提高电捕焦油器安全生产运行的措施

简要叙述了电捕焦油器开工以来存在的问题,对电捕捕焦油器不能安全稳定运行的原因进行了分析,并采取改进措施。实践证明,改进工艺技术合理,方法可行,电捕焦油器运行效果达到指标要求。     

Ecotoxicity evaluation of Cu- and Fe-CNT complexes based on the activity of bacterial bioluminescence and seed germination

The toxic effects of the composites of Fe~0 and Cu~0 with different percentages of CNTs were examined based on the activity of bacterial bioluminescence and seed germination. In terms of the EC_50 values, the toxic effects of Cu~0 on bacterial bioluminescence and seed germination were approximately 2 and 180 times greater than that of Fe~0, respectively. The toxicity increased with increasing CNT content in the Cu-CNT mixtures for both organisms,whereas opposite results were observed with Fe-CNT mixtures. The mean toxic effects of Cu-CNT(6%) were approximately 1.3–1.4 times greater than that of Cu-CNT(0%), whereas the toxic effects of Fe-CNT(6%) were approximately 2.1–2.5 times lower than that of Fe-CNT(0%) for both the bioluminescence activity and seed germination. The causes of this phenomenon are unclear at this point. More research will be needed to elucidate the mechanism of the toxicity of nano-mixture materials and the causes of the different patterns of toxicity with Cu-and Fe-CNT mixtures.     

两种桑科植物叶片光合及光呼吸对模拟干旱的响应

采用150 g/L的聚乙二醇(Polyethylene glycol,PEG)模拟干旱胁迫,研究两种桑科植物(构树和桑树)的叶片光合及光呼吸特征对干旱胁迫的响应。对植物培养液的相关化学参数以及叶片的光合参数进行测定,结果表明:干旱对构树根系吸水能力的影响小于桑树的;构树以中光合-低蒸腾-高水分利用率的模式适应干旱环境,桑树以低光合-低蒸腾-高水分利用率的模式来应对干旱环境;在模拟干旱环境下,构树以稳定的羧化效率-高光呼吸速率-高光呼吸利用份额来适应外界胁迫,而桑树以低羧化效率-低光呼吸速率-低光呼吸利用份额来应对外界胁迫。构树表现出对外界干旱胁迫更好的适应性,这种适应机制可能与其较强的光呼吸作用及其碳酸氢根离子利用能力有关。这种"以碳换水"的机制可能是喀斯特适生植物适应岩溶干旱的又一个重要机制。     

在污染条件下生物的生态效应

主要就污染物对动物、植物及人体健康的危害，以及在污染条件下生物的适应与进化作一综述。     

我国淡水水域光合产物的气候生产力探讨

根据太阳辐射在水体中的有效分布、生长季水温和浮游植物光合生态特性等因子,模拟计算了我国大陆东部淡水水域的光合生产力、气候生产力及其季节变化的地理规律。从中得知,这些水域初级产物的年气候生产力主要呈纬向分布,由南向北递减,各地范围在 1.6-24.4gC/m²·a之间,长江以南是>15.0gC/m²·a的高值区,长城以北和四川盆地为<10.0gC/m²·a的低值区,因此,在气候生产力高值区有可能充分利用气候资源优势,开发低成本的自然淡水水域渔业;而在低生产力区,受自然资源的局限其自然捕鱼量需适量控制,因地制宜。     

Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

利用光合细菌处理养猪场污水的试验研究

采用煤渣作为填料 ,光合细菌培养物作为挂膜菌的生物接触氧化法 ,对养猪场污水处理进行了试验研究 ,结果表明 :CODCr,NH3 N ,NO-2 N ,S2 - 的平均去除率分别达到 89 3% ,80 1 % ,90 6% ,82 4% ;水中光合细菌数从580个 /mL增加到 4 8× 1 0 4 个 /mL ,达到了废水资源化的目的。     

取代苯类化合物的二维息定量结构-活性相关研究

为了预测非反应性麻醉型化合物对发光菌的发光半抑制浓度,评价该类化合物的毒性效应,采用独特的二维HQSAR分析方法,根据分子碎片的类型,将分子结构转变成具有特征的分子指纹,并用数字进行标记。这些标记出的数字作为QSAR的描述符,经过偏最小二乘法计算,建立起化合物结构与生物毒性之间的相关关系,由此所获得的HQSAR预测值与实测值之间也存在较好的相关性,即-1g_(pre)EC_(50)=0.311 0.929(-1g_(exp)EC_(50))(n=13,r=0.964)。这一模型的预测效果明显优于传统的二维QSAR模型,其结果可以为定量评估同类化合物的生物毒性提供可靠依据。     

Sex-dependent obesogenic effect of tetracycline on Drosophila melanogaster deteriorated by dysrhythmia

Antibiotics have been identified as obesogens contributing to the prevalence of obesity. Moreover, their environmental toxicity shows sex dependence, which might also explain the sex-dependent obesity observed. Yet, the direct evidence for such a connection and the underlying mechanisms remain to be explored. In this study, the effects of tetracycline, which is a representative antibiotic found in both environmental and food samples, on Drosophila melanogaster were studied with consideration of both sex and circadian rhythms (represented by the eclosion rhythm). Results showed that in morning-eclosed adults, tetracycline significantly stimulated the body weight of females (AM females) at 0.1, 1.0, 10.0 and 100.0 µg/L, while tetracycline only stimulated the body weight of males (AM males) at 1.0 µg/L. In the afternoon-eclosed adults, tetracycline significantly stimulated the body weight of females (PM females) at 0.1, 1.0 and 100.0 µg/L, while it showed more significant stimulation in males (PM males) at all concentrations. Notably, the stimulation levels were the greatest in PM males among all the adults. The results showed the clear sex dependence of the obesogenic effects, which was diminished by dysrhythmia. Further biochemical assays and clustering analysis suggested that the sex- and rhythm-dependent obesogenic effects resulted from the bias toward lipogenesis against lipolysis. Moreover, they were closely related to the preference for the energy storage forms of lactate and glucose and also to the presence of excessive insulin, with the involvement of glucolipid metabolism. Such relationships indicated potential bridges between the obesogenic effects of pollutants and other diseases, e.g., cancer and diabetes.     

光化学反应的环境效应

光化学反应具有良好的环境效应，本文概述了有机合成和环境化学中光化学反应对环境的影响。