全文获取类型
收费全文 | 2358篇 |
免费 | 302篇 |
国内免费 | 1327篇 |
专业分类
安全科学 | 82篇 |
废物处理 | 76篇 |
环保管理 | 283篇 |
综合类 | 2304篇 |
基础理论 | 425篇 |
环境理论 | 3篇 |
污染及防治 | 390篇 |
评价与监测 | 224篇 |
社会与环境 | 200篇 |
出版年
2024年 | 18篇 |
2023年 | 106篇 |
2022年 | 156篇 |
2021年 | 195篇 |
2020年 | 180篇 |
2019年 | 167篇 |
2018年 | 156篇 |
2017年 | 178篇 |
2016年 | 216篇 |
2015年 | 238篇 |
2014年 | 195篇 |
2013年 | 274篇 |
2012年 | 212篇 |
2011年 | 270篇 |
2010年 | 172篇 |
2009年 | 161篇 |
2008年 | 156篇 |
2007年 | 127篇 |
2006年 | 149篇 |
2005年 | 94篇 |
2004年 | 77篇 |
2003年 | 99篇 |
2002年 | 63篇 |
2001年 | 64篇 |
2000年 | 57篇 |
1999年 | 38篇 |
1998年 | 30篇 |
1997年 | 32篇 |
1996年 | 31篇 |
1995年 | 28篇 |
1994年 | 12篇 |
1993年 | 8篇 |
1992年 | 2篇 |
1991年 | 13篇 |
1990年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1981年 | 2篇 |
1977年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有3987条查询结果,搜索用时 31 毫秒
951.
Smodis B 《Journal of environmental management》2007,85(1):121-128
In the framework of the IAEA programmes, Member States involved in air pollution studies using nuclear analytical techniques have harmonized their methodologies. Participants characterising chemical composition of size fractionated airborne particulate matter based their methodology on a common type of air sampler, centralised data collection and evaluation, and the same kind of data processing. Institutions involved in biomonitoring air pollution identified appropriate organisms to be applied at a regional scale, and harmonized procedures for sample preparation and analysis, as well as data processing and presentation. Both metrology approaches have been validated and disseminated in many Member States. 相似文献
952.
研究多点电喷汽油机燃用不同掺混比的乙醇/汽油混合燃料时的排放及催化器的转化性能.结果表明,在汽油机参数未做任何调整的情况下,与汽油机相比,乙醇/汽油混合燃料汽油机催化器之前的CO排放降低,降幅接近15%;HC排放在大负荷时略有升高;NOx排放基本相同;乙醇对排放物催化转换效率的影响与电喷汽油机的转速、负荷和空燃比控制策略有关.用气相色谱分析仪测录的未燃乙醇排放在大负荷时略有升高,甲醇排放量变化不大,乙醛排放量随乙醇含量增大而增大,经三效催化转化器后,可以被控制在接近零排放的水平.在怠速工况,随乙醇含量增加,CO、HC和NOx的排放与汽油机相比略有降低. 相似文献
953.
从分子质量的变化分析有机物对GAC吸附内分泌干扰物(BPA)的影响 总被引:3,自引:1,他引:2
从分子质量分布的角度研究了水中有机物对颗粒活性炭(GAC)吸附双酚A(BPA)容量及吸附速率的影响.结果表明,相对于以去离子水为本底的BPA溶液来说,GAC吸附以滤后水、臭氧后出水和原水为本底的BPA溶液的Langmuir模型的最大吸附容量qm值分别下降了29.95%、43.56%和44.44%,而其拟二级动力学模型的k2值分别下降了43.05%、49.75%和56.38%.相对分子质量3 000以上,尤其是10 000以上的有机物堵塞GAC的二级微孔;3 000以下,尤其是1 000以下的有机物与BPA分子之间存在直接的竞争吸附,是导致GAC对BPA的吸附容量以及吸附速率下降的主要原因. 相似文献
954.
The determination of nitrogen (N) based loading rates for land application of biosolids is challenging and site specific. Over loading may contribute to environmental, agricultural, or human health problems. The objective of this study was to monitor N mineralization and losses in a moderately alkaline and calcareous desert soil amended with either anaerobically digested (AN) or lime-stabilized (LS) biosolids, and irrigated with and without urea enriched water. For Experiment 1, N inputs, leaching and residuals in soil were evaluated in an open soil column system. For Experiment 2, ammonia (NH3) emissions were evaluated in a closed soil column system. In Experiment 1, AN and LS biosolids increased soil ON (organic N) by three and two fold, respectively. Respective net N mineralization of ON from biosolids alone was 90% and 62% without urea, and 71% and 77%, respectively with added urea. Nitrogen leaching losses and residuals in amended soil did not account for all N inputs into the soil/biosolids system. In Experiment 2, NH3 emissions were not significantly different among treated soils with or without added urea, except LS amended soil receiving urea. Ammonia losses did not account for unaccounted N in Experiment 1. We concluded that deep placement and rapid mineralization of AN biosolids promoted anaerobic soil conditions and denitrification, in addition to the high denitrification potential of desert soil. LS biosolids showed greater potential than AN biosolids for safe and beneficial land application to desert soils regardless of biosolids placement and the inclusion of N rich irrigation water. 相似文献
955.
