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41.
简易、快速检测有机磷农药的酶片和生色基质片 总被引:12,自引:0,他引:12
研制出简易、快速检测有机磷农药的酶片和生色基质片。用胆碱酯酶抑制试验检测水中的有机磷农药,检测灵敏度在0.01—10mg/L范围,适宜温度在25—35℃之间,分析周期约为15—20min。甲胺磷和水胺硫磷等硫代磷酸酯类农药经溴水活化后检测灵敏度也达上述水平。实际水样检测表明,检样中农药含量在检测灵敏度范围内时,阳性结果相当明显,溶液吸光度比值A对照/A检样>2。由于检测时无需配制试剂和使用仪器,本法特别适宜于现场检测。 相似文献
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GC-ECD检测水中有机氯和有机磷农残研究 总被引:1,自引:0,他引:1
本文研究GC-ECD同吋检测水体中十二个有机氯农药和有机磷农药组分的最佳测试条件。在选定的测试条件下,方法检测下限达0.2ng/L(α-666)和0.8ng/L(甲基-1605),线性范围均达10~3数量级,水样加标回收率在82.5—100%之间。 相似文献
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废弃农药厂土壤和地下水中有机磷农药的健康风险评价 总被引:3,自引:2,他引:1
采用气相色谱氮磷检测器法测定了某废弃农药厂土壤和地下水中有机磷农药(OPPs)的含量,并用美国环保署(USEPA)推荐的健康风险评价方法,对该场地土壤和地下水中OPPs引起的健康风险进行了初步评价。结果表明,土壤、地下水中∑OPPs的检出浓度范围分别为1.3~1 129μg/kg和48.0~149.2 ng/L,点位检出率分别为73%、100%。土壤和地下水中OPPs的非致癌总风险指数均小于1,致癌总风险指数均在10-4以下。根据USEPA的建议值,初步认为该场地土壤和地下水中OPPs不会对人体产生明显的健康危害。 相似文献
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Martha P. García De Llasera Leopoldo Cruz-Reyes Luz E. Vera-Avila 《Journal of environmental science and health. Part. B》2013,48(1):25-32
A method based on matrix solid-phase dispersion (MSPD) was developed for quantitative extraction of three organophosphorus pesticides (OPPs) from the Mexican axolotl, Ambystoma mexicanum. The determination was carried out using high- performance liquid chromatography (HPLC) with diode array spectrophotometric UV detection (DAD). The MSPD extraction with octadecylsilyl (C18) sorbent combined with a silica gel clean-up and acetonitrile elution was optimised for chlorpyrifos, fenthion and methyl parathion. The method was validated, yielding recovery values higher than 90%. The precision, expressed as the relative standard deviation (RSD), was less than or equal to 6% in muscle samples at spiking levels of 10 and 5 ppm. Linearity was studied from 15 to 60 ppm for chlorpyrifos and fenthion, and from 7.5 to 30 ppm for methyl parathion. The limits of detection (LODs) were found to be less than or equal to 0.5 ppm.This method was applied to the analysis of samples from a chlorpyrifos-exposed axolotl, demonstrating its use as an analytical tool for toxicological studies. 相似文献
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Substituted urea compounds are well-known as potent inhibitors of juvenile hormone epoxide hydrolase (JHEH) of the tobacco hornworm Manduca sexta. Docking simulations of 47 derivatives inside JHEH were performed to gain insight into the structural characteristics of these complexes. The obtained orientations show a strong similitude with the observed in the known X-ray crystal structures of human soluble epoxide hydrolase (sEH) complexed with dialkylurea inhibitors. In addition, the predicted inhibitor concentration (IC50) of the above-mentioned compounds as JHEH inhibitors were obtained by a quantitative structure-activity relationship (QSAR) method by using comparative molecular field analysis (CoMFA) applied to aligned dataset. The best models included steric and electrostatic fields and had adequate predictive abilities. In addition, these models were used to predict the activity of an external test set of compounds that was not used for building the model. Furthermore, plots of the CoMFA fields allowed conclusions to be drawn for the choice of suitable inhibitors. 相似文献
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SBR生化法处理有机磷农药废水 总被引:6,自引:0,他引:6
采用SBR生化法处理有机磷农药废水,生产规模试运行结果表明,SBR生化法具有装置结构简单、运转录活、操作方便、COD和有机磷去除率高等特点。 相似文献