太湖流域水环境天地一体化监测体系构建与应用

为全面提升中国水环境监测预警能力和水平,建立天地一体化监测体系,以太湖流域为研究区域,探索了水环境天地一体化监测方法,有效地结合地面常规监测与卫星遥感监测技术优势,弥补了现行环境监测体系的不足,为环境污染,生态变化,灾害监测、预警、评估及应急救助等指挥体系提供参考。     

洪泽湖硝基苯类化合物的污染特征

对洪泽湖水质、底泥及水生生物样品10种硝基苯类化合物的浓度进行了测定,水样中总硝基苯类化合物的含量在0.179~5.17μg/L,北部湖区和南部湖区的总硝基苯类化合物的浓度较高,其中成河北(S7)的浓度最高。底泥中的含量在0.137~4.50μg/kg,北部湖区及出湖口附近形成一个硝基苯类化合物的污染带,其中成河东(S6)的浓度最高。水生生物体内的总硝基苯含量按鲫鱼、白鱼、泥鳅、龙虾、河蚌、螺蛳依次升高。     

高温灰化—电极法测定乌伦古湖鱼中氟的方法初探

以乌伦古湖鱼体(鱼肉,不含鱼内脏)为研究对象,在碱性条件下,用硝酸镁固定样品中氟,高温灰化去除有机物,盐酸浸提,用离子缓冲溶液消除干扰离子,离子选择电极法测定乌伦古湖鱼中的氟。实际样品中加入1.00 mg/kg氟标准品,测定回收率分别为89.5%和88.0%,RSD为3.02%和4.29%。     

盘式固相萃取-液相色谱-串联质谱法快速测定地表水中n-壬基酚、n-辛基酚和双酚A

建立了盘式固相萃取?超高效液相色谱?串联质谱快速测定地表水中n?壬基酚、双酚A、n?辛基酚的方法。1L水样经过Φ47 mm的C18盘式固相萃取膜盘萃取净化,用二氯甲烷／甲醇（体积比1∶1）洗脱、浓缩定容至1 mL。采用Waters BEH C18色谱小柱,以甲醇?0?1％氨水溶液为流动相,梯度洗脱分离后,UPLC?MS／MS多级监测模式（ MRM）下以外标法进行定性定量分析。该方法检出限：双酚A为1 ng／L,n?壬基酚为0?1 ng／L,n?辛基酚为0?1 ng／L。对同一环境样品进行了3种质量浓度（5、50、200 ng／L）的加标回收实验,平均回收率为84?6％～118?8％,相对标准偏差为1?8％～8?3％。基于该方法,对巢湖入湖河流水样进行了检测,质量浓度为13?2～42?3 ng／ L。     

生态、经济协同发展的滨湖区空间管制分区研究——以巢湖东段为例

生态敏感性极高的滨湖区正面临着人类开发带来的环境威胁。旨在通过滨湖区空间管制,处理好保护与开发的关系,避免和减少开发过程中可能带来的负面环境问题,实现滨湖区持续、健康发展。应用模糊评价与GIS空间分析方法,首先从生态环境敏感性、经济发展潜力两大方面出发,构建了包括2项I 级指标、9项Ⅱ级指标和32项Ⅲ级指标的滨湖区空间管制分区评价指标体系;应用GIS空间分析模块,以500 m网格为基本评价单元,分别进行滨湖区的生态敏感性、经济发展潜力以及二者的叠加评价。结果显示：滨湖区从单元上可确定4类开发功能取向（适宜、较适宜、限制、禁止建设）,从区域生态、经济协同发展要求下,从满足生产、生活和生态的需要,宜将滨湖区划定不同功能的空间管制区     

Importance of sulfate reducing bacteria in mercury methylation and demethylation in periphyton from Bolivian Amazon region

Sulfate reducing bacteria (SRB) are important mercury methylators in sediments, but information on mercury methylators in other compartments is ambiguous. To investigate SRB involvement in methylation in Amazonian periphyton, the relationship between Hg methylation potential and SRB (Desulfobacteraceae, Desulfobulbaceae and Desulfovibrionaceae) abundance in Eichhornia crassipes and Polygonum densiflorum root associated periphyton was examined. Periphyton subsamples of each macrophyte were amended with electron donors (lactate, acetate and propionate) or inhibitors (molybdate) of sulfate reduction to create differences in SRB subgroup abundance, which was measured by quantitative real-time PCR with primers specific for the 16S rRNA gene. Mercury methylation and demethylation potentials were determined by a stable isotope tracer technique using ²⁰⁰HgCl and CH₃²⁰²HgCl, respectively. Relative abundance of Desulfobacteraceae (<0.01-12.5%) and Desulfovibrionaceae (0.01-6.8%) were both highly variable among samples and subsamples, but a significant linear relationship (p < 0.05) was found between Desulfobacteraceae abundance and net methylmercury formation among treatments of the same macrophyte periphyton and among all P. densiflorum samples, suggesting that Desulfobacteraceae bacteria are the most important mercury methylators among SRB families. Yet, molybdate only partially inhibited mercury methylation potentials, suggesting the involvement of other microorganisms as well. The response of net methylmercury production to the different electron donors and molybdate was highly variable (3-1104 pg g⁻¹ in 12 h) among samples, as was the net formation in control samples (17-164 pg g⁻¹ in 12 h). This demonstrates the importance of community variability and complexity of microbial interactions for the overall methylmercury production in periphyton and their response to external stimulus.     

