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951.
Effects of initial iron corrosion rate on long-term performance of iron permeable reactive barriers: Column experiments and numerical simulation 总被引:3,自引:1,他引:2
Jin suk O Sung-Wook Jeen Robert W. Gillham Lai Gui 《Journal of contaminant hydrology》2009,103(3-4):145-156
Column experiments and numerical simulation were conducted to test the hypothesis that iron material having a high corrosion rate is not beneficial for the long-term performance of iron permeable reactive barriers (PRBs) because of faster passivation of iron and greater porosity loss close to the influent face of the PRBs. Four iron materials (Connelly, Gotthart-Maier, Peerless, and ISPAT) were used for the column experiments, and the changes in reactivity toward cis-dichloroethene (cis-DCE) degradation in the presence of dissolved CaCO3 were evaluated. The experimental results showed that the difference in distribution of the accumulated precipitates, resulting from differences in iron corrosion rate, caused a difference in the migration rate of the cis-DCE profiles and a significant difference in the pattern of passivation, indicating a faster passivation in the region close to the influent end for the material having a higher corrosion rate. For the numerical simulation, the accumulation of secondary minerals and reactivity loss of iron were coupled using an empirically-derived relationship that was incorporated into a multi-component reactive transport model. The simulation results provided a reasonable representation of the evolution of iron reactivity toward cis-DCE treatment and the changes in geochemical conditions for each material, consistent with the observed data. The simulations for long-term performance were also conducted to further test the hypothesis and predict the differences in performance over a period of 40 years under typical groundwater conditions. The predictions showed that the cases of higher iron corrosion rates had earlier cis-DCE breakthrough and more reduction in porosity starting from near the influent face, due to more accumulation of carbonate minerals in that region. Therefore, both the experimental and simulation results appear to support the hypothesis and suggest that reactivity changes of iron materials resulting from evolution of geochemical conditions should be considered in the design of iron PRBs. 相似文献
952.
This work presents a first estimation of the sedimentation rate for the Red Lake (Romania). The sediment accumulation rates were determined by two well-known methods for recent sediment dating: 210Pb and 137Cs methods. Both techniques implied used the gamma emission of the above-mentioned radionuclides. The 210Pb and 137Cs concentrations in the sediment were measured using a gamma spectrometer with a HpGe detector, Gamma-X type. Activities ranging from 41 ± 7 to 135 ± 34 Bq/kg were found for 210Pb and from 3 ± 0.5 to 1054 ± 150 Bq/kg for 137Cs. The sediment profile indicates acceleration in sedimentation rate in the last 18 years. Thus, the sedimentation process for the Red Lake can be divided in two periods, the last 18 years, and respectively, the period before that. Using the Constant Rate of 210Pb Supply method values between 0.18 ± 0.04 and 1.85 ± 0.5 g/cm2 year (0.32 ± 0.08 and 2.83 ± 0.7 cm/year) were obtained. Considering both periods, an average sedimentation rate of 0.87 ± 0.17 g/cm2 year (1.17 cm/year) was calculated. Considering an average depth of 5.41 m for the lake and the sedimentation rate estimated for the last 18 years, it could be estimated that the lake will disappear in 195 years. 相似文献
953.
单质硫改性介孔炭对水溶液中汞的吸附性能研究 总被引:2,自引:1,他引:1
对介孔炭CMK-3进行单质硫改性得到OMC-S,并通过静态吸附实验研究了该材料对水溶液中汞的吸附性能。研究结果表明:单质硫改性可以在介孔炭上负载12.33%的硫,从而使得介孔炭对汞的吸附容量从185 mg/g提高到476 mg/g;OMC-S具有较广的适用pH值范围,在pH 3~11.5范围内其对汞的吸附去除率均达到92%以上;氯离子对OMC-S的吸附性能具有一定的抑制作用,原因在于它能和汞离子络合形成一系列吸附性能较差的Hg-Cl络合物,而腐殖酸在所研究的范围内对OMC-S的吸附性能无明显影响。 相似文献
954.
