ABR反应器的碱度变化及调控研究

研究了折流厌氧反应器(ABR)运行中碱度的变化情况及其与ABR各格室中VFA、pH和COD变化之间的关系.结果表明,碱度沿程变化与反应器的VFA浓度变化密切相关,碱度和pH值的最低点出现在VFA浓度最高点.碱度条件是通过pH值影响系统的运行.ABR沿程碱度和pH值变化都存在一个先降低后上升的过程.碱度控制一般以保证ABR沿程最低pH值不低于6.0为准,6.5以上为佳.进水碱度的下限与反应器的进水浓度密切相关.在低负荷COD条件下[3.7 kg/(m³·d)],保持ABR运行良好的最低碱度为800 mg/L.     

生活垃圾焚烧飞灰在饰面砖中资源化应用技术

分析了飞灰的性质,利用飞灰、红泥及缸砂研制饰面砖,研究了飞灰对饰面砖性能及微观结构的影响,并对其安全性进行了评价。结果表明:飞灰主要化学成分是CaO、SiO2、Al2O3,构成SiO2-Al22O3-金属氧化物体系,可用作饰面砖的原材料;当飞灰掺加量为20%时,饰面砖表现出良好的性能:抗压强度19·2MPa,吸水率7·2%,表观质量达到一等品要求;与飞灰相比,饰面砖中重金属浸出能力大大降低:As、Pb、Ni、Cr、Cu、Hg、Cd水平振荡浸出毒性未检测出,Zn的水平振荡浸出值下降到飞灰中的0·014倍,Hg、Cd有效浸出毒性未检测出,As、Pb、Ni、Cr、Cu、Zn的有效浸出毒性分别下降到飞灰中的0·056、0·001、0·067、0·058、0·056、0·029倍。     

新型汽车空调制冷剂CMR-O2与R12、R134a性能比较

介绍一种新型制冷剂CMR-02。为分析其应用于汽车空调的可行性,比较了CMR-02与R134a和R12三种制冷剂在热工性能、环境性能、安全性与共沸性等方面的优劣,并比较了CMR-02和R134a的压缩机性能,发现CMR-02的单位质量制冷量增加显著(68.10%),单位容积制冷量增加14.38%,符合环保要求,且成本低廉,可以作为R12的一种较好的过渡性替代物。     

电磁兼容测量结果可追溯性技术探讨

无线电波因其具有较强的方向性和反射性等传播特点,往往会引起电磁兼容测量结果的不稳定甚至有较大的偏差,如果不对测量过程中的测量和试验布置、试品的工况、记录报告等要素进行可追溯性分析和控制,势必会造成测量结果的随意和不确定性.因此在电磁兼容测量实验室,非常有必要对测量过程和测量结果进行可追溯性研究、分析和控制,一是提供准确可再现的测量数据,对客户负责,二是通过可追溯性控制,再现试验和测量过程,验证测量结果,对实验室的风险进行预见和预防.本文主要立求通过实际案例的分析,畅述和分析在电磁兼容测量实验室如何建立可追溯性的控制体系.     

固相萃取-UPLC-MS/MS法测定环境水体中多种抗生素

采用固相萃取-超高效液相色谱串联质谱法测定环境水样中25种磺胺类和喹诺酮类抗生素,通过优化试验条件,使方法在2.00μg/L～200μg/L范围内线性良好,方法检出限为1.01ng/L～2.85ng/L,7次测定结果的RSD为2.3%～8.0%。将该方法用于自来水和地表水测定,结果均为未检出,高、低质量浓度水平的加标回收率为61.2%～102%。     

HPLC-三重四级杆质谱法测定医疗废水中抗生素残留

采用固相萃取/高效液相色谱-三重四级杆质谱法同时测定医疗废水中的20种超痕量抗生素残留,通过优化试验条件,使方法在100μg/L～100μg/L范围内线性良好,方法检出限为024ng/L～122ng/L。空白水样和实际水样3个质量浓度水平的加标回收率分别为80.2%～108%和75.8%～114%,6次测定结果的RSD分别为2.4%～8.4%和1.7%～8.1%。将该方法用于测定重庆市2家三甲医院医疗废水中的超痕量抗生素残留,结果有11种抗生素检出,其余均为未检出。     

Sludge concentration dynamic distribution and its impact on the performance of UNITANK

UNITANK is a biological wastewater treatment process that combines the advantages of traditional activated sludge process and sequencing batch reactor, which is divided into Tank A, B and C. In this study, the sludge distribution and its impact on performance of UNITANK were carried out in Liede Wastewater Plant （WWTP） of Guangzhou, China. Results showed that there was a strong affiliation between Tank A and B of the system in sludge concentration distribution. The initial sludge concentration in Tank A could present the sludge distribution of the whole system. The sludge distribution was mainly influenced by hydraulic condition. Unsteady sludge distribution had an impact on variations of substrates in reactors, especially in decisive reactor, and this could lead to failure of system. Settler could partially remove substrates such as COD and NO3-N, but there was adventure of sludge deterioration. The rational initial sludge concentration in Tank A should be 4000-6000 mg/L MLSS.     

