生物化学法处理含酚废水的研究进展

含酚废水来源广、数量多，对人体和动植物都有很大的危害，因此．．必须对舍酚废水进行有效的处理。综述了含酚废水的处理技术和处理结果，特别是对生物法处理含酚废水的现状与发展进行了介绍和评述。     

Measurement of the Oxygen Mass Transfer Through the Air-Water Interface (5 pp)

Goal, Scope and Background Gas mass transfer through the liquid-gas interface has enormous importance in various natural and industrial processes. Surfactants or insoluble compounds adsorbed onto an interface will inhibit the gas mass transfer through the liquid-gas surface. This study presents a technique for measuring the oxygen mass transfer through the air-water interface. Experimental data obtained with the measuring device were incorporated into a novel mathematical model, which allowed one to calculate diffusion conduction of liquid surface layer and oxygen mass transfer coefficient in the liquid surface layer. Methods A special measurement cell was constructed. The most important part of the measurement cell is a chamber containing the electrochemical oxygen sensor inside it. Gas exchange between the volume of the chamber and the external environment takes place only through the investigated surface layer. Investigated liquid was deoxygenated, which triggers the oxygen mass transfer from the chamber through the liquid-air interface into the liquid phase. The decrease of oxygen concentration in the cell during time was measured. By using this data it is possible to calculate diffusional parameters of the water surface layer.Results Diffusion conduction of oxygen through the air-water surface layer of selected wastewaters was measured. The diffusion conduction of different wastewaters was about 3 to 6 times less than in the unpolluted water surface. It was observed that the dilution of wastewater does not have a significant impact on the oxygen diffusion conduction through the wastewater surface layer. This fact can be explained with the presence of the compounds with high surface activity in the wastewater. Surfactants achieved a maximum adsorption and, accordingly, the maximum decrease of oxygen permeability already at a very low concentration of surfactants in the solution. Oxygen mass transfer coefficient of the surface layer of the water is found to be.Conclusion A simple technique for measuring oxygen diffusion parameters through the air-water solution surface has been developed. Derived equations enable the calculation of diffusion parameters of the surface layer at current conditions. These values of the parameters permit one to compare the resistances of the gas–liquid interface to oxygen mass transfer in the case of adsorption of different substances on the surface layer. Recommendation and Outlook This simple technique may be used for a determination of oxygen permeability of different water-solution surface layers. It enables one to measure the resistance to the oxygen permeability of all inflowing wastewater surface layers in the wastewater treatment plant, and to initiate a preliminary cleaning of this wastewater if required. Similarly, we can measure oxygen permeability of natural waterbodies. Especially in the case of pollution, it is important to know to what extent the oxygen permeability of the water surface layer has been decreased. Based on the tehnique presented in this research, fieldwork equipment will be developed.     

工业污水可生物降解性评价方法研究

针对生化系统经常遭受异常进水或毒性物质冲击的情况,提出了以耗氧速率(OUR)和相对耗氧速率(SOUR)快速评价污水可生物降解性的方法,以提高活性污泥系统的处理效率和运行管理水平。试验结果表明:OUR和SOUR对异常pH值水质条件以及苯酚、甲醛和甲醇等毒性物质的存在都非常敏感。对于大庆石化公司水气厂化工污水处理场的活性污泥来说,甲醛对微生物的毒性最强,甲醇次之,而苯酚则最弱。化工污水处理场活性污泥对三者的允许浓度分别为70、170、350 mg/L。     

COMPUTER-OPTIMIZED STORMWATER TREATMENT (COST) PROGRAM: PHILADELPHIA CASE STUDY1

ABSTRACT: Two computer models, the Continuous Stormwater Pollution Simulation System (CSPSS) and the Computer Optimized Storm-water Treatment Program (COST), were developed to aid in performing water quality planning. This paper describes COST and its site specific applications to the Philadelphia urban area, using the results from an updated CSPSS receiving water simulation. COST provides a planning and conceptual design tool to identify the economically optimum combination of wet weather and dry weather pollution abatement alternatives. Economic analysis procedures incorporated are based on production theory and marginal cost analysis. This study demonstrates that by transforming BOD removal to reduction in low DO events, using CSPSS results, the benefits associated with pollutant removal can be accounted for explicitly by COST simulations. This is important because a pound of BOD removed from combined sewer overflow may be of more benefit to the receiving water than a pound of BOD removed from urban stormwater runoff. The selection of a pollution control strategy is often a difficult decision which should consider social, political, financial, and regulatory factors. It is suggested that such a selection can be based on evaluating the tradeoffs between total annual costs and receiving water improvements, as determined using the COST and CSPSS programs.     

WATER QUALITY IMPACTS AND INDICATORS OF METABOLIC ACTIVITY OF THE ZEBRA MUSSEL INVASION OF THE SENECA RIVER1

ABSTRACT: The conspicuous shifts in summertime values of common measures of water qualify that have persisted for 10 years (1993 to 2002) in the Seneca River, New York, as a result of the zebra mussel invasion are documented. Resolution of patterns in time and space is supported by water quality monitoring that extends back to the late 1970s. Patterns are evaluated to describe the stability of impacts and quantify metabolic activity of the invader. The water quality impacts that have persisted unabated for 10 years since the invasion are the most severe documented for a river in North America. Changes in summer median conditions since the invasion include: (1) a 16‐fold decrease in chlorophyll concentration (Chi), (2) a 2.5‐fold increase in Secchi disc transparency, (3) a 17‐fold increase in soluble reactive phosphorus concentration, (4) a 3.7‐fold increase in total ammonia concentration, (5) a greater than 25 percent decrease in dissolved oxygen (DO) concentration, and (6) a decrease in pH of 0.55 units. The strength of these signatures has been driven by anthropogenic influences that include upstream nutrient loading and morphometric modifications of the river, and the functioning of Cross Lake, through which the river flows. This hypereutrophic lake sustains dense zebra mussel populations and related water quality impacts in the river downstream of the lake outflow by acting as a source of veligers and suitable food for this bivalve. Evidence is presented that levels of metabolic activity of the zebra mussel in this river have been resource limited, manifested through increased consumption of Chl and DO with increased delivery of these constituents in the lake's outflow.     

