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31.
珠江三角洲地区大气中有机氯农药的被动采样观测 总被引:8,自引:0,他引:8
利用PUF被动采样装置,对珠江三角洲地区大气中有机氯农药(OCPs)进行监测.结果显示,广东省大气中有机氯农药主要是滴滴涕(DDTs)、六六六(HCH)及氯丹(Chlordane),其中DDTs约占总OCPs的54.5%;香港大气中农药残留主要是氯丹和DDTs,氯丹约占总含量的51.3%.珠三角地区大气中有机氯农药空间分布差异明显(580-5500pg·m-3),香港平均浓度远远低于广东省.另外,广东省仍有工业DDT在使用,造成广东省大气中有"新"的工业DDT输入;而三氯杀螨醇是香港大气中DDT高含量的重要来源;广东省和香港HCH主要源于林丹使用的残留,香港的Eastern及Tsuen Wan源于工业六六六使用的残留;珠江三角洲所有采样点的HCB含量较低,大气中HCB少量残留可能是HCB作为药物中间体的化学合成及HCB在大气中长距离传输的结果. 相似文献
32.
Ewelina Wawryk-Gawda Michał K. Zarobkiewicz Katarzyna Chłapek Patrycja Chylińska-Wrzos Barbara Jodłowska-Jędrych 《毒物与环境化学》2019,101(7-8):404-419
AbstractThe use of electronic cigarettes increases as a supposedly healthier form of nicotine consumption, but safety of vaping remains uncertain. In this study, we assessed whether the use of electronic cigarettes increases the risk of infertility in male rats. Malformations of sperm morphology were more frequent in nicotine-exposed groups than in the control group. Vacuolization of seminiferous epithelium, reduction of spermatogenesis, increased apoptosis of spermatogonia and spermatocytes, and acceleration of degeneration of testes were observed. The male reproductive organs are slightly less affected by vaping than by smoking. Nevertheless, in consequence both may lead to the reduction of fertility. 相似文献
33.
Efficacy of extracting indices from large‐scale acoustic recordings to monitor biodiversity 下载免费PDF全文
Rachel T. Buxton Mary Clapp Erik Meyer Erik Stabenau Lisa M Angeloni Kevin Crooks George Wittemyer 《Conservation biology》2018,32(5):1174-1184
Passive acoustic monitoring could be a powerful way to assess biodiversity across large spatial and temporal scales. However, extracting meaningful information from recordings can be prohibitively time consuming. Acoustic indices (i.e., a mathematical summary of acoustic energy) offer a relatively rapid method for processing acoustic data and are increasingly used to characterize biological communities. We examined the relationship between acoustic indices and the diversity and abundance of biological sounds in recordings. We reviewed the acoustic‐index literature and found that over 60 indices have been applied to a range of objectives with varying success. We used 36 of the most indicative indices to develop a predictive model of the diversity of animal sounds in recordings. Acoustic data were collected at 43 sites in temperate terrestrial and tropical marine habitats across the continental United States. For terrestrial recordings, random‐forest models with a suite of acoustic indices as covariates predicted Shannon diversity, richness, and total number of biological sounds with high accuracy (R2 ≥ 0.94, mean squared error [MSE] ≤170.2). Among the indices assessed, roughness, acoustic activity, and acoustic richness contributed most to the predictive ability of models. Performance of index models was negatively affected by insect, weather, and anthropogenic sounds. For marine recordings, random‐forest models poorly predicted Shannon diversity, richness, and total number of biological sounds (R2 ≤ 0.40, MSE ≥ 195). Our results suggest that using a combination of relevant acoustic indices in a flexible model can accurately predict the diversity of biological sounds in temperate terrestrial acoustic recordings. Thus, acoustic approaches could be an important contribution to biodiversity monitoring in some habitats. 相似文献
34.
为了研究硬煤破坏过程中的动态力学特性,采用Φ50 mm变截面分离式霍普金森压杆(SHPB)试验系统,对45#钢制薄壁套筒施加环向约束的硬煤试件进行不同加载速率的冲击压缩试验,得到被动围压下轴向应力-应变曲线、径向应力-应变曲线及最大被动围压和冲击速度的关系。研究结果表明:峰值应力、峰值应变随着冲击速度的增大而增大,最大被动围压值与冲击速度呈幂次增长的关系;被动围压下的硬煤试件变形受到限制,试件延性、抗压能力显著提高;随着冲击速度的增大,薄壁套筒对试件的约束也逐渐增大,达到峰值后,冲击速度对被动围压的影响减小,筒壁厚度影响着被动围压效果。 相似文献
35.
36.
利用被动扩散法测定空气中的二氧化氮是最近几年许多发达国家所采用的方法。在二氧化氮(以后以NO2记)被动监测分析方法及Saltzman法的基础上,对所选用的化学试剂及试剂的用量、操作方法等方面进行了改进与研究,实验结果表明用对氨基苯磺酸取代对氨基苯磺酰胺,更具有可操作性、经济性和适用性。 相似文献
37.