Transformations of particles, metal elements and natural organic matter in different water treatment processes

Characterizing natural organic matter （NOM）, particles and elements in different water treatment processes can give a useful information to optimize water treatment operations. In this article, transformations of particles, metal elements and NOM in a pilot-scale water treatment plant were investigated by laser light granularity system, particle counter, glass-fiber membrane filtration, inductively coupled plasma-optical emission spectroscopy, ultra filtration and resin absorbents fractionation. The results showed that particles, NOM and trihalomethane formation precursors were removed synergistically by sequential treatment of different processes. Preozonation markedly changed the polarity and molecular weight of NOM, and it could be conducive to the following coagulation process through destabilizing particles and colloids; mid-ozonation enhanced the subsequent granular activated carbon （GAC） filtration process by decreasing molecular weight of organic matters. Coagulation-flotation and GAC were more efficient in removing fixed suspended solids and larger particles; while sand-filtration was more efficient in removing volatile suspended solids and smaller particles. Flotation performed better than sedimentation in terms of particle and NOM removal. The type of coagulant could greatly affect the performance of coagulation-flotation. Pre-hydrolyzed composite coagulant （HPAC） was superior to FeCl3 concerning the removals of hydrophobic dissolved organic carbon and volatile suspended solids. The leakages of flocs from sand-filtration and microorganisms from GAC should be mitigated to ensure the reliability of the whole treatment system.     

Non-UV based germicidal activity of metal-doped TiO2 coating on solid surfaces

A stain-based screening method was developed to screen different catalyst coatings for their germicidal activity. A Baclight dead/live bacteria viability kit （invitrogen, molecular probes） was used for staining the cell. The screening was carried out following a standard procedure. This included loading cell suspension to solid surface and maintaining contact for 30 min, then staining with a mixture containing dyes. The stained cells were observed using an epifluorescent microscope and photographed with a CCD camera under UV. Metal-doped TiO2 coatings on AI plates were prepared and tested for non-UV germicidal activity without using UV. It was tested using model microorganisms such as Bakers Yeast （Saccharomyces cerevisiae）, Bacillus subtilis, Pseudomonas putida, and Escherichia coli. On the basis of the germicidal activity of catalyst and the degree of damage caused to the cells, the stained cells may appear green （viable）, green with red or yellow nuclei and yellow （compromised） or red （nonviable）. According to their stained color, cells were counted to calculate the percentage of dead, live, and compromised cells. Compromised cells are cells that grow very slowly after reculturing indicating a degree of reversible cell damage. Screening the germicidal activity using this staining method is accurate and efficient, and requires less time than the culture-based method. A modification to the procedure for measuring germicidal activity of rough surfaces or fibrous coatings was developed. Both TiO2 and metal-doped TiO2 （Ag, Pt, Au, Cu） possess non-UV based germicidal activity. The germicidal activity of TiO2 was found to be related with its wetting property and can be improved by UV irradiation before testing. It is not greatly affected by contact time, indicating a fast acting germicidal activity.     

Improvement of the antifouling characteristics in a bioreactor of polypropylene microporous membrane by the adsorption of Tween 20

Surface modification by physical adsorption of Tween 20 was accomplished on polypropylene microporous membranes (PPMMs). Attenuated total reflection-Fourier transform infrared spectroscopy (ATR/FT-IR) and scanning electron microscope (SEM) were used to characterize the chemical and morphological changes on the membrane surfaces. Water contact angles and relative pure water fluxes were measured. The data showed that the hydrophilic performance for the modified membranes increased with the increase in the adsorption amount of Tween 20 onto the surface or into the pores of polypropylene microporous membranes. To test the antifouling property of the membranes by the adsorption of Tween 20 in a membrane bioreactor (MBR), filtration for active sludge was performed using synthetic wastewater. With the help of the data of water fluxes and the FE-SEM photos of the modified PPMMs before or after operating in a MBR for about 12 d, the PPMMs with monolayer adsorption of Tween 20 showed higher remained flux and stronger antifouling ability than unmodified membrane and other modification membranes studied.