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101.
Antonio Velasco Sergio Hernández Martha Ramírez 《Journal of environmental science and health. Part. B》2013,48(7):498-504
Organochlorine pesticides were intensively used in Mexico from 1950 until their ban and restriction in 1991. However, the presence of these compounds is commonly reported in many regions of the country. The aim of the present study was to identify and quantify residual organochlorine and organophosphorus pesticides in agricultural soil in Rio Verde region, San Luis Potosi state, which has been identified as possibly polluted by pesticides. Composed samples from 24 zones covering an area of approximately 5,440 ha were analyzed. The most frequently found pesticides were p,p´-DDT followed by ,p,p´-DDE, heptachlor, endosulfan and γ-HCH whose frequency rates were 100, 91, 83 and 54%, respectively. The concentration of p,p´-DDT in the crops grown in these soils was in the following order: chili > maize > tomato > alfalfa. The results obtained in this study show that p,p´-DDT values are lower or similar to those found in other agricultural regions of Mexico. Methyl and ethyl parathion were the most frequent organophosphate pesticide detected in 100% and 62.5% of the samples with average concentrations of 25.20 and 47.48 μg kg–1, respectively. More research is needed to establish the background levels of pesticides in agricultural soils and their potential ecological and human health effects in this region. 相似文献
102.
G.R. Tortella R.A. Mella-Herrera D.Z. Sousa O. Rubilar G. Briceño L. Parra M.C. Diez 《Chemosphere》2013
The impact of repeated carbendazim (CARB) applications on the extent of CARB dissipation, the microbial diversity, the community level physiological profile (CLPP), and the enzymatic activity within the biomixture of an on-farm biopurification system was evaluated. After three successive CARB applications, the CARB dissipation efficiency was high; the efficiency of dissipation was 87%, 94% and 96% after each application, respectively. Although microbial enzymatic activity was affected significantly by CARB application, it could recover after each CARB pulse. Likewise, the numbers of cultivable bacteria, fungi and actinomycetes (as measured in CFUs) were slightly affected by the addition of CARB, but the inhibitory effect of the pesticide application was temporary. Denaturing gradient gel electrophoresis (DGGE) and Biolog Ecoplate assays demonstrated that the microbial populations remained relatively stable over time when compared to the control. The results obtained herein therefore demonstrate the high dissipation capacity of this biomixture and highlight the microbiological robustness of this biological system. 相似文献
103.
Abstract Three models describing adsorption‐desorption kinetics of pesticides in soil, that could be incorporated into computer programs on pesticide movement in soil, were discussed, The first model involved single first‐order rate equations for adsorption and desorption. Results from an analytical and a numerical solution for local equilibration were compared. Concentration‐time relationships for the solution and adsorbed phases were calculated for different rate constants, initial conditions, and partition ratios at equilibrium. The second model described simultaneous adsorption‐desorption equilibration with two mechanisms, both with their own rate constants. After a comparatively fast equilibration with the first mechanism, there was a gradual increase in extent of overall‐adsorption, accompanied with a shift to greater amounts adsorbed by the second mechanism. With the third model, adsorption equilibration occurred by diffusion into a stagnant region. With diffusion distances ranging from 0.1 to 4.0 cm, the time needed for approach to adsorption equilibrium varied from about 0.25 days to about one year. Some of the possibilities of these models were discussed considering published experimental results. 相似文献
104.
G. A. El Zorgani 《Journal of environmental science and health. Part. B》2013,48(6):1091-1098
Abstract Cotton‐producing areas of the Centrol Sudan, bordered by the Blue and the White Nile, have been subjected to repeated applications of pesticides. This region is irrigated by a series of canals, the Gezira canals, which hold large amounts of fresh water. Lake Nubia at the Sudan‐Egypt border is another important fresh water reservoir and fisheries ground. Fish from both the Gezira and Lake Nubia showed elevated concentrations of pesticides, suggesting that continued pesticides application would endanger the equatic fauna of this region and the proposed fresh water fishery. 相似文献
105.