目的 为星载无源微波器件能够在地面通过加速寿命试验验证其在轨可靠性和寿命提供理论依据和试验方法.方法 设计一种温度和功率同时作用下的双应力加速寿命数学模型,通过分析加速应力与寿命的对应关系,设计科学合理的加速寿命试验方案,通过分析加速寿命试验下器件指标的变化,给出器件可靠性和寿命评估结果.结果 以某隔离器这一典型无源微波器件为例,在选取激活能0.8 eV下,利用温度-功率双应力加速寿命数学模型,计算得隔离器要满足10 a的在轨寿命和可靠性,加速寿命试验时间需不低于1230 h.通过1300 h以上的加速寿命试验,对比试验前后隔离器指标,隔离器的正向损耗恶化了0.07 dB,说明加速寿命试验对产品电性能老化有一定影响,但指标变化均在技术要求范围内,产品能够满足可靠性和寿命要求.结论 设计的温度-功率双应力加速寿命数学模型和加速寿命试验方案,能够为星载无源微波器件高可靠长寿命验证提供参考和借鉴. 相似文献
38.
Paul J. Weldon 《Chemoecology》2004,14(1):1-4
Summary. Many animals acquire substances on their integument from heterospecifics
through anointing. In active or self-anointing, animals rub against scent
sources or they apply them by appendage or mouth. In passive anointing, animals
adsorb emitted chemicals. Most investigators suggest that chemicals appropriated
via anointing deter predators, ectoparasites, and/or microbial pathogens. Similarly,
nesting birds and brood parasites of social insects acquire chemicals from and reside
unmolested near or within insect colonies. The acquisition through anointing of
chemicals that deter predators, ectoparasites, microbial pathogens, and other
offenders, i.e. defensive anointing, constitutes an extended phenotype: the
genetic machinery by which defensive compounds are synthesized does not reside with
the anointing organisms, but the sensory mechanisms and/or behavioral tendencies by
which chemicals are appropriated from heterospecifics do. The ecological
relationships between anointing organisms and chemical donors, and between
chemical donors and those responding to chemicals appropriated via anointing, may
be unorthodox. Interactions between anointing organisms and chemical donors typically
entail abrasive contact with or other damage to the latter. These encounters sometimes
are evidenced by telltale marks on chemical donors or by chemicals deposited on the
integument of anointing organisms. The organisms furnishing chemicals and those
affected by them may not interact, and they may even occupy different habitats, because
mobile anointing organisms are the medium by which chemicals are disseminated. Thus,
in allelochemical studies where anointing is involved, species can be tested, with
ecological legitimacy, using chemicals from organisms they might fail to interact with
in nature. Practical implications of anointing stem from its potential importance in
conservation and captive management, where consideration is given to the protection
that animals derive by accessing topically acquired chemicals from heterospecifics. 相似文献
39.
将三油酸甘油酯-醋酸纤维素复合膜(TECAM)用作被动采样器,开展水体中一甲基锡(MMT)、二甲基锡(DMT)、一丁基锡(MBT)、二丁基锡(DBT)、三丁基锡(TBT)、二苯基锡(DPhT)和三苯基锡(TPhT)等7种有机锡氯化物的富集实验,膜样品经甲醇/醋酸溶液提取、乙基化衍生和正己烷萃取等前处理后,用气相色谱-质谱法(GC-MS)进行定性和定量检测,得到水体中痕量有机锡污染的相关指纹信息。结果表明,7种目标化合物均可在TECAM膜上富集,48 h后均可达到平衡状态;有机锡富集能力差异较大,其TECAM膜/水分配系数(log KTECAM)与其辛醇-水分配系数(log Kow)呈现显著正相关性(r=0.97, n=7)。甲基锡富集能力较低,但可定性筛查;而苯基锡和丁基锡等5种目标化合物在TECAM膜上的被动采样速率在0.06~0.16 L·g~(-1)·d~(-1)范围变化,经反演所得其在水体中的时间加权平均浓度与传统的主动采样法所得浓度没有显著差异(P0.05)。因此,基于TECAM被动采样技术可以实现水体中极性范围较广的痕量有机锡污染筛查取证。 相似文献
40.
A traditional method of summarizing spatial distribution of species is the observed species-area curve. Often the observed species-area curve is surprisingly close to the expected species-area curve under the hypothesis of random placement of individuals. This has been used as evidence supporting the hypothesis. In this paper, we argue that using the observed species-area curve to test the general random placement hypothesis is highly inefficient. We present a testing method based on the classical 2 test for over-dispersion which is not only more efficient but also applicable to situations where complete abundance information are unavailable. We also discuss three alternatives of the hypothesis. The focus of this paper is on these and other general issues relevant to communities of different types. No applications are included in this paper. 相似文献