Andrew O. Hughes Jon M. Olley Jacky C. Croke Ian T. Webster 《Journal of environmental radioactivity》2009,100(10):858-865
Fallout 137Cs has been widely used to determine floodplain sedimentation rates in temperate environments, particularly in the northern hemisphere. Its application in low fallout, tropical environments in the southern hemisphere has been limited. In this study we assess the utility of 137Cs for determining rates of floodplain sedimentation in a dry-tropical catchment in central Queensland, Australia. Floodplain and reference site cores were analysed in two centimetre increments, depth profiles were produced and total 137Cs inventories calculated from the detailed profile data. Information on the rates of 137Cs migration through local soils was obtained from the reference site soil cores. This data was used in an advection–diffusion model to account of 137Cs mobility in floodplain sediment cores. This allowed sedimentation rates to be determined without the first year of detection for 137Cs being known and without having to assume that 137Cs remains immobile following deposition. Caesium-137 depth profiles in this environment are demonstrated to be an effective way of determining floodplain sedimentation rates. The total 137Cs inventory approach was found to be less successful, with only one of the three sites analysed being in unequivocal agreement with the depth profile results. The input of sediment from catchment sources that have little, or no, 137Cs attached results in true depositional sites having total inventories that are not significantly different from those of undisturbed reference sites. 相似文献
955.
Today the resources are becoming scarcer, which should not be regarded as unexhausted any more. Correspondingly, the production would be constrained by the scarcity of resources clearly. Then the economic researchers would pay much more attention to reducing the consumption of natural resources in the future. Therefore this paper brings foreword the conception of elasticity ratio of resource consumption based on the concept of elasticity and analyzes the relationship between the parameters. For the certain relationships between the elasticity ratio of resource consumption and resource consumption, this paper will try to reveal, to keep economy growing while resource consumption reducing, what conditions should be met as to the relationships among resource productivity, its growth rate, energy saving efficiency, economic growth rate and elasticity ratio of resource consumption. This paper proves the relationship between the China's energy consumption and economy growth using statistic data from 1978 to 2003. 相似文献
956.
This paper presents industrial experience of process identification, monitoring, and control in a full-scale wastewater treatment plant. The objectives of this study were (1) to apply and compare different process-identification methods of proportional-integral-derivative (PID) autotuning for stable dissolved oxygen (DO) control, (2) to implement a process monitoring method that estimates the respiration rate simultaneously during the process-identification step, and (3) to propose a simple set-point decision algorithm for determining the appropriate set point of the DO controller for optimal operation of the aeration basin. The proposed method was evaluated in the industrial wastewater treatment facility of an iron- and steel-making plant. Among the process-identification methods, the control signal of the controller's set-point change was best for identifying low-frequency information and enhancing the robustness to low-frequency disturbances. Combined automatic control and set-point decision method reduced the total electricity consumption by 5% and the electricity cost by 15% compared to the fixed gain PID controller, when considering only the surface aerators. Moreover, as a result of improved control performance, the fluctuation of effluent quality decreased and overall effluent water quality was better. 相似文献
957.
958.
使用加速量热仪(ARC)研究硝酸异辛酯(EHN)的热分解,得到热分解温度随时间的变化曲线,自放热速率、分解压力随温度的变化曲线以及分解压力随升温速率的变化曲线。分析在绝热条件下硝酸异辛酯的热分解反应动力学和热分解过程,计算表观活化能、指前因子和反应热等参数。根据绝热热分解的起始温度和反应热数据,给出硝酸异辛酯在反应危险度等级中的分类,并计算在75℃时的反应风险指数。 相似文献
959.
竹地板与普通实木地板燃烧性能的锥形量热仪对比实验研究 总被引:3,自引:1,他引:2
随着竹地板的广泛应用,竹木地板的火灾燃烧性能也将引起人们的关注.本文采用锥形量热仪对竹木地板的引燃时间、热释放速率、总热释放和一氧化碳的产率及体积比浓度等燃烧性能与普通实木地板进行了比较研究.研究结果表明:在相同条件下,竹木地板试样的引燃时间较短,临界引燃辐射热通量较低,引燃危险相对较大;竹木地板试样燃烧中第一个热释放速率峰值出现的时间短,且峰值相对较大,其潜在的轰燃危险相对较大;此外,竹木试样的一氧化碳的产率和燃烧初期在烟气中的体积比浓度相对较大. 相似文献
960.
某铀矿山废石场及尾砂库氡污染调查 总被引:5,自引:0,他引:5
黄建兵 《环境监测管理与技术》2001,13(2):27-30
通过对某退役铀矿山的 14个废石堆放场及 3个尾砂库氡析出率的测量及内照射剂量的估算 ,表明 ,只有一个废石场的氡析出率超过国家规定的管理限值水平 ;尾砂库的氡析出率较高 ,个别测点的氡析出率超出管理限值水平近 7倍 ;因氡析出而使当地居民额外所受的年最大有效剂量当量为 0 0 5 8mSv。指出在尾砂库表面覆盖黄土 ,可以有效降低氡析出水平 ,当覆盖厚度达 0 5m时 ,可将氡析出水平降低 84%以上。 相似文献