Atrazine, propazine and simazine were tested separately and in mixture by batch procedure in a laboratory-constructed apparatus. 3.75 l of a buffered s-triazines pesticide solution was treated at room temperature by 325-mesh zero-valent iron powder (ZVIP) (20 g/l). High performance liquid chromatography was used to separate by-products and study the decline in the pesticide’s concentrations. Results obtained show that the order of degradation was simazine, atrazine and then propazine. The half-lives (t1/2) of the s-triazines pesticides are, respectively, 7.4, 9.0 and 10.6 min when they are treated separately, and 9.8, 11.2 and 13.7 min when they are treated together under the same conditions. The final by-product obtained after 50 min of contact of simazine with ZVIP shows a shift to longer wavelength in its UV spectrum. A similar phenomenon is shown for atrazine and propazine. Identical primary by-products are produced and subsequently degraded to 4,6-(diamino)-s-triazine, which seems to be the major by-product of the reductive treatment process. Pathways for the degradation of the studied s-triazines by ZVIP are proposed. 相似文献
106.
Human exposures to pesticides can occur in the workplace, in the household and through the ambient environment. While several articles have reviewed the impact of pesticide exposures on human respiratory health in occupational settings, to the best of our knowledge, this article is the first one to review published studies on the association between pesticide exposures and human respiratory health in the general populations. In this article, we critically reviewed evidences up to date studying the associations between non-occupational pesticide exposures and respiratory health in general populations. This article also highlighted questions arising from these studies, including our recent analyses using the data from the Canadian Health Measures Survey (CHMS), for future research. We found few studies have addressed the impact of environmental pesticide exposures on respiratory health, especially on lung function, in general populations. In the studies using the data from CHMS Cycle 1, exposures to OP insecticides, pyrethroid insecticides, and the organochlorine pesticide DDT were associated with impaired lung function in the Canadian general population, but no significant associations were observed for the herbicide 2,4-D. Future research should focus on the potential age-specific and pesticide-specific effect on respiratory health in the general population, and repeated longitudinal study design is critical for assessing the temporal variations in pesticide exposures. Research findings from current studies of non-occupational pesticide exposures and their health impact in general population will help to improve the role of regulatory policies in mitigating pesticide-related public health problems, and thereafter providing greater benefit to the general population. 相似文献
107.
Sorption coefficients (Kp) of several organochlorine insecticides (OCs) in volcanic ash silt from Central Java are presented. Selected experimental and estimated octanol‐water partition coefficient (P) values are used to study log‐log regressions with Kp data collected from the literature (PAHs, chlorophenols, phenylureas, chloro‐s‐triazines, carbamates and organophosphorus insecticides) and those of the OCs determined in the present study. Leaching distances and bioactivities in soil are correlated with the Kp values of the pesticides, and with the organic matter and the water content of the soil. 相似文献
108.
Alan Miller 《Environmental management》1993,17(5):563-574
There is a continuing debate about the proper role of analytical (positivist) science in natural resource decision making.
Two diametrically opposed views are evident, arguing for and against a more extended role for scientific information. The
debate takes on a different complexion if one recognizes that certain kinds of problem, referred to here as “wicked” or “trans-science”
problems, may not be amenable to the analytical process. Indeed, the mistaken application of analytical methods to trans-science
problems may not only be a waste of time and money but also serve to hinder policy development. Since many environmental issues
are trans-science in nature, then it follows that alternatives to analytical science need to be developed. In this article,
the issues involved in the debate are clarified by examining the impact of the use of analytical methods in a particular case,
the spruce budworm controversy in New Brunswick. The article ends with some suggestions about a “holistic” approach to the
problem. 相似文献
109.
Daraghmeh A Shraim A Abulhaj S Sansour R Ng JC 《Environmental geochemistry and health》2007,29(1):45-50
The aim of this work was to report on imidacloprid [IUPAC name 1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine] residues in some vegetables, fruits, and water samples collected from the West Bank, Palestine,
in 1998 and 1999. Imidacloprid and its derivatives in the study samples were extracted by methanol/water and oxidized into
6-chloronicotinic acid and subsequently derivatized into 6-chloronicotinic acid trimethylsilyl ester before being determined
by GC/MS. Imidacloprid residues were detected in more than half of the analyzed samples. The highest and lowest imidacloprid
concentrations were found in eggplant (0.46 mg/kg) and green beans (0.08 mg/kg), respectively. An increase of 11–120% in imidacloprid
concentration in the 1999 samples was observed when compared with those of 1998. This may suggest imidacloprid accumulation
in the soil and/or increased use by local farmers. The imidacloprid residue concentrations in several crops were found to
exceed the CODEX maximum residue limit. 相似文献
110.