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791.
采集FACE(Free Air CO2 Enrichment)平台下运行3年的水稻(Oryza sativaL.)/小麦(Triticum aestivumL.)轮作土壤(0~15cm耕作层土壤),利用超声波分散-湿筛分法对烘干土样进行颗粒分级,分析土壤各粒级及其碳、氮的分布特征,研究大气CO2浓度升高对土壤碳周转的影响。结果表明:高浓度大气CO2条件下稻/麦轮作3年后,土壤颗粒组成较对照发生了改变,>53μm粒级的质量分数减小27%(p<0.05),约占土壤总质量20%;53~25μm粒级的质量分数增大35%(p<0.05),约占土壤总质量25%;<25μm无明显变化,约占土壤总质量55%,三种粒级之间质量分数呈显著差异(p<0.05)。FACE条件下,不同粒级土壤颗粒碳质量分数在两个氮水平下平均为:>53μm(30.60g·kg-1),<25μm(13.08g·kg-1),25~53μm(12.85g·kg-1),氮质量分数分别为2.42g·kg-1,1.33g·kg-1,1.12g·kg-1。>53μm粒级的土壤颗粒碳、氮质量分数均极显著高于其它两个粒级(p<0.001)。FACE条件下土壤总碳、氮质量分数高于对照,增幅分别为6.2%和6.7%。从各粒级土壤颗粒碳、氮质量分数变化分析,新增碳、氮主要进入>53μm粒级中,表明该粒级土壤颗粒对土壤碳氮循环(转化和保存)起着重要作用。该研究结果表明高浓度大气CO2条件下,稻/麦轮作农田土壤将成为大气CO2的汇,这将为预测我国未来农田土壤碳的变化趋势提供科学依据。 相似文献
792.
煤中痕量元素与三态硫关系的模型 总被引:12,自引:0,他引:12
将青山烟煤按不同比重分级后,分别测定了各级煤粉中痕量元素Be、Cd、Pb、Co,Cr,Cu,Ni,As以及三态硫的含量,发现痕量元素与三态硫之间有一定的相关关系,本文用回归分析法建立了痕量元素与三态硫关系的模型,并用该模型对青山烟煤某一比重范围内煤粉中的痕量元素含量进行预报,结果令人满意。 相似文献
793.
The impacts of a functional and a demolished copper processing works on the aquatic and terrestrial environment in the vicinity of the works was investigated by determining the levels of selected trace metals in river water, river sediments, channel margin sediments and overbank soils. Samples were taken at five sites within an area of the Churnet Valley in Staffordshire, where the River Churnet flows through the two works. Analysis of river water samples by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) has shown that only copper is present above background levels considered to typify uncontaminated rivers. Analysis of river sediments, channel margin sediments and overbank soils by nitric-perchloric acid digestion and Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) analysis has indicated contamination by arsenic, cadmium and copper in the vicinity of both works. Arsenic and copper are deposited primarily within the aquatic environment, although some contamination of the terrestrial environment by copper is also observed. Cadmium is deposited primarily within the terrestrial environment. The deposition of arsenic and copper in river and channel margin sediments respectively is also related to current and historical contamination. 相似文献
794.
三种空气微生物采样方法的比较 总被引:2,自引:0,他引:2
在室内自然条件下,对三种空气微生物采样方法进行比较。结果表明,ANDERSEN采样器法,LWC-1笄样器法和平皿沉降法测定的室内空气微生物粒子浓度分别为2634个/m^%3,2395个/m^3和1380个/m^3,LWC-1型和ANDERSEN二种采样器的采样结果之间没有明显差异,二种采样器的采样结果均明显高于平皿沉降法的采样结果。ANDERSEN采样器的采样效率高,且可同时测定空气微生物粒子的浓 相似文献
795.
Spread of metals through an invertebrate food chain as influenced by a plant that hyperaccumulates nickel 总被引:6,自引:0,他引:6
Lynsey R. Peterson Victoria Trivett Alan J.M. Baker Carlos Aguiar A. Joseph Pollard 《Chemoecology》2003,13(2):103-108
Summary. Hyperaccumulation of metals in the shoot system of
plants is uncommon, yet taxonomically and geographically widespread. It
may have a variety of functions, including defense against herbivores.
