地下水污染的原位值复技术——PRB法

原位修复地下水污染技术,具有经济、高效等特点.国外大量研究表明,此技术可以有效去除地下水中的重金属和有机污染物.本文主要介绍了原位修复技术中的PRB方法及其特点,并通过实验验证了其对地下水中重金属、有机物和三氮等污染物的去除效果,以此为基础,讨论了在我国开发应用该技术的前景及应注意的问题.     

Optimal Environmental Management Strategy and Implementation for Groundwater Contamination Prevention and Restoration

An innovative management strategy is proposed for optimized and integrated environmental management for regional or national groundwater contamination prevention and restoration allied with consideration of sustainable development. This management strategy accounts for availability of limited resources, human health and ecological risks from groundwater contamination, costs for groundwater protection measures, beneficial uses and values from groundwater protection, and sustainable development. Six different categories of costs are identified with regard to groundwater prevention and restoration. In addition, different environmental impacts from groundwater contamination including human health and ecological risks are individually taken into account. System optimization principles are implemented to accomplish decision-makings on the optimal resources allocations of the available resources or budgets to different existing contaminated sites and projected contamination sites for a maximal risk reduction. Established management constraints such as budget limitations under different categories of costs are satisfied at the optimal solution. A stepwise optimization process is proposed in which the first step is to select optimally a limited number of sites where remediation or prevention measures will be taken, from all the existing contaminated and projected contamination sites, based on a total regionally or nationally available budget in a certain time frame such as 10 years. Then, several optimization steps determined year-by-year optimal distributions of the available yearly budgets for those selected sites. A hypothetical case study is presented to demonstrate a practical implementation of the management strategy. Several issues pertaining to groundwater contamination exposure and risk assessments and remediation cost evaluations are briefly discussed for adequately understanding implementations of the management strategy.     

An Evaluation of the Influence of Natural Science in Regional-Scale Restoration Projects

Regional-scale restoration is a tool of growing importance in environmental management, and the number, scope, and complexity of restoration programs is increasing. Although the importance of natural science to the success of such projects generally is recognized, the actual use of natural science in these programs rarely has been evaluated. We used techniques of program evaluation to examine the use of natural science in six American and three Western European regional-scale restoration programs. Our results suggest that ensuring the technical rigor and directed application of the science is important to program development and delivery. However, the influence of science may be constrained if strategies for its integration into the broader program are lacking. Consequently, the influence of natural science in restoration programs is greatest when formal mechanisms exist for incorporating science into programs, for example, via a framework for integration of science and policy. Our evaluation proposes a model that can be used to enhance the influence of natural science in regional-scale restoration programs in the United States and elsewhere.     

富营养化浅水湖泊稳态转换理论与生态恢复探讨

从清水稳态与浊水稳态转换的过程、稳态阈值、稳态恢复力等方面介绍了浅水湖泊的稳态转换理论,总结了浊水稳态与清水稳态恢复力的影响因素,以及清水稳态与浊水稳态相互转换的驱动力,分析了富营养化引起的植物群落演替和稳态转换的过程.根据稳态转换理论和太湖五里湖的生态恢复实践,提出以改善生境条件为稳态转换驱动力进行生态恢复,并阐述了降低营养盐浓度、提高水体透明度、清除某些鱼类、改善基底、调节水位、软围隔消浪等生境改善措施.      

海口市南渡江河岸带生态修复策略与技术路径研究

河流作为自然界的一部分,是人类文明的摇篮,也是人类活动的重要区域.河岸带是河流生态系统的重要组成部分,在维系生态平衡中发挥着巨大作用.本文以南渡江河岸带生态修复为例,提出了河岸带的3种生态修复策略和5种生态修复模式,并对未来河流生态修复重点提出了相关建议,以期为国内河流生态修复与综合管理提供参考与借鉴.     

三峡水库消落带典型主动与被动修复策略对土壤饱和导水率的影响

人工造林的主动修复与退耕还林还草的被动修复是退化生态系统典型的生态修复策略.以三峡水库运行后形成的消落带为研究对象,研究不同生态修复策略对消落带土壤饱和导水率的影响,对生态脆弱带的水土保持效应具有重要意义.选取桑树+水杉复合林(主动修复)、自然草地(被动修复)、农田(对照)为研究样地,探究了两种不同生态修复策略下三峡水...     

山-水-林-田-湖-草-海-城修复模式的实践应用 ——威海华夏城采石场生态修复及其效益评价

山-水-林-田-湖-草系统保护与修复强调生态系统整体性、系统性和稳定性,生态系统的健康稳定有利于生态系统服务功能的全面优化提升,对确保生态环境安全和社会经济健康协调发展至关重要.山东威海华夏城受大规模开山采石活动影响,区域生态环境遭到破坏,居民生产生活受到严重干扰,经过10余年生态修复,华夏城实现了生态效益与社会经济效...     

稀水溶液中Cr(Ⅵ)光化学还原的研究

研究了稀水溶液中Cr(Ⅵ)的光化学还原过程,考察了·OH自由基俘获剂的种类、结构及溶液pH值对Cr(Ⅵ)还原的影响结果表明稀水溶液中Cr(Ⅵ)的还原过程分化学还原与光化学还原两步进行,前者为直接氧化还原过程,后者则经历自由基反应;·OH自由基俘获剂中羟基的数量和位置对Cr(Ⅵ)的还原均有影响,羟基α位碳上氢原子数量愈多,碳氢键强度愈小,愈有利于Cr(Ⅵ)还原;溶液pH值对Cr(Ⅵ)的还原有重要影响,随着pH值的升高,其还原率和反应速率均下降,当pH≥70时,Cr(Ⅵ)的还原基本停止     

水溶液中4-氯酚的微波辅助光化学降解

研究了微波辅助无极紫外灯(MW/UV)光化学降解4-氯酚(4CP)模拟废水;为了考察溶液中4CP的降解效果,用紫外可见分光光度法(UV-VIS)和离子色谱法(IC)测定了溶液中4CP的降解率和Cl^-浓度.结果表明,MW/UV体系中30mg/L 4CP反应120min的降解率由紫外(UV)光解体系的21.56%提高到52.40%.提高溶液的pH值、向体系通入氧气、增强光照度以及外加氧化剂H₂O₂均能增加水溶液中4CP的降解率.微波辅助光化学降解4CP服从一级反应动力学方程.     

参与光化学反应的物质对UV能量吸收的估算

在对北京紫外辐射(UV)观测资料分析的基础上,提出参与光化学反应的物质对UV能量具有吸收作用.计算了1990年12个月实际天气比晴天UV能量的减少值在64～109 W/m2之间,这一减少受臭氧、"水汽"、气溶胶等因子的衰减分别为39.1～66.3,21.5～36.5,3.2～5.5 W/m2(12月除外),12个月的平均值分别为48.3,26.6,4.0 W/m2.计算结果表明,云天大气对UV能量有衰减,其衰减能量中有26.6 W/m2是"水汽的作用",即参与大气光化学反应的物质对UV能量吸收所造成的,此计算值同国外观测与模式的研究结果比较接近.由于现有模式中还没有考虑这一部分能量,所以造成模式结果与观测结果间较大的差异.