Use of Synthetic Aperture Radar for Selecting Alaskan Lakes for Winter Water Use1

Abstract: Water resources are limited in many areas of the North Slope, Alaska, particularly during winter. Water is used by the oil industry for ice road construction and maintenance, drilling and facility operations, and potable water supplies. The coastal plain between Teshekpuk Lake, in the National Petroleum Reserve‐Alaska (NPR‐A) and the Colville River has numerous shallow lakes, but further south in the northern foothills of the Brooks Range, and east to the Canning River, lakes are fewer. While many oil and gas lease sales have been conducted, or are proposed, access to the leases may be limited because of the lack of available water for ice road construction. Ice roads are the main means by which exploration is conducted in the Arctic, putting a stress on freshwater bodies that do not freeze to the lakebed in winter. Lakes that do not freeze to the lakebed also serve as overwintering habitat for fish. The purpose of this paper is to report on the potential distribution of water bodies that may provide overwinter water in selected areas from Teshekpuk Lake to the Canning River. The project used synthetic aperture radar (SAR) imagery to search for the presence of water in lakes in March 2006. In the Kuparuk and Canning SAR images, 52 and 61% of lakes were frozen to their beds by March 2006, accounting for 49 and 57% of the lake area in these study regions. Conversely, only 2% of the lakes in the Teshekpuk region were frozen to the bottom by March 2006. Unfrozen water was more available because of deeper and more numerous lakes in the Teshekpuk Lake region (west) than in the Canning River area (east). While only specific SAR tiles were analyzed herein, the method will be a useful tool for land managers who seek to evaluate the potential for ice road construction across the Arctic.     

The Potential Use of Synthetic Aperture Radar for Estimating Methane Ebullition From Arctic Lakes1

Abstract: Arctic lakes are significant emitters of methane (CH₄), a potent greenhouse gas, to the atmosphere; yet no rigorous quantification of the magnitude and variability of pan‐Arctic lake emissions exists. In this study, we demonstrate the potential for a new method using synthetic aperture radar (SAR) imagery to detect methane bubbles in lake ice to scale up whole‐lake measurements of CH₄ ebullition (bubbling) to regional scales. We estimated ebullition from lakes, which is often the dominant mode of lake emissions, by mapping the distribution of bubble clusters frozen in early winter ice across surfaces of seven tundra lakes and one boreal forest lake in Alaska. Applying previously measured ebullition rates associated with four distinct classes of bubble clusters found in lake ice, we estimated whole‐lake emissions from individual lakes. The percent surface area of lake ice covered with bubbles (R² = 0.68) and CH₄ ebullition rates from lakes (R² = 0.59) and were correlated with radar return values from RADARSAT‐1 Standard Beam mode 3 for the tundra lakes, suggesting that with appropriate scaling and consideration for variability in lake‐ice conditions, this technique has the potential to be used for estimating broader‐scale regional and pan‐Arctic lake methane emissions.     

退田还湖对鄱阳湖洪水调控能力的影响

利用实测资料统计了鄱阳湖近50年来湖盆形态和洪水水情的变化,表明由于围垦的作用,1954~1992年鄱阳湖面积共减小1 300 km2,容积共减少81×108 m3,调节系数从17.3%下降到13.7%,调洪能力降低20.8%;20世纪90年代与50年代相比,年最高水位平均值抬高1.80 m。计算了退田还湖对近50年来两次特大洪水（1954年洪水和1998年洪水）最高水位的效应值,表明分别可使1954年洪水和1998年洪水的最高水位降低0.72 m和0.68 m。估算了退田还湖对鄱阳湖洪水位频率的影响,表明50年一遇和100年一遇的洪水位分别可降低0.63 m和0.68 m。计算还表明,高水还湖（单退）降低洪水位的作用与圩区还湖前夕的内涝程度密切相关,说明及时排除圩区的内涝对保障退田还湖的防洪减灾作用至关重要。分析了退田还湖面临的主要问题,分别是高水还湖圩区的内涝问题和平垸行洪（双退）圩区的血防问题;探讨解决这两个问题的具体对策,分别为单退圩堤采用“限高加固,排空待蓄”的运作方式,双退圩堤采用“敞开进洪,兼顾血防”的运用方式。     

碧塔海自然保护区景观空间格局研究

在地理信息系统(GIS)与遥感(RS)技术的支持下,选择多种定量指数对滇西北高原典型湿地区———碧塔海自然保护区进行了空间格局分析研究。通过分析,揭示了研究区景观空间格局的结构和特征及受扰程度,为研究区的湿地资源利用与保护提供了科学依据和决策支持。