This study investigated the effects of hyperaccumulation on metal
concentrations across trophic levels. We collected plant material, soil,
and invertebrates from Portuguese serpentine outcrops whose vegetation
is dominated by the nickel hyperaccumulator Alyssum pintodasilvae.
Samples were analyzed for nickel, chromium, and cobalt. Grasshoppers,
spiders, and other invertebrates collected from sites where A.
pintodasilvae was common had significantly elevated concentrations of
nickel, compared to nearby sites where this hyperaccumulator was not
found. Chromium and cobalt, occurring in high concentrations in the
serpentine soil but not accumulated by A. pintodasilvae, were not
elevated in the invertebrates. Therefore, it appears likely that a flux
of nickel to herbivore and carnivore trophic levels is specifically
facilitated by the presence of plants that hyperaccumulate this metal.
The results may be relevant to the development of phytoremediation and
phytomining technologies, which use plants to extract metals from the
soil.
Reveived 22 August 2002; accepted 2 April 2003.
R1D="
Correspondence to: A. J. Pollard, e-mail:joe.pollard@furman.edu 相似文献
796.
光子相关光谱(PCS)在无机高分子絮凝剂形态表征中的应用 总被引:6,自引:1,他引:6
本文运用现代先进的微粒检测手段光子相关光谱对常见的两类无机高分子絮凝剂的形态进行了表征。实验结果表明:在所测聚合氯化铁溶液中,体系呈较为单一的集中分布,由平移扩散系数计算得到平均有效直径在5-11nm左右。在所测聚合氯化铝溶液中,主要为双峰分布,熟化后样品约为2-5nm的小颗粒与数十nm以上分布较宽的聚集体,另外,本文对光子相关光谱在形态表征中的优缺点及其它应用的可能性也作了一定的论述。 相似文献
797.
The relationship between epilithic periphyton (biofilm) bound metals and metals bound to sediments in freshwater systems 总被引:1,自引:0,他引:1
Surficial sediments and epilithic periphyton (biofilm) were sampled from six sites on the River Churnet and five sites on the River Manifold in Staffordshire and analysed for cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn). The sites demonstrated a wide range of sediment trace metal concentrations determined by inductively coupled plasma optical emission spectrometry (ICP-OES) and atomic absorbtion spectroscopy (AAS). Biofilm was removed from the substrate using physical abrasion and 0.005 M ethylenediaminoethanetetra-acetic acid (EDTA) extractant. The European Standards, Measurements and Testing Programmes (BCR) operationally defined geochemical speciation scheme was used to determine the exchangeable, acid soluble fraction of the sediments. Significant positive correlations were determined between the EDTA extractable biofilm and the exchangeable sediment fraction for Cd, Cu and Zn but not for Pb. Natural epilithic periphyton may be a potential metal biomonitor particularly of Cu, Cd and Zn in aquatic systems and provide supporting information in relation to potential sediment toxicity. 相似文献
798.
799.
Evaluation of PCDD/F congener distributions in MWI flue gas treated with SCR catalysts 总被引:1,自引:0,他引:1
Partitioning of PCDD/F congeners between gaseous and particulate phases and removal efficiencies of the air pollution control devices (APCDs) for PCDD/Fs at an existing municipal waste incinerator (MWI) in Taiwan are evaluated via stack sampling and analysis. The MWI investigated is equipped with electrostatic precipitators (EP), wet scrubbers (WS) and selective catalytic reduction system (SCR) as APCDs. The average PCDD/F concentration of stack gas is 1.49 ng/N m3, and the International Toxic Equivalent Quantity (I-TEQ) is 0.043 ng-I-TEQ/N m3. The EP increases PCDD/F concentration by 174.0% while the average removal efficiency of WS + SCR system for PCDD/Fs reaches 99.1%. In addition, the PCDF removal efficiency achieved with WS + SCR system (97.1–99.8%) is higher than that for PCDDs (96.5–99.3%). The results obtained on gas/particulate partitioning in flue gas indicate that the particulate-phase PCDD/Fs accounted for 65% at the inlet of EP, 20% at the outlet of EP and 50% at the stack, respectively, of the total PCDD/F concentrations. This study also indicates that as the chlorination level of PCDD/F congeners increases, the percentage of PCDD/Fs existing in gas phase decreases in all flue gas samples. 相似文献
800.