The objective of this study was to quantify sorption properties for kerogen/black carbon (BC)-bearing sediments. Single-solute sorption isotherms were measured for five pristine marine sediments using phenanthrene, naphthalene, 1,3,5-trichlorobenzene, and 1,4-dichlorobenzene as the sorbates. The results showed that the sorption isotherms were nonlinear and that the organic carbon normalized single point KOC values were comparable to those reported in the literature for the purified keorgen and BC, but are much higher than the data reported for HA and kerogen/BC-containing terrestrial soils and sediments. It is likely that koergen and BC associated with these pristine marine sediments may not be encapsulated with humic acids or Fe and Mn oxides and hydroxides as often do in terrestrial soils and sediments. As a result, they may be fully accessible to sorbing molecules, exhibiting higher sorption capacities. The study suggests that competition from background HOCs and reduced accessibility when kerogen and BC are associated with terrestrial sediments may dramatically increase variability of sorption reactivities of geosorbents. Such variability may lead to large uncertainties in the prediction of sorption from the contents of kerogen and/or BC along with TOC. 相似文献
956.
The role of phenolic groups in the interaction of natural organic matter (NOM) with metal hydroxides was investigated with ATR-FTIR spectroscopy and adsorption tests by employing a series of dihydroxybenzoic acids (DHBAs) as the NOM surrogates and aluminum hydroxide as the adsorbent. All DHBAs examined in this study were found to be adsorbed on aluminum hydroxide by forming inner-sphere complexes. Carboxylic groups governed the complexation of DHBAs with aluminum hydroxide at low pH or in cases when the two hydroxyl groups were not adjacent to each other and neither of them was ortho to the carboxylic group. The involvement of the phenolic groups, ortho to another phenolic group or ortho to the carboxylic groups, in the complexation increased with increasing pH as the deprotonation of phenolic groups was easier at higher pH. The presence of phenolic groups increased the electron density of the carboxylic groups and facilitated the inner-sphere complexation of the carboxylic groups with metal hydroxide. The correlation between the pKa values and the amount of organic acid adsorbed on the aluminum hydroxide revealed that the adsorption of DHBAs at acidic pH was largely dependent on the surface chelate formation rather than on the electronic effect. 相似文献
957.
958.
Using estimates of land suitable for restoration in woodlands, grasslands, and deserts, as well as estimates of the rate at
which restoration can proceed, we estimate that carbon storage in these biomes can range up to 0.8 billion tons of carbon
per year (Gt C/yr), for a combination of land management strategies. This corresponds to a reduction in atmospheric buildup
of 0.5 Gt C/yr, which represents up to 15% of the average annual atmospheric carbon buildup in the next century, 3.5 Gt C/yr,
assuming the IPCC 92d scenario. A global strategy for reducing atmospheric carbon dioxide concentration will require the implementation
of multiple options. The advantage of carbon storage in restored drylands is that it comes as a side benefit to programs that
are also justifiable in terms of land management. 相似文献
959.
Mehrez Samaali Michael D. Moran Vronique S. Bouchet Radenko Pavlovic Sophie Cousineau Mourad Sassi 《Atmospheric environment (Oxford, England : 1994)》2009,43(32):4873-4885
The influence of chemical initial conditions and chemical lateral boundary conditions (CLBCs) on long-term regional air quality model simulations was investigated using outputs from an annual simulation of the year 2002 on a North American domain. This simulation was carried out using the AURAMS regional air quality model. It was subdivided into three multi-month segments with two overlap periods (May 15–30 and September 1–30) to allow the segments to be run in parallel. For this approach to work, model predictions had to match very closely by the end of the two-week and four-week overlap periods. The time required for the values of daily domain-average surface PM2.5 concentration to match for the two simulation segments associated with each of the two overlap periods was four and six days, respectively. For individual locations within the model domain, however, the required spin-up period was as much as nine days, considerably longer than the 2–4-day spin-up period usually assumed in the literature. For ozone, on the other hand, the daily domain-average surface ozone concentration values did not converge for either overlap period. A zero-gradient CLBC had been used for all run segments and species. When a time-invariant CLBC for ozone was used instead, the daily domain-average surface ozone concentration values behaved more realistically and did converge after fewer than three days. A similar improvement was also obtained for individual locations, but with spin-up periods of up to nine days. Model chemical spin-up time thus seems to be dependent on the species considered, the time required for the influence of the inflow boundaries to reach all locations within the domain, and the impact of local emissions sources. These results suggest the use of a spin-up period of longer than one week for a large (continental) domain and long-term simulation of PM2.5 and O3 rather than the 2–4 days commonly assumed in the literature. 相似文献
960.
Wun-Cheng Wang 《Journal of the American Water Resources Association》1974,10(4):662-671
ABSTRACT: The adsorption of phosphate on particulate matter from the Illinois and Spoon Rivers was investigated. Adsoprtion reached equilibrium after 5 to 6 days and adsorption isotherms were linear for both constant and varying amounts of particulate matter. Adsorption was maximum at pH 8.3 – 8.4 and minimum at 6.0. Rates of adsorption were influenced by the equilibrium concentration of phosphate-P and were essentially the same for the Illinois and Spoon Rivers. However, the quantity of phosphate-P adsorbed per unit weight of particulate matter differed for the two streams with that in the Illinois River exhibiting an adsorption capacity 7 times that of the Spoon River. 相似文献