农药施用对兴凯湖水中农药残留的影响及其风险评价

主要研究了中国东北兴凯湖周围水稻种植区域农药残留以及对湖水水质的影响.分别于水稻抽穗期和水稻成熟期在兴凯湖地区对稻田、排干和大小兴凯湖地表水进行采集并对27种农药及其降解产物进行分析.结果表明,在水稻抽穗期所分析的27种农药及其降解产物全部检出,总浓度范围为247.97~6 094.49 ng·L^-1;水稻成熟期检出25种,总浓度范围为485.36~796.23 ng·L^-1,两时期对比,抽穗期的农药及其降解产物检出数量更多且总浓度更高;在水稻抽穗期阿特拉津、西草净和多效唑为主要检出农药,在水稻成熟期阿特拉津和稻瘟灵为主要检出农药;大小兴凯湖水中农药的分布特征与排干水相似,表明大小兴凯湖水中农药及其降解产物很可能来源于稻田排干的输入;在排干和大小兴凯湖水中,阿特拉津、西草净、扑草净、丁草胺、稻瘟灵和草酮RQ均值大于0.1,对水生生物存在潜在生态风险.     

基于物种敏感性分布法的毒死蜱对稻田生态系统生态风险评价

生物敏感性分布法(Species Sensitivity Distributions,SSD)是一种基于单物种测试和概率统计学的、较高级的外推风险评估方法。该方法在国内外均被广泛应用于各种污染物风险评价中。本文选取了采用logistic和normal这2种SSD分布模型,分析了国内外毒死蜱对3组水生生物组合的毒性数据;并且获得各自SSD的HCx值。3组毒性数据分别为:浙江稻田水生生物组,长三角地区水生生物组和美国水生生物组。浙江稻田水生物SSD分布的HC5为:0.32μg·L~(-1)(logistic模型)和0.35μg·L~(-1)(normal模型);HC10为1.50μg·L~(-1)(logistic模型)和1.26μg·L~(-1)(normal模型);HC20为8.13μg·L~(-1)(logistic模型)和5.96μg·L~(-1)(normal模型);HC50为145.44μg·L~(-1)(logistic模型)和115.74μg·L~(-1)(normal模型)。据此判断水稻种植季节,稻田水域毒死蜱对食蚊鱼、鳑鲏、泽蛙蝌蚪、轮虫、常见腹足类和双壳类软体动物以及绝大多数藻类等的风险较小。利用冗余分析研究了生物物种数量、物种组成结构和拟合模型对HCx影响。结果表明:物种组成结构对HCx有较为明显的影响。具体表现为对毒死蜱较为敏感物种数量与HCx存在明显的负相关性;对毒死蜱不敏感的物种则与HCx呈现正相关性。     

Use pattern of pesticides and their predicted mobility into shallow groundwater and surface water bodies of paddy lands in Mahaweli river basin in Sri Lanka

Pesticides applied on agricultural lands reach groundwater by leaching, and move to offsite water bodies by direct runoff, erosion and spray drift. Therefore, an assessment of the mobility of pesticides in water resources is important to safeguard such resources. Mobility of pesticides on agricultural lands of Mahaweli river basin in Sri Lanka has not been reported to date. In this context, the mobility potential of 32 pesticides on surface water and groundwater was assessed by widely used pesticide risk indicators, such as Attenuation Factor (AF) index and the Pesticide Impact Rating Index (PIRI) with some modifications. Four surface water bodies having greater than 20% land use of the catchment under agriculture, and shallow groundwater table at 3.0 m depth were selected for the risk assessment. According to AF, carbofuran, quinclorac and thiamethoxam are three most leachable pesticides having AF values 1.44 × 10^?2, 1.87 × 10^?3 and 5.70 × 10^?4, respectively. Using PIRI, offsite movement of pesticides by direct runoff was found to be greater than with the erosion of soil particles for the study area. Carbofuran and quinclorac are most mobile pesticides by direct runoff with runoff fractions of 0.01 and 0.08, respectively, at the studied area. Thiamethoxam and novaluron are the most mobile pesticides by erosion with erosion factions of 1.02 × 10^?4 and 1.05 × 10^?4, respectively. Expected pesticide residue levels in both surface and groundwater were predicted to remain below the USEPA health advisory levels, except for carbofuran, indicating that pesticide pollution is unlikely to exceed the available health guidelines in the Mahaweli river basin in Sri Lanka.     

