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21.
Fe3+催化氧化S(Ⅳ)反应机理初探 总被引:2,自引:0,他引:2
通过分析酸性条件下(pH为1~3),Fe3 催化氧化S(Ⅳ)过程中溶液吸光度变化的趋势,对Fe3 催化氧化S(Ⅳ)的反应机理进行了初步推导.实验证明,液相中该反应机理主要是催化氧化与自由基反应相结合,O2的存在对于反应有重要作用,O-2的生成是S(Ⅳ)被氧化的关键;当水中溶解氧接近耗尽时,反应进程发生改变.当Fe3 、S(Ⅳ)浓度增加,自由基生成量增加时,有利于反应进行;作为反应产物,Fe2 、S(Ⅵ)浓度增加,反应推动力减小,反应速率降低;同时Fe2 、SO24-可以与溶液中的其它物质形成配合物,影响了Fe3 -S(Ⅳ)配合物的生成与分解,不利于S(Ⅵ)的氧化. 相似文献
22.
沼泽红假单胞菌H3对酸性红B2GL染料的厌氧脱色和降解作用 总被引:7,自引:0,他引:7
从印染厂污泥中分离到一株沼泽红假单胞菌(RhodopseudomonaspalustrisH3),在光照厌氧条件下该菌生长细胞可将100mg/L酸性红B2GL染料去除到30mg/L.完整细胞脱色的最适条件为pH70,温度30℃,细胞浓度20—25mg/mL(湿重).低浓度的阳离子对脱色影响不大.在通Ar气使严格厌氧和加有还原性辅酶I的条件下无细胞提取液的脱色活性最高,比活率为154×10-2mg/(mg·h).根据降解产物的分析,推断了该菌对酸性红染料的降解代谢途径. 相似文献
23.
24.
湿式氧化技术处理炼油厂碱渣废水 总被引:3,自引:0,他引:3
考察了湿式氧化法处理运行过程 ,以及相关参数的控制方案。在实现装置出水、废气达标排放的前提下 ,稳定控制装置运行是可以实现的。如后续有酸化除酚工艺和SBR工艺进行再处理 ,则应选用温度 (14 5± 5 )℃ ,压力控制在 0 6~ 0 .7MPa的湿式氧化法 相似文献
25.
范炳均 《石油化工环境保护》2002,25(3):23-26
介绍某公司腈纶污水的水质特点,处理工艺、主要设备及构筑物设计参数。该污水预处理装置运行以来,处理效果良好,符合后续生化处理的进水要求。 相似文献
26.
《环境科学学报(英文版)》2023,35(4):387-395
This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H2O2, UV/TiO2 and UV/K2S2O8 (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H2O2 process, and the higest removal rate even reached to 83%. UV/TiO2 and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H2O2 was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics. 相似文献
27.
工程菌处理高纯二甲醚生产废水的研究 总被引:3,自引:0,他引:3
工程菌LEY7是以假单胞菌D3 菌株 (Pseudomonassp.D3 )为受体 ,以缓慢牙孢杆菌 3RM2 菌株 (Bacilluslentus 3RM2 ) ,假单胞菌W1 (Pseudomonassp .W1 )和W2 (Pseudomonassp .W2 )为供体 ,用多基因转化原生质球构建而成。工程菌LEY7能同时降解 4种化合物。用工程菌LEY7处理化工废水 ,工艺采用二级氧化。处理效果 :进水COD =10 0 0mg/L ,处理后出水COD在 10 0mg/L以下。COD去除率达到 90 %以上。 相似文献
28.
Guofei Jiang Benjie Zhu Junzhi Sun Fang Liu Yongqiang Wang Chaocheng Zhao 《环境科学学报(英文版)》2023,35(3):244-257
High-efficiency photocatalysts are of great significance for the application of photocatalytic technology in water treatment.In this study,N/Cu co-doped ZnS nanosphere photocatalys(N/Cu-ZnS) is synthesized by a hydrothermal method for the first time.After doping,the tex ture of nanosphere becomes loose,the nanometer diameter is reduced,making the specific surface area of catalyst increased from 34.73 to 101.59 m2/g.The characterization results show that more ZnS (111) crystal planes a... 相似文献
29.
《环境科学学报(英文版)》2023,35(4):263-274
The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H2-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOFCo) being 245°C, 1.23 × 10−3 moltoluene/(gcat·sec), and 11.58 × 10−3 sec−1 for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO2, SO2 or NH3, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O2 and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H2O and CO2. 相似文献
30.
长炼第二污水处理场氧化沟工艺运行小结 总被引:2,自引:1,他引:2
臭伯尔氧化沟池容大,停留时间长,运行稳定,对氧化沟污泥培养及开工运行进行了小结,并结合运行过程中的几个问题进行了分析和探讨。 相似文献