有机气溶胶的来源与形成研究现状

介绍了有机气溶胶来源与形成的研究现状,从有机气溶胶的化学组成特征、一次有机气溶胶的来源和二次有机气溶胶的形成机制论述其研究进展.一次有机气溶胶主要来源于烹调油烟、机动车排放、生物质燃烧、工业或民用燃油锅炉释放出的有机物,还有道路扬尘、沥青、刹车尘、轮胎屑、室外香烟烟雾、以及高等植物蜡、细菌活动和草本植物等.大气中的半挥发性有机物可通过物理和化学吸附形成二次有机气溶胶,一些挥发性有机物可通过气相化学反应转化为低挥发性的物质并形成二次有机气溶胶,其主要前体物是芳香族化合物,如苯、甲苯、二甲苯,以及烯烃、烷烃、环烷烃、萜烯和生物排放的非饱和氧化物.     

利用干酪根固体~(13)C核磁共振法研究下古生界碳酸盐岩的热演化程度

应用固体~(13)C－NMR技术对下古生界,海相碳酸盐岩干酪根的化学组成和结构特征进行研究，提出应用该技术所测算的干酪根结构参数“芳核平均结构尺寸”能较准确地反映碳酸盐岩的热成熟度。首次提出芳核平均结构尺寸与镜质体反射率之间的关系在干酪根的热演化过程中具有“三段式”特征。利用这一成果对华北地区下古生界成熟度进行了测定，与地质背景甚为吻合。     

农药废水的“物化+生化”处理技术研究

生产久效磷和亚磷酸三甲脂产生的废水是高浓度、毒性大的有机农药废水 ,采用适当的物化手段作为预处理可以降低废水的CODCr和毒性 ,提高废水的可生化性 ,再经过以光合细菌为主的接触氧化处理 ,整个系统CODCr的去除率达到 99% ,出水CODCr降低至 2 0 0mg/L。     

区域(城市)水体中主要有机毒物的筛选

本研究发展了区域(或城市)水体中主要有毒化学品的筛选方法。 在城市下游采集大体积水样,用CH_2Cl_2洗脱,再用有机溶剂萃取,用硅胶柱把有机物分成许多馏分,馏分最终变为水溶液。每个馏分中有机物浓度比原水大1000倍。用这种馏分水溶液进行溞的急性毒性试验和Ames试验。只对毒性大的馏分进行色谱/质谱/数据系统的鉴定和定量分析,然后根据各个化合物的急性毒性、降解难易和“三致”物质的资料及原水样中有机物的浓度资料,就可筛选出一个区域(城市)水体中的主要有毒化学品。     

危险废物安全填埋场运行机制与收费标准

危险废物安全填埋场应探讨企业化经营模式。在单一处理模式、一体化经营模式和依托于大型企业模式中选择适宜的模式。填埋场建设资金筹集渠道中,由废物产生单位集资建设是可行办法。探讨了填埋场收费标准的计算方法,并给出计算公式。     

Molecular behavior and interactions with microbes during anaerobic degradation of bio-derived DOM in waste leachate

It is the key to control bio-derived dissolved organic matters (DOM) in order to reduce the effluent concentration of wastewater treatment, especially for waste leachate with high organic contaminants. In the present study, the anaerobic degradation of aerobically stabilized DOM was investigated with DOM substrate isolated through electrodialysis. The degradation of bio-derived DOM was confirmed by reduction of 15% of total organic carbon in 100 days. We characterized the molecular behavior of bio-derived DOM by coupling molecular and biological information analysis. Venn based Sankey diagram of mass features showed the transformation of bio-derived DOM mass features. Occurrence frequency analysis divided mass features into six categories so as to distinguish the fates of intermediate metabolites and persistent compounds. Reactivity continuum model and machine learning technologies realized the semi-quantitative determination on the kinetics of DOM mass features in the form of pseudo-first order, and confirmed the reduction of inert mass features. Furthermore, network analysis statistically establish relationship between DOM mass features and microbes to identify the active microbes that are able to utilize bio-derived DOM. This work confirmed the biological technology is still effective in controlling recalcitrant bio-derived DOM during wastewater treatment.     

Dynamic fate modeling of γ-hexachlorocyclohexane in the lower reaches of the Liao River

A QWASI model dependent on temperature is parameterized to describe the long-term fate of persistent organic pollutants (POPs) in the Liao River. The model parameters, namely fugacity capacity, degradation rate, and transfer coefficient, are profoundly affected by temperature. This model is used to simulate the fate of γ-hexachlorocyclohexane (γ-HCH) in the lower reaches of the Liao River from 1998 to 2008. Modeling results show that γ-HCH fugacity capacities in air, water, and sediment increase as temperature decreases, and the transfer and transformation rate coefficients increase as temperature increases. The variations of transfer and transformation parameter D values depend on fugacity capacities, and transfer and transformation coefficients simultaneously. The performance of the model is evaluated by comparing the predicted and observed concentrations in the water and sediment of the Liao River. The predicted values agree well with the observed value in the order of magnitude, in most cases within the factor of 3. It is believed that the model is appropriate for simulating the long term fate of POPs in the Liao River. Translated from Environmental Science, 2006, 27(1): 121–125 [译自: 环境科学]     

酸性高氟废水处理试验研究

对某化工厂高氟酸性废水经过试验后，采用二级石灰－氯化钙沉淀絮凝法处理，出水的氟浓度达到了国家规定的一级排放标准，且系统运行稳定，工艺简便，易于施工和运行管理。     

黄河口及邻近海域溶解态无机磷、有机磷、总磷的分布研究

于2003年8月下旬对黄河口及邻近海域进行了十船连续同步27h采样调查,分析了调查区域的溶解态无机磷、有机磷、总磷的平面分布、断面分布、时间分布特征.结果表明,在调查区域内,溶解态无机磷浓度很低,而溶解态有机磷浓度较高(占溶解态总磷的85%以上),是溶解态总磷的主要组成部分.各形态磷的平面分布、断面分布均呈现出由河口向邻近海域降低的趋势,溶解态总磷、溶解态有机磷梯度变化较溶解态无机磷更为明显;潮汐对河口浅水区的各形态磷浓度影响较大,对邻近调查海域的影响不明显.     

医疗废物焚烧残余物固化技术初探

根据对医疗废物焚烧残余物中有毒有害物质的化验分析结果,确定焚烧残余物中有毒有害成分含量仍较高,部分指标超出标准值,必须对其进行稳定化/固化处理,避免对土壤及地下水环境造成污染.本文阐述了稳定化/固化处理原理及处理工艺,使医疗废物无害化、减量化和资源化的处理原则得以全面实现.