我国和东亚地区硫化物的大气输送研究——流场分型统计输送模式

提出了一种流场分型欧拉酸沉降输送模式,计算了1993年4月东亚地区硫氧化物平均浓度的时空分布以及我国各省区和东亚主要国家的硫沉降量?通过与实测资料对比,模式有较好的可信度,是一个计算硫氧化物长期平均浓度和硫沉降的简便?实用的酸沉降输送模式?      

发电与高压输变电工程的工频电磁场现状及防护

通过对典型发电与高压输变电工程工频电磁场的现场检测,阐明了发电与高压输变电工程的工频电磁场现状.在此基础上,根据科学界关于极低频电磁场对人体短期和长期效应研究的明确结论,介绍了发电与高压输变电工程的工频电磁场暴露对人体健康的影响.同时,从卫生安全的角度提出了防止和减少工频电磁场影响的综合防护措施,其中包括:慎重选址,合理设计,适当个体防护和必要的警示标识.另外,扼要地介绍了工频电磁场的有关卫生标准和测量方法.     

TAMMEF therapy in the treatment of shoulder periarthritis: efficacy and safety

The utility and the safety of the extremely low frequencies (ELF) electromagnetic fields in the treatment of numerous diseases have been demonstrated. Moreover, the effects of these fields seem to depend on their respective codes (frequency, intensity, waveform). We want to value the effects and the safety of the therapeutic application of a musically modulated electromagnetic field (TAMMEF) system, which field is piloted by a musical signal and its parameters (frequency, intensity, waveform) are modified in time, randomly varying within the respective ranges, so that all possible codes can occur during a single application. Sixty subjects, affected by shoulder periarthritis were enrolled in the study and randomly divided into three groups of 20 patients each: the first exposed to TAMMEF, the second exposed to ELF, the third exposed to a simulated field. All subjects underwent a cycle of 15 daily sessions of 30 min each and a clinical examination upon enrolment, after 7 days of therapy, at the end of the cycle and at a follow-up 30 days later. All the patients of TAMMEF group and ELF group completed the therapy without the appearance of side effects: they presented a significant improvement of the subjective pain and the functional limitation, which remained stable at the follow-up examination. In those exposed to a simulated field group, there was no improvement of the pain symptoms or articular functionality. This study suggests that the TAMMEF system is efficacious and safe in the control of pain symptoms and in the reduction of functional limitation in patients with shoulder periarthritis. Moreover, the effects of the TAMMEF system cover those produced by the ELF field.     

Exposure to electromagnetic fields in the magnetic resonance imaging environment in South Africa

Occupational exposure to radiofrequency (RF) and static magnetic fields at magnetic resonance imaging (MRI) suites is of continuing concern to personnel who routinely work in this environment. Questions regarding the levels of occupational RF and static field exposure have increased with the increasing demand for anesthetics to be administered in this environment. The present study was thus designed towards addressing the above-mentioned problem by gaining information regarding exposure levels of clinical personnel at MRI units in South Africa. Three 1.5 MRI units in Bloemfontein, South Africa were utilized to evaluate the exposure of clinical personnel to the electromagnetic fields present in the MRI environment over a period of time and during different clinical MRI procedures. Three rounds of measurements of RF fields in the MRI environment were done. All the three measurement rounds were focused on the low frequencies, 5 Hz–32 kHz, as well as on the high frequencies, 300 kHz–40 GHz. First round measurements were done to establish the background of the RF fields in and around the magnet room during an MRI examination. Second round RF field measurements were done at a specific location, 1 m away from the bore on the right-hand side of the bed, in the MRI room. The third round measurements were of the same format as the second round, but the specific location was against the magnet bore. Two pieces of Narda Safety Test Solution instruments, the EFA-300 and EMR-300, were used to measure the electromagnetic and magnetic exposure fields generated from the MRI scanners. Results of the measurements indicate that the electromagnetic fields measured during different clinical procedures do not exceed the International Commission on Non-Ionizing Radiation Protection (2000) guidelines in these units. Results from round two and three showed that the RF and gradient exposure 1 m and up against the bore entrance does not exceed these guidelines (rms average over 6 min). Ongoing new developments in MRI scanning create the need for continuously monitoring exposure of patients and workers to the EMF fields in the MRI environment.     

