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921.
922.
Peter A. Cott Paul K. Sibley Andrew M. Gordon R.A. Bodaly Kenneth H. Mills W. Murray Somers Gerald A. Fillatre 《Journal of the American Water Resources Association》2008,44(2):328-342
Abstract: In northern regions, large volumes of water are needed for activities such as winter road construction. Such withdrawals, particularly from small lakes, can reduce oxygen concentrations and water levels, potentially affecting aquatic organisms. Withdrawal limits have been developed by regulatory agencies, but are largely theoretical. Water withdrawal thresholds were tested in two small lakes by removing 10% and 20% of their respective under‐ice volumes and comparing oxygen parameters, temperature, over‐wintering habitat, and northern pike (Esox lucius) abundance to reference conditions. Because of a milder winter, oxygen parameters were elevated in reference lakes in the period following withdrawal compared to the prewithdrawal period. The 10% withdrawal resulted in a ?0.2 m shift in the oxygen concentration profile at 4 mg/l in that lake, but had no effect on total volume‐weighted oxygen, or volume of over‐wintering habitat. In contrast, the 20% withdrawal caused 0.7 m reduction in the oxygen concentration profile at 4 mg/l compared to the previous year, a 26% decline in the volume‐weighted oxygen concentration, and a 23% reduction in the volume of over‐wintering habitat compared to prewithdrawal conditions. Water temperatures were slightly (≤ 10%) colder in the upper strata in the year following the withdrawal in both withdrawal and reference lakes. Northern pike abundance was not impacted by water withdrawals in either of the lakes. The results of this study show that the effects of water withdrawal on the parameters investigated reflected the characteristics of the lakes, and would therefore be expected to vary from lake to lake. Policy development to mitigate impacts must therefore reflect the site‐specific nature of water withdrawal. 相似文献
923.
Phenylated arsenic compounds occur as highly toxic contaminants in former military areas where they were formed as degradation products of chemical warfare agents. Some phenylarsenic compounds such as roxarsone and aminophenylarsonic acids were applied as food additive and veterinary drugs in stock-breeding and therefore pose an environmental risk in agricultural used sites. Very few data exist in the literature concerning uptake and effects of phenylarsenic compounds in plants growing on contaminated soils. In this study, the accumulation, extractability, and metabolization of five different phenylarsenic compounds, phenylarsonic acid, p- and o-aminophenylarsonic acid, phenylarsine oxide, and 3-nitro-4-hydroxyphenylarsonic acid called roxarsone, by the terrestrial plant Tropaeolum majus were investigated. Ion chromatography coupled to inductively coupled plasma mass spectrometry was used to differentiate these arsenic compounds, and inductively coupled plasma atomic emission spectroscopy was used for total arsenic quantification. All compounds considered were taken up by the roots and transferred to stalks, leaves, and flowers. The strongest accumulation was observed for unsubstituted phenylarsonic acid followed by its trivalent analogue phenylarsine oxide that was mostly oxidized in soil whereas the amino- or nitro- and hydroxy-substituted phenylarsonic acids were accumulated to a smaller degree.The highest extraction yield of 90% for ground leaf material was achieved by 0.1 M phosphate buffer, pH 7.7, in a two-step extraction with a total extraction time of 24 h. The extraction of higher amounts of arsenic (50–70% of total arsenic present in leaves depending on arsenic species application) from non-ground intact leaves with deionized water in comparison with the buffer (20–40% of total arsenic) is ascribed to osmotic effects. The arsenic species analysis revealed a cleavage of the amino groups from the phenyl ring for plants treated with aminophenylarsonic acids. A further important metabolic effect consisted in the production of inorganic arsenate and arsenite from the phenylated arsonic acid groups. 相似文献
924.
