC-OND) has been developed as a direct method for quantification and characterization of DON. However, the applications of SEC-OND method still subject to poor separations between DON and DIN species and unsatisfied N recoveries of macromolecules. In this study, we packed a series of SEC columns with different lengths and resin materials for separation of different N species and designed an independent vacuum ultraviolet (VUV) oxidation device for complete oxidation converting N species to nitrate. To guarantee sufficient N recoveries, the operation conditions were optimized as oxidation time ≥ 30 min, injection mass (sample concentration × injection volume) < 1000 µL × mg-N/L for macromolecular proteins, and neutral pH mobile eluent. The dissolved O₂ concentration in SEC mobile phase determined the upper limit of VUV oxidation at a specific oxidation time. Compared to conventional HW50S column (20 × 250 mm), HW40S column (20 × 350 mm) with mobile phase comprising of 1.5 g/L Na₂HPO₄·2H₂O + 2.5 g/L KH₂PO₄ (pH = 6.85) could achieve a better separation of DON, nitrite, nitrate, and ammonia. When applied to river water, lake water, wastewater effluent, groundwater, and landfill leachate, the SEC-OND method could quantify DON as well as DIN species accurately and conveniently even the DIN/TDN ratio reached 0.98.     

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.     

光化学反应的环境效应

光化学反应具有良好的环境效应，本文概述了有机合成和环境化学中光化学反应对环境的影响。     

对水体中有机污染综合指标及其相互间的关系探研

通过对水体中各有机污染综合指标的含义及各指标测定方法条件控制的论述,阐明了各指标间的相互关系,对我们在水质监测中的质量控制、数据的综合分析和判断有一定的指导意义。     

下古生界海相碳酸盐烃源岩地球化学的研究现状

本文对国内外下古生界海相碳酸盐岩研究的四个主要方面作了总结：（1）有机质丰度及其影响因素；（2）有机质赋存形式；（3）下古生界海相碳酸盐岩有机质丰度和生烃潜力恢复方法和原理；（4）下古生界海相碳酸盐岩热成熟度研究。这四个方面是评价我国下古生界海相碳酸盐岩勘探前景至关重要的因素，也是近年来我们研究下古生界海相碳酸盐岩的热点和难点问题。