洞庭湖湿地稻区化肥环境影响评估

研究采用时间序列分析法,预测洞庭湖区2010年2、020年人口将分别达到1 396.38×104人、1 492.31×104人,稻谷总需求量分别为5 002.17×103t,5 284.79×103t,化肥投入实物量将分别为1 466.91×103t,1 549.79×103t。在总结国内外化肥投入影响环境研究基础上建立了化肥环境影响评估模型,预计2010,2020年洞庭湖区区水稻生产因化肥带来环境成本将分别达到2.2×108元、2.32×108元,占稻谷销售效益的3.4%和3.13%,稻田生态系统和社会将难以承受,建议政府在化肥过量施用的地区征收化肥环境税。     

Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China

Heavy metal concentrations in agricultural soils of Zhejiang Province were monitored to indicate the status of heavy metal contamination and assess environmental quality of agricultural soils. A total of 908 soil samples were collected from 38 counties in Zbejiang Province and eight heavy metal （Cd, Cr, Pb, Hg, Cu, Zn, Ni and As） concentrations had been evaluated in agricultural soil. It was found 775 samples were unpolluted and 133 samples were slightly polluted and more respectively, that is approximately 14.65% agricultural soil samples had the heavy metal concentration above the threshold level in this province by means of Nemerow＇s synthetical pollution index method according to the second grade of Standards for Soil Environmental Quality of China （GB15618- 1995）. Contamination of Cd was the highest, followed by Ni, As and Zn were lower correspondingly. Moreover, Inverse Distance Weighted （IDW） interpolation method was used to make an assessment map of soil environmental quality based on the Nemerow＇s pollution index and the soil environmental quality was categorized into five grades. Moreover, ten indices were calculated as input parameters for principal component analysis （PCA） and the principal components （PCs） were created to compare environmental quality of different soils and regions. The results revealed that environmental quality of tea soils was better than that of paddy soils, vegetable soils and fruit soils. This study indicated that GIS combined with multivariate statistical approaches proved to be effective and powerful tool in the mapping of soil contamination distribution and the assessment of soil environmental quality on provincial scale, which is beneficial to environmental protection and management decision-making by local government.     

Fractionation and solubility of cadmium in paddy soils amended with porous hydrated calcium silicate

Previous studies have shown that porous hydrated calcium silicate （PS） is very effective in decreasing cadmium （Cd） content in brown rice. However, it is unclear whether the PS influences cadmium transformation in soil. The present study examined the effect of PS on pH, cadmium transformation and cadmium solubility in Andosol and Alluvial soil, and also compared its effects with CaCO3, acidic porous hydrated calcium silicate （APS） and silica gel. Soil cadmium was operationally fractionationed into exchangeable （Exch）, bound to carbonates （Carb）, bound to iron and manganese oxides （FeMnOx）, bound to organic matters （OM） and residual （Res） fraction. Application of PS and CaCO3 at hig rates enhanced soil pH, while APS and silica gel did not obviously change soil pH. PS and CaCO3 also increased the FeMnOx-Cd in Andosol and Carb-Cd in Alluvial soil, thus reducing the Exch-Cd in the tested soils. However, PS was less effective than CaCO3 at the same application rate. Cadmium fractions in the two soils were not changed by the treatments of APS and silica gel. There were no obvious differences in the solubility of cadmium in soils treated with PS, APS, silica gel and CaCO3 except Andosol treated 2.0% CaCO3 at the same pH of soil-CaC12 suspensions. These findings suggested that the decrease of cadmium availability in soil was mainly attributed to the increase of soil pH caused by PS.