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11.
研究了以固定相TiO2为催化剂光催化降解垃圾渗滤液中有机污染物的可行性。试验了制备TiO2膜的适宜条件以及光照时间等各种因素对COD的去除率和UV335脱色率的影响。研究表明,COD为418mg/L的垃圾渗滤液经400W高压汞灯光照30min,COD的去除率和UV335脱色率分别为44.3%和75.0%。光照时间60min时,COD的去除率和UV335脱色率可提高至54%和90%。光照30min后与活性炭柱联用,COD的去除率和UV335脱色率分别提高到68.3%和84.6%。 相似文献
12.
The effects of different aluminium chloride concentrations together with varying calciumchloride concentrations on root growth, cell division and nucleoli in root tip cells of Allium cepa werestudied. The concentrations used for aluminium chloride were 10-4, 10-3 and 10-2 mol/L ; and for calcium chloride were 10-5 , 10-4 , 10-3 and 10-2 mol/L, respectively. The results showed that after thetreatments with 10-2 to 10-3 mol/L Al3+ , root growth was severely inhibited , a large nurnber of thecells with c-mitosis were induced and the nucleolar material was extruded from the nucleus into the cytoplasm. However , the treatments with 10-2 to 10-3 mol/L of Al3+ together with 10-2)to 10-5 mol/LCa2+ suggested that Ca2+ gave the obviously protective effects against Al3+ poisoning in root growth.cell division and nucleoli of the root tip cells in A. cepa. The possible mechanism of these protective effects of Ca2+) is also briefly discussed. 相似文献
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TiO2膜固载型多孔催化剂的光催化分解试验 总被引:3,自引:0,他引:3
以多孔基质为载体,用溶胶-凝胶法制备出载TiO2薄膜的多孔型光催化剂。用X射线衍射和扫描电镜对催化剂的物相和形貌进行了表征,此催化剂能在光照下分解水溶液中四环素抗菌素。经1h光照,四环素的分解率可达85%左右。 相似文献
15.
采用改进的Sol-gel方法,制备了一种新型的单分散椭球形微孔结构的纳米GeO2/TiO2复合光催化剂,并用TG-DTA、XRD、XPS、UV-vis、FT-IR、TEM、BET等手段进行了表征.以难生化降解的染料罗丹明B为目标降解物,采用HPLC测定不同光照时间下催化剂对染料降解的情况,考察了催化剂的光催化活性结果表明,改进的Sol-gel法制得的复合光催化剂具有明显的孔结构,而且比表面积大、粒径小、粒径分布窄、分散性好;与适量GeO2复合后能够有效提高TiO2纳米粒子的光催化活性;复合光催化剂的最佳制备条件为GeO2摩尔含量为0.1%,煅烧温度为400℃,所制得的GeO2/TiO2光催化活性比纯TiO2有显著提高. 相似文献
16.
Liu Zhengchao Pan Xunxi Dong Wenbo Hou Huiqi Zhang Zhenman Hou Jian Yu Yong Li Changlin 《环境科学学报(英文版)》1997,9(1):95-99
In this paper pulsed corona discharge is shown to be effective for the decomposition of CF3Cl(Freon-13).The pressure of CF3Cl was 2.67×103Pa,after discharged for 2 min,39.5% of CF3Cl was decomposed.The products were mainly CF4,Cl2 and CF2Cl2.The yield increased by adding O2 or air.Under the same conditions,more than 94% decomposition yield was obtained if 5.32×103Pa O2 or air was added.The composition of products became CF2O,Cl2 and CF4.While the partial pressure of O2 or air reached 1 arm,the decomposition yield decreased to 54.5% and 48. 5% respectively. 相似文献
17.
The preparation of immobilizing-catalysts for decomposing ozone by using dipping method was studied. XRD, XPS and TEM were used to characterize the catalysts. The three kinds of catalysts were selected preferentially, and their catalytic activities were investigated. The results showed that the catalyst with activated carbon dipping acetate( active components are Mn:Cu = 3:2, active component proportion in catalyst is 15%, calcination temperature is 200℃ ) has the best catalytic activity for ozone decomposing. One gram of catalyst can decompose 17.6g ozone at initial ozone concentration of 2.5g/m^3 and the residence time in reactor of 0.1s. The experimental results also indicated that humidity of reaction system had negative effect on catalytic activity. 相似文献
18.
《环境科学学报(英文版)》2023,35(3):340-348
In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu2O heterojunctioned catalyst is fabricated by heating Cu2O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu2O is heated at 180°C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm3/(g·hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu2O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future. 相似文献
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贫燃条件下汽车尾气中NOx催化净化研究进展 总被引:2,自引:0,他引:2
汽车尾气排放的NOx(主要是NO)是城市大气的主要污染源之一。本综述了近l0年来贫燃条件下NOx催化转化为N2的催化剂研究进展。这些方法包括HC-SCR、NO直接催化分解、NOx吸附-还原等。讨论了不同催化剂的性能影响因素。新的负载材料MFI、MCM-41、SAPO-34的应用增强了催化剂的性能。双功能催化剂由于两种活性位的协同作用表现出较高的活性和选择性。新的纳米结构概念催化剂NOx吸附还原中发现有广泛应用。介绍了上述催化脱除NOx的各种机理并指出了今后研究的方向。 相似文献