生物接触氧化法在炼油废水回用处理中的应用

利用生物接触氧化法对炼油厂的外排污水进行深度处理,在曝气时间大于3h的情况下,可以有效地降低COD、氨氮,伴随硝化反应的发生,出水的碱度也下降。当停留时间足够时,水气比对水中溶解氧的浓度影响不大,较低的有机物浓度成为微生物降解活动的限制因素。经过生物接触氧化处理后的污水的腐蚀速率反而升高,体现出微生物的腐蚀作用和硝化反应的作用。     

试论工业氧气管道的事故原理与控制技术

系统阐述了工业氧气管道燃爆事故的一些重要原因 ,通过事故树分析了各种事故致因的逻辑关系 ,并提出了对其进行预防和控制的机理和方法     

Removal and recycling of copper from aqueous solutions using treated Indian barks

Removal of copper from aqueous solutions containing 100–1000 ppm, using different Indian bark species, was performed on laboratory scale. The percentage removal of metal ions depends on the solution pH, bark species and time. The efficiency of copper removal by the used raw barks increases with a rise of solution pH and reaches a maximum of about 65–78% around pH 4–5. However, the decontaminated aqueous solutions were colored due to the dissolution of soluble organic compounds contained in the raw bark. This increases the biological and chemical oxygen demand (BOD and COD) of the solutions as well as the total organic carbon content (TOC). For this reason, raw bark should be treated either by chemical or biological means. Such treatment will allow the extraction of the soluble organic compounds and increase the chelating capacity and efficiency of the treated bark. Depending on the pH value, the chelating efficiency of treated barks is about 1.2–2.2 times that of the raw ones. Moreover, the retention capacity of the Indian treated bark varies from about 42–51 mg/g of dry bark. It is equal to or higher than that of common European species. About 1.8 mols of H₃O⁺ are released, by the treated barks, for every mol of chelated copper ions. Moreover, scanning electron microscopy (SEM) observations show uniform distribution of metal ions throughout the copper saturated bark. Infra red (IR) spectra suggest that the copper ions are chelated to hydroxyl and/or carboxyl functional groups of organic compounds contained in the treated bark. It seems that the interaction of the copper ions with the bark follows a cation exchange mechanism. This hypothesis is supported by elution experiments that allow recovery of about 99% of the contained copper. The retention capacity of the treated bark is almost constant after five cycles of chelation–elution, suggesting that the ‘life time cycle' is sufficiently long for continuous industrial application. The spent copper loaded barks can either be incinerated or pyrolysed. It generates solids containing either ≈80% of CuO or ≈14% of Cu°, respectively. Such materials can be used either in the secondary or primary copper production, thus offering a friendly environmental solution of effluents' treatment. The suggested process can be used as an alternative to the classical technologies for effluent decontamination. It is also efficient for polishing effluents treated by other methods.     

THE EFFECTS OF ARTIFICIAL CIRCULATION ON A HYPEREUTROPHIC LAKE1

ABSTRACT: Crystal Lake, a small urban lake in Robbinsdale, MN, had been artificially circulated for 12 years before a detailed water quality evaluation was undertaken. In 1986, the circulation system was shut off for a two-year assessment. Although the lake remained hypereutrophic, the use of the lake, which included shoreline fishing and feeding ducks and geese, did not appear to be seriously impaired by the absence of artificial circulation. The circulation system was returned to service in October 1987 (there are 16 diffusers in this 0.31 km^?2 lake). Continuous limnological data from October 1987 through October 1988, plus several sampling dates in 1989, compares to the two non-circulation years (1986 and 1987) as follows: there was a two- to three-fold increase in the lake's concentration of total phosphorus, total Kjeldahl nitrogen, and chlorophyll and a similar decrease in Secchi disk transparency. The surface oxygen concentration was reduced and the deep waters were nearly anoxic. In fact, following a wind storm in 1988, the entire lake became anoxic due to the mixing of high BOD throughout the water column, and a summertime fish-kill resulted. All of these occurrences are related to the artificial circulation of the lake.     

EFFECT OF THE PAPER INDUSTRY ON WATER QUALITY OF THE LOWER FOX RIVER1

ABSTRACT: The Lower Fox River, Wisconsin, hosts the densest concentration of paper mills in the US., with 18 located along a 4Gde stretch between Lake Winnebago and Green Bay, Lake Michigan. Some of these companies use only primary, others also secondary, waste treatment techniques. Comparison of the quantities of wastes discharged with the legal limits indicates that all plants discharge only 40-50 percent or less of the allowable suspended solids; most discharge < 50 percent of the allowable BOD. This is equal or better than the performance of paper companies elsewhere in the state. Reductions in pollutant discharges have corresponded to improved water quality, though too much BOD is still discharged to be adequately assimilated by the Fox River. The relatively low current level of discharges means permit levels would have to be drastically cut to make any significant impact on water quality. Only a few companies might be seriously affected by such changes. Flow and temperature related permits would likely be more effective, but more difficult to comply with for the industry. Toxic substances are also a potential problem, particularly chlororganic compounds that can form in situ from the chlorine frequently used for pulp bleaching.