全文获取类型
收费全文 | 4297篇 |
免费 | 397篇 |
国内免费 | 1716篇 |
专业分类
安全科学 | 256篇 |
废物处理 | 167篇 |
环保管理 | 744篇 |
综合类 | 2978篇 |
基础理论 | 683篇 |
污染及防治 | 959篇 |
评价与监测 | 338篇 |
社会与环境 | 232篇 |
灾害及防治 | 53篇 |
出版年
2024年 | 7篇 |
2023年 | 53篇 |
2022年 | 121篇 |
2021年 | 140篇 |
2020年 | 128篇 |
2019年 | 158篇 |
2018年 | 163篇 |
2017年 | 192篇 |
2016年 | 264篇 |
2015年 | 246篇 |
2014年 | 314篇 |
2013年 | 421篇 |
2012年 | 410篇 |
2011年 | 446篇 |
2010年 | 354篇 |
2009年 | 463篇 |
2008年 | 274篇 |
2007年 | 320篇 |
2006年 | 316篇 |
2005年 | 271篇 |
2004年 | 204篇 |
2003年 | 176篇 |
2002年 | 147篇 |
2001年 | 128篇 |
2000年 | 108篇 |
1999年 | 103篇 |
1998年 | 75篇 |
1997年 | 68篇 |
1996年 | 69篇 |
1995年 | 73篇 |
1994年 | 43篇 |
1993年 | 28篇 |
1992年 | 33篇 |
1991年 | 20篇 |
1990年 | 14篇 |
1989年 | 5篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 4篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有6410条查询结果,搜索用时 31 毫秒
181.
182.
183.
Catalytic oxidation is widely used in pollution control technology to remove volatile organic compounds. In this study, Pd/ZSM-5 catalysts with different Pd contents and acidic sites were prepared via the impregnation method. All the catalysts were characterized by means of N2 adsorption- desorption, X-ray fluorescence (XRF), HE temperature programmed reduction (H2-TPR), and NH3 temperature programmed desorption (NH3-TPD). Their catalytic performance was investigated in the oxidation of butyl acetate experiments. The by-products of the reaction were collected in thermal desorption tubes and identified by gas chromatography/mass spectrometry. It was found that the increase of Pd content slightly changed the catalytic activity of butyl acetate oxidation according to the yield of CO2 achieved at 90%, but decreased the cracking by-products, whereas the enhancement of strong acidity over Pd-based catalysts enriched the by-product species. The butyl acetate oxidation process involves a series of reaction steps including protolysis, dehydrogenation, dehydration, cracking, and isomerization. Generally, butyl acetate was cracked to acetic acid and 2- methylpropene and the latter was an intermediate of the other by-products, and the oxidation routes of typical by-products were proposed. Trace amounts of 3-methylpentane, hexane, 2-methylpentane, pentane, and 2-methylbutane originated from iso4merization and protolysis reactions. 相似文献
184.
Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon(AC) for H2 S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H2 S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N2 adsorption, X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N2-H2S-H2-CO-Hg atmosphere(simulated coal gas) was higher than that in N2-H2S-Hg and N2-Hg atmospheres, which showed that H2 and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N2-H2S-Hg and N2-Hg atmospheres. 相似文献
185.
Yuguang Zhang Jing Cong Hui Lu Guangliang Li Yuanyuan Qu Xiujiang Su Jizhong Zhou Diqiang Li 《环境科学学报(英文版)》2014,26(8):1717-1724
Acidobacteria is one of the most dominant and abundant phyla in soil,and was believed to have a wide range of metabolic and genetic functions. Relatively little is known about its community structure and elevational diversity patterns. We selected four elevation gradients from 1000 to 2800 m with typical vegetation types of the northern slope of Shennongjia Mountain in central China. The vegetation types were evergreen broadleaved forest,deciduous broadleaved forest,coniferous forest and sub-alpine shrubs. We analyzed the soil acidobacterial community composition,elevational patterns and the relationship between Acidobacteria subdivisions and soil enzyme activities by using the 16 S rRNA meta-sequencing technique and multivariate statistical analysis. The result found that 19 known subdivisions as well as an unclassified phylotype were presented in these forest sites,and Subdivision 6 has the highest number of detectable operational taxonomic units(OTUs). A significant single peak distribution pattern(P 0.05) between the OTU number and the elevation was observed. The Jaccard and Bray–Curtis index analysis showed that the soil Acidobacteria compositional similarity significantly decreased(P 0.01) with the increase in elevation distance. Mantel test analysis showed the most of the soil Acidobacteria subdivisions had the significant relationship(P 0.01) with different soil enzymes. Therefore,soil Acidobacteria may be involved in different ecosystem functions in global elemental cycles. Partial Mantel tests and CCA analysis showed that soil pH,soil temperature and plant diversity may be the key factors in shaping the soil Acidobacterial community structure. 相似文献
186.
采用了等体积浸渍法制备二氧化钛负载钒氧化物催化剂(V2O5/TiO2),研究了V2O5负载量、反应温度、烟气流量、氨氮比以及运行时间各因素对NH3选择性催化还原NO反应(SCR)效率的影响.研究结果表明:经过500℃温度下煅烧,烟气流量为200ml/min,负载量为7wt%的V2O5/TiO2催化剂,在400℃温度下反应,NO脱除率可达70.5%. 相似文献
187.
188.
189.
低C/N污水的生化处理过程中,由于碳源不足,不能满足硝化和反硝化的要求,造成出水NH3-N超标。采用SBR工艺对某基地污水处理站厌氧处理后的低C/N污水进行改造,处理后出水COD去除率达到97%以上,NH3-N去除率达到93%以上。 相似文献
190.
分析2013年大气降水pH值及近10年历史演变的方法分析丹东市酸雨污染现状、特征,并从污染源和气候条件解释酸雨形成的原因,确定酸雨的形成受外来空气污染物影响较大,而酸雨强度的大小具有本地环境条件和环境污染特征。 相似文献