The river Hindon is one of the important tributaries of river Yamuna in western Uttar Pradesh (India) and carries pollution
loads from various municipal and industrial units and surrounding agricultural areas. The main sources of pollution in the
river include municipal wastes from Saharanpur, Muzaffarnagar and Ghaziabad urban areas and industrial effluents of sugar,
pulp and paper, distilleries and other miscellaneous industries through tributaries as well as direct inputs. In this paper,
chemical mass balance approach has been used to assess the contribution from non-point sources of pollution to the river.
The river system has been divided into three stretches depending on the land use pattern. The contribution of point sources
in the upper and lower stretches are 95 and 81% respectively of the total flow of the river while there is no point source
input in the middle stretch. Mass balance calculations indicate that contribution of nitrate and phosphate from non-point
sources amounts to 15.5 and 6.9% in the upper stretch and 13.1 and 16.6% in the lower stretch respectively. Observed differences
in the load along the river may be attributed to uncharacterized sources of pollution due to agricultural activities, remobilization
from or entrainment of contaminated bottom sediments, ground water contribution or a combination of these sources. 相似文献
925.
Ambient particles vary greatly in their ability to affect visibility, climate and human health. The fine fraction of aerosol
is responsible for greater and wider effects on human health; thus, investigation of this fraction is very important. Continuous
measurements of PM2.5 (particulate matter below 2.5 μm in size) concentrations at the Preila monitoring station started in
2003. During a period of 2 years, the episodes of high daily and semi-hourly concentrations of PM2.5 were measured. These
episodes did not depend on the season or time of day. The substantial role of long-range transport of pollutants to these
increases in concentration was shown using chemical and statistical analysis. It was found that most of the severe episodes
occurred when air masses came from a specific site besides it was established that air masses of different origin were characterized
by different mixing layer depth. Lower mixing depth was observed in air masses characterized by higher observed concentrations
at the measuring site and vice versa. PM2.5 concentrations showed diurnal and seasonal variations whose pattern reflected
the regional origin of the aerosol. The regional pollution level was evaluated by the statistical analysis of PM2.5 concentrations.
The background annual average of PM2.5 mass concentration for the eastern coast of the Baltic Sea was 15.1 ± 0.8 μg m−3. 相似文献
926.
927.
928.
在实验室通过模拟土壤柱研究了人工地下水回灌过程中溶解性有机物的去除及其三卤甲烷生成势和三卤甲烷生成活性的变化.利用XAD树脂将回灌水中的溶解性有机物分为3个部分:疏水性有机酸、过渡亲水性有机酸和亲水性有机物.疏水性有机酸的三卤甲烷生成活性高于过渡亲水性有机酸和亲水性有机物.土壤含水层处理(SAT)对亲水性有机物的去除率为68.51%,对疏水性有机酸和过渡亲水性有机酸的去除率分别为58.64%和41.86%.经SAT系统处理后,溶解性有机物及各有机组分的三卤甲烷生成势减少,而三卤甲烷生成活性升高.疏水性有机酸是生成三卤甲烷的主要有机组分.亲水性有机物在SAT系统进水中的三卤甲烷生成活性较低,但由于含量高,三卤甲烷生成势也较大.而过渡亲水性有机酸由于含量和三卤甲烷生成活性较低,三卤甲烷生成势也较低. 相似文献
929.
制革废水水质、水量波动大,污染负荷重,有毒性,较难处理。本工程采用“预处理-混凝-水解酸化-循环式活性污泥法”处理制革废水,研究了C-TECH池曝气时间与CODCr、NH3-N负荷及DO的变化规律。结果表明,控制水解酸化池HRT12.5h,曝气时间8h,C-TECH池污泥浓度4.5g/L,CODCr污泥负荷0.4kg/(kg.d),NH3-N污泥负荷0.07kg/(kg.d),出水可达一级排放标准;通过可编程逻辑控制器PLC、在线DO测定仪及鼓风机变频装置控制DO浓度,用DO浓度作为循环式活性污泥池过程和反应时间控制参数,可节约能耗。 相似文献
930.