产业结构调整对流域供需水平衡及水质改善的影响

基于系统动力学(SD)模型和水质(WQ)模型建立了描述深圳河流域社会、经济、水资源和水环境系统的耦合模型(SD-WQM).定量分析了三产比例调整、工业结构内部调整及产业技术提升对流域供需水平衡和水质改善的影响.结果表明,三产比例调整对流域水资源平衡有一定改善作用,但对流域水质变化不敏感;工业调整中劳动密集型产业的比重减少或技术提升、第三产业技术提升对流域的水资源平衡和水质改善作用明显.根据各措施的敏感性,设计了可以满足流域供需水平衡与水质要求的综合调整方案.     

水质模型与CMB相耦合的河流污染源源解析技术

开发了水质模型与化学质量平衡模型(CMB)相耦合的河流污染源源解析技术,用于解析上游断面、直排工业源、支流源和未知源对河流受体断面的污染贡献。该技术可解析具体污染源对环境受体的相对贡献率和绝对贡献值,并附有诊断指标以判断拟合结果的优劣。利用开发出的源解析模型对山东省小清河主要断面进行了解析,发现解析结果与实际情况相符且满足诊断指标要求。扩散模型与受体模型的有机结合,提高了解析结果与实际情况的符合程度。     

关于自然资源核算的研究进展与争议问题

十八届三中全会提出要探索编制自然资源资产负债表,对领导干部实行自然资源资产离任审计.自然资源核算是编制自然资源资产负债表的首要工作,为了促进生态文明建设,建立我国自然资源资产负债表制度,也需要对自然资源进行科学的核算.论文从核算项目分类,理论方法和实践应用三个方面综述了国内外自然资源核算的研究进展,力图厘清国内外自然资源核算研究的共识与争议问题.西方国家资源核算研究起步较早,在理论方法和实际应用方面已取得了丰富的成果.与之相比,我国的研究还主要集中在理论分析层面,自然资源的核算方法多是沿用国外的估价模型,缺乏创新.目前,国内外普遍按照先实物量再价值量,先存量再流量,先分类再综合的原则进行自然资源核算研究.但是,各国的核心项目分类尚未统一,自然资源估价方法的选择还存在争议.在实践方面,联合国等五大机构联合发布的SEEA受到世界各国的广泛追捧,很多国家开始在此基础上探索本国的资源核算体系.通过比较分析国内外的研究进展和共识问题,论文提出了我国自然资源资产负债表编制需要解决的问题,包括确定核算项目,选择估价方法,分步推进自然资源核算和自然资源核算与自然资源资产负债表的衔接.这些问题的解决思路主要从四个方面展开:选择可控或拥有的,产权明晰的自然资源作为核算项目,充分考虑资源要素的经济,生态和社会价值选择估价方法,优先建立单项资源的区域自然资源核算体系,结合各方力量设计我国统一的自然资源核算标准.根据上述思路,开展自然资源核算研究,将资源环境核算纳入国民经济核算,构建自然资源核算框架体系,是编制我国自然资源资产负债表的一项重要内容,对顺利开展生态文明建设具有重要意义.     

基于绝热火焰温度多元混合气体可燃性极限的理论预测

为了预测多元混合气体可燃性极限,通过化学平衡计算软件分析确定了气体在可燃性下限（LFL）和可燃性上限（UFL）的燃烧产物及计算绝热火焰温度（CAFT）,基于能量平衡方程和简化反应模型,分别建立了混合气体LFL和UFL预测模型。应用该预测模型对CH4、C2H4、C3H8、C3H6和CO组成的不同比例混合气体可燃性极限进行预测。结果表明:简化反应模型对于LFL和UFL预测值与文献中实验值的平均相对误差分别为2.76%和5.45%,相关系数分别为0.995和0.950;同时发现两步简化模型对含有C2H4和CO混合组分预测结果误差较大,但对于平均碳原子数大于2的混合气体,预测结果一致性较好。     

Full scale treatment of hazardous wastewater through thermal reduction

An attempt has been made to present the data relating to full scale application of evaporation‐incineration technology for containment of wastewater emanating from H‐acid (mono sodium salt of 1 amino‐8‐hydroxynapthalene 3,6‐disulphonic acid) production with recourse to zero wastewater discharge. The wastewater is acidic with high concentrations of COD and total dissolved salts and BOD/COD ratio of 0.11. NO_x, SO_x, SPM and CO from stack emissions are within the standards stipulated by the statutory bodies.     

