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191.
Milko Novi? Irena Grgi? Mateja Poje Vida Hudnik 《Atmospheric environment (Oxford, England : 1994)》1996,30(24):4191-4196
Redox cycling of Fe(II)/Fe(III) during the catalyzed aqueous S(IV) oxidation by dissolved oxygen in the presence of Fe(II) and/or Fe(III) at an initial pHi of 4.4, often observed in atmospheric waters, was studied in detail. It has been found that the reaction rate is not considerably affected by the oxidation state of iron at the start of the reaction. An equilibrium between Fe(II) and Fe(III) was established a few minutes after the start of the reaction, regardless of the oxidation state of iron at the beginning of the experiment. The prevailing oxidation state of iron in a particular phase of the reaction depends on the concentration of S(IV) in the reaction solution. It has been found that the formation of polymerized hydroxo Fe(III) species is also included in the mechanism of the Fe-catalyzed oxidation of S(IV). The formation of these species was confirmed by the on-line measurement of Fe(II) and Fereac. The results also clearly demonstrate that the pHi of the solution is a major factor, controlling the concentration of Fe(III) ions, the form of S(IV) species, and consequently the reaction rate of S(IV) oxidation by oxygen. 相似文献
192.
紫外光催化氧化技术处理有机污染物的研究动态 总被引:5,自引:1,他引:5
主要介绍了北美先进的紫外光催化氧化技术对有机废水、废气的处理研究与应用,简要介绍三种类型光催化反应器的结构。该技术在国外处于研究阶段,预期应用前景很好,尤其适用于电力充沛地区有机废水、废气的处理,具有应用方便、处理效果好,投资费用低等特点。 相似文献
193.
194.
ComparisonofsomeatmosphericchemicalmodelingschemesShenJi,ZhaoQianxueResearchCenterforEcoEnviromentalSciences,ChineseAcademy... 相似文献
195.
Zhang Yuan-hang Xie Shao-dong Zeng Li-min Wang Hui-xiang Yu Kai-heng Zhu Chang-jian Pan Nan-ming Wang Bo-guang 《环境科学学报(英文版)》1999,11(3):355-360
A comprehensive field measurement was set up in Guangzhou City of China and the key was placed on NOx and O3 pollution. The results indicated that the average driving speed of vehicle was only 14 km/h in downtown with high frequency of idle and acceleration. Upward fluxes of CO and NO were observed in Dongfeng street. NOx annual mean concentration in urban area increased year by year, and NOx was identified as the most important pollutant since 1995. Photochemical smog pollution was serious in general,spatial and seasonal distribution of O3 was observed. O3 concentration was kept in a high level in autumn, and its formation was restrained in summer due to frequent thunderstorm and high humidity. The numerical simulation showed the average concentration and maximum concentration of O3 would increase 60%—100% if vehicular emission increased 100% in Guangzhou. 相似文献
196.
燃煤烟气中多环芳烃(PAHs)光化学降解的研究 总被引:4,自引:0,他引:4
研究了各种条件下,燃煤烟气中多环芳烃(PAHs)的光化学降解。实验结果表明,采用模拟日光中紫外部分的荧光灯照射,PAHs光解率随光照强度、照射时间、温度和水蒸气含量的增加而增大。由此推断,在夏季高温、潮湿和高日照条件下,PAHs一般在数小时内即全部降解。而在冬季低温、干燥和低日照的气候条件下,PAHs降解速率很小,可在大气中停留较长时间,扩散到较远距离。还提出了由烟气中水蒸气产生的气态OH自由基以及未燃尽烃类自由基与激发态PAHs碰撞导致发生PAHs污染物光化学降解的反应机理。 相似文献
197.
Photoreaction of particle-bound 1-nitropyrehe (1-NP) under simulated atmospheric condition has been studied. When 1-NP coated on the surface of silica gel was suspended in a stream of nitrogen, oxygen or air, respectively, and exposed to intensive light of xenon lamp, photochemical reaction took place. The result of kinetic study showed it to be of the second order. The photoreaction products were identified by off-line HPLC/MS as 1,6-pyrenequinone, 1,8-pyrenequinone, trinitro-hydroxypyrene, dinitrohydroxypyrene, 6,6'- dipyrenenone, etc. The mutagenicity of photochemical reaction products is higher in oxygen and air, and lower in nitrogen than that of the precursor 1-NP, as detected by the Ames Bioassay. 相似文献
198.
在光催化剂的参与下,光催化产生·OH、·O2-等自由基,电催化产生·OH、OH-等自由基,这些自由基是水系中存在的氧化能力最强的氧化剂.本实验将光、电协同催化应用于直接深兰L废水的处理上,研究了影响染料废水脱色(降解)的有关因素.表明了在电场作用下,光催化氧化的效果将得到加强,从而大大提高了染料废水的降解速率. 相似文献
199.
IntroductionInstallationofscrubbersortheuseoflowsulfur containingcoalaretwooptionsusedbypowerplantstoreduceSO2 emissions.ThemajorityofpowerplantscontrolSO2 emissionsusinglimebasedscrubbing ,althoughthisdesulfurizationprocesshasanumberofadvantages,italsoh… 相似文献
200.
HNO_3催化氧化煤系硫铁矿生产聚铁工艺研究 总被引:2,自引:0,他引:2
提出一种以HNO3氧化煤系硫铁矿后产物FeSO4 、H2 SO4 以及补充的FeSO4 和H2 SO4 为原料 ,放出NO为催化剂 ,O2 为氧化剂 ,生产无机净水剂聚铁的生产方法 ,并讨论其工艺条件 相似文献