依据经济水平建立的华中-华南粮食运输模型

从中国土地利用现状出发，根据目前的中国粮食生产、粮食需求关系和地区经济水平差异等因素,建立了粮食调拨运输模型——计划经济型(非市场原理型)和市场原理型(自由购买型)。并将这两种模型分别应用到中国华中-华南地区,讨论了中国华中—华南地区的粮食储备变化特点。模拟结果显示:非市场原理型运输模型中,随着粮食运输强度系数的增大,城市地区的粮食不足现象逐步得到缓解;而粮食产地的粮食储量也将相应减少，粮食分布的区域不平衡不会长期存在。依据市场原理型运输模型,随着粮食吸收系数的增大,粮食储备迅速集中到沿海城市,此后粮食生产地区的粮食储备开始减少,内陆地区会出现大范围的粮食短缺现象。这种粮食分布的区域不平衡现象越来越大。     

天平的不等臂性对测试的影响

天平是一种重要的试验室检测仪器,在个体防护用品的检验工作中同样不可或缺,比如防护服的透气量测试、旋转辊筒法对防护鞋外底磨耗量的检测等,都会用到天平。本文主要从产生天平不等臂的原因及不等臂的检测、不等臂的调整等方面,简要论述了天平的正确性对测量的影响。     

EVAPOTRANSPIRATION FROM A BULRUSH‐DOMINATED WETLAND IN THE KLAMATH BASIN,OREGON1

ABSTRACT: Growing‐season evapotranspiration and surface energy and water balances were investigated for an extensive, bulrush‐dominated wetland in the Upper Klamath National Wildlife Refuge of south‐central Oregon, a semi‐arid region with competing demands for scarce water resources. Turbulent fluxes of sensible and latent heat were measured by eddy covariance for 1.2 to 1.9 days during each of four site visits during late‐May to mid‐October 1997. Mean daytime latent heat flux and the Bowen ratio ranged from 148 to 178 W m^?2 and from 0.38 to 0.51, respectively, during late May, mid‐July, and late August site visits. By mid‐October, when the plant canopy had senesced, daytime latent heat flux and the Bowen ratio averaged 46 W m^?2 and 2.8, respectively. An hourly Penman‐Monteith (PM) model that was fitted to the surface‐flux data provided values for the surface resistance to water‐vapor diffusion that ranged from 78 s m^?1 during late August to 206 s m^?1 during mid‐October. Similarly, a Priestley‐Taylor (PT) model provided values for the PT multiplier (a) that ranged from 0.96 during late August to 0.37 during mid‐October. The PM and PT models predicted evapotranspiration totals of 560 and 480 mm, respectively, for May 28 to October 12, 1997.     

A model for tropospheric multiphase chemistry: application to one cloudy event during the CIME experiment

A multiphase box model for a remote environment of the troposphere has been developed with an explicit chemistry for both gas and aqueous phase. The model applied to a set of measurements performed by Voisin et al. (2000) during the European CIME experiment for a cloud event on 13th December 1997 at the top of the Puy de Dôme (France). The results of the simulation are compared to the measurements in order to follow the evolution of the ambient chemical composition as a function of the pH and of the varying water content. After verifying that the model retrieves the main features observed in the behavior of species in the cloud droplets, a detailed analysis of the simulated chemical regime is performed. It essentially discusses the sources and sinks of radical in aqueous phase, the relative importance of the oxidation pathways of volatile organic compounds by the main radicals and the conversion of S(IV) into S(VI) which seems to be influenced by the presence of peroxonitric acid, HNO₄, in aqueous phase in the environmental conditions that are considered with low H₂O₂. These numerical results are then compared with the theoretical study from Herrmann et al. (2000), who proposed a slightly different mechanism, including C2 chemistry and transition metal chemistry whereas they neglect some reaction pathways, such as the one involving OHCH₂O₂ radical. This double confrontation between model results and both real experimental data and numerical results from Herrmann et al. (1999c) underlines limitations of such modeling approach that does not include any dynamical or microphysical coupling but also demonstrates its capability to identify the main oxidants or reactants in aqueous phase in real environmental conditions more realistic than a purely theoretical approach. The originality of this study resides in the explicit and exhaustive ways the chemical reactions are treated in aqueous phase and in a first attempt to compare such a detailed chemical scheme to real environmental conditions.     

天然水体中亚硝酸根和硝酸根的光化学研究进展

综述了近年来亚硝酸根和硝酸根 (NO-2 /NO-3 )在天然水体中的环境光化学研究进展。重点介绍了NO-2 /NO-3 光解生成活性氧 (如羟基 )的机理及其影响因素 ,探讨了NO-2 /NO-3 光解引发天然水体中有机物反应的环境意义 ,并据此提出了